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Simultaneous derivatization/pre-concentration of 3-phenoxybenzaldehyde as transformation product of permethrin with 2,4-dinitrophenylhydrazine by solid phase extraction and spectrophotometric detection

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Abstract

A simple, cheap and sensitive solid phase extraction method has been described for simultaneous derivatization and preconcentration of 3-phenoxybenzaldehyde (3-pbAl) in aqueous samples. The method is based on the reaction of 3-pbAl with 2,4-dinitrophenylhydrazine (DNPH) to form 2,4-dinitrophenyhydrazone in a column packed with silica gel. Using 100 mg of the sorbent, this compound was sorbed at pH 3 and recovered with 4 mL acetonitrile prior to its spectrophotometric determination at 407 nm. The effect of DNPH concentration, pH, sample flow rate and volume, elution conditions and foreign ions has been investigated. A preconcentration factor of 25 was achieved by passing 100 mL of sample through the column. The relative standard deviation for 5 replicate analyses at three concentration levels of 3-pbAl was from 0.34 to 1.12%.The calibration curve was linear from 0.01 to 5 μg/mL of 3-pbAl, and limit of detection (S/N = 3) was 1.4 ng/mL. Molar absorptivity was found to be 4.7 × 104 L/(mol cm).

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Authors and Affiliations

  1. Department of Chemistry, Vali-e-Asr University of Rafsanjan, Rafsanjan, Iran

    Mahboubeh Saeidi & Zeinab Yazdani

  2. Department of Chemistry, Payame Noor University, Tehran, PO BOX19395-4697, Iran

    Fatemeh Sabermahani

Authors
  1. Mahboubeh Saeidi
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  2. Zeinab Yazdani
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  3. Fatemeh Sabermahani
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Correspondence to Mahboubeh Saeidi.

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Saeidi, M., Yazdani, Z. & Sabermahani, F. Simultaneous derivatization/pre-concentration of 3-phenoxybenzaldehyde as transformation product of permethrin with 2,4-dinitrophenylhydrazine by solid phase extraction and spectrophotometric detection. J Anal Chem 70, 17–21 (2015). https://doi.org/10.1134/S1061934815010104

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