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Synthesis and characterization of bismuth-containing oxyfluoroniobate glasses

  • Physical Methods of Investigation
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Abstract

New glasses are prepared in the MnNbOF5-BaF2-BiF3 system. The thermal parameters of these glasses are analyzed as influenced by bismuth trifluoride. IR and Raman spectroscopy shows that the glass structures are built of Nb(O, F)6 polyhedra, which are linked by oxygen bridges to form glass nets via. A medium-order order region in the glass includes fluoroniobate polyhedra not linked directly to bismuth trifluoride polyhedra. A Ba0.55Bi0.45F2.45 crystalline phase is discovered at 320°C in a glass of composition 20MnNbOF5-40BaF2-40BiF3.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, Russia

    L. N. Ignat’eva, N. N. Savchenko, T. F. Antokhina, S. A. Polishchuk, Yu. V. Marchenko & E. B. Merkulov

  2. Institute of Automatics and Electrometry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    N. V. Surovtsev

  3. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, Leninskii pr. 49, Moscow, 119991, Russia

    V. M. Buznik

Authors
  1. L. N. Ignat’eva
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  2. N. N. Savchenko
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  3. N. V. Surovtsev
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  4. T. F. Antokhina
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  5. S. A. Polishchuk
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  6. Yu. V. Marchenko
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  7. E. B. Merkulov
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  8. V. M. Buznik
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Additional information

Original Russian Text © L.N. Ignat’eva, N.N. Savchenko, N.V. Surovtsev, T.F. Antokhina, S.A. Polishchuk, Yu.V. Marchenko, E.B. Merkulov, V.M. Buznik, 2010, published in Zhurnal Neorganicheskoi Khimii, 2010, Vol. 55, No. 6, pp. 996–1003.

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Ignat’eva, L.N., Savchenko, N.N., Surovtsev, N.V. et al. Synthesis and characterization of bismuth-containing oxyfluoroniobate glasses. Russ. J. Inorg. Chem. 55, 925–931 (2010). https://doi.org/10.1134/S003602361006015X

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  • DOI: https://doi.org/10.1134/S003602361006015X

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