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Adsorption and precipitation of anionic dye Reactive Red 120 from aqueous solution by aminopropyl functionalized magnesium phyllosilicate

  • Separation Technology, Thermodynamics
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Abstract

Dye wastewater causing destruction in ecosystem from a variety of plants an operation needs various factors for environmental cleanup. To improve removal efficiency of dye wastewater, various adsorbents including clay and nonclay-related materials have been tried. The use of soluble aminopropyl functionalized magnesium phyllosilicate (Mg-AMP clay) as an adsorbent for the textile anionic dye Reactive Red 120 (RR 120) was examined thermodynamically and kinetically. The adsorption kinetics followed the pseudo-second-order and Langmuir isotherm equation fitted best models. A maximum amount of adsorption was determined to be 229.9 mg/g, which is one of the highest values studied so far. An Mg-AMP clay dosage of 10 mg/mL obtained from Langmuir model a maximum adsorption capacity of 229.94, 182.26 and 156.54 mg/g at 298.15, 308.15 and 318.15 K, respectively. Moreover the thermodynamic activation parameters such as enthalpy and entropy were determined. We suggest the removal mechanism of RR 120 using Mg-AMP clay by adsorption and precipitation.

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Authors and Affiliations

  1. Department of Biochemical and Polymer Engineering, Chosun University, 309 Pilmundaero, Dong-gu, Gwangju, 61452, Korea

    Yong-Woon Kim, Jung-Hun Kim & Hyun-Jae Shin

  2. Department of Environmental Engineering, Chosun University, 309 Pilmundaero, Dong-gu, Gwangju, 61452, Korea

    Deok Hyun Moon

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  1. Yong-Woon Kim
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  2. Jung-Hun Kim
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  3. Deok Hyun Moon
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  4. Hyun-Jae Shin
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Correspondence to Hyun-Jae Shin.

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Kim, YW., Kim, JH., Moon, D.H. et al. Adsorption and precipitation of anionic dye Reactive Red 120 from aqueous solution by aminopropyl functionalized magnesium phyllosilicate. Korean J. Chem. Eng. 36, 101–108 (2019). https://doi.org/10.1007/s11814-018-0168-8

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  • DOI: https://doi.org/10.1007/s11814-018-0168-8

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