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Interaction between block copolymer micelles in solution

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Frontiers in Polymer Science

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 71))

Abstract

Interactions between micelles of the three-block copolymer polystyrene-block-(hydrogenated polybutadiene)-block-polystyrene in selective solvent mixtures 1,4-dioxane/0-30 vol. % n-heptane were investigated by light scattering methods. Experimental values of the second virial coefficient, A 2, from the time-averaged light scattering data agree with theoretical values for the hard sphere model. The diffusion viral-coefficient values, k D, from quasielastic light scattering measurements agree within the limits of experimental error with the experimental k D value determined by Kops-Werkhoven and coworkers for spherical silica particles. Virtually monodisperse block-copolymer micelles appeared to be suitable for testing theoretical results obtained for hard sphere interactions.

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, 162 06, Prague 6, Czechoslovakia

    Č. Koňák, Z. Tuzar, P. Štěpánek, B. Sedláček & P. Kratochvíl

Authors
  1. Č. Koňák
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  2. Z. Tuzar
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  3. P. Štěpánek
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  4. B. Sedláček
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  5. P. Kratochvíl
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Editor information

W. Wilke

Additional information

Dedicated to Prof. Dr. H.-G. Kilian on the occasion of his 60th birthday.

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© 1985 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Koňák, Č., Tuzar, Z., Štěpánek, P., Sedláček, B., Kratochvíl, P. (1985). Interaction between block copolymer micelles in solution. In: Wilke, W. (eds) Frontiers in Polymer Science. Progress in Colloid & Polymer Science, vol 71. Steinkopff. https://doi.org/10.1007/BFb0114009

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  • DOI: https://doi.org/10.1007/BFb0114009

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-0691-6

  • Online ISBN: 978-3-7985-1698-4

  • eBook Packages: Springer Book Archive

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