Skip to main content
Log in

The preparation and properties of some lithium borate based glasses

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The preparation and properties of lithium borate based glasses are described. The properties which were monitored included the glass-forming ability, the thermal stability, the chemical durability and the mechanical behaviour. Methods which were used in an attempt to improve the mechanical properties of these glasses are also discussed, including controlled crystallization, chemical ion-exchange and fibre reinforcement. The strongest glass, which had a mean strength of ~ 280 MPa in biaxial flexure, was produced by ion-exchange in molten sodium nitrate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. L. Griscom, in “Borate glasses: structure, properties and applications”, edited by L. D. Pye, V. D. Rréchette and N. J. Kreidl (Plenum Press, New York, 1978) pp. 11–138.

    Chapter  Google Scholar 

  2. S. A. Feller, W. J. Dell and P. J. Bray, J. Non-Cryst. Solids 51 (1982) 21.

    Article  CAS  Google Scholar 

  3. N. J. Kreidl in “Glass science and technology”, Vol. 1, edited by D. R. Uhlmann and N. J. Kreidl, (Academic Press, New York, 1983) pp. 105–299.

    Google Scholar 

  4. M. Shibata, C. Sanchez, H. Patel, S. Feller, J. Stark, G. Sumcad and J. Kasper, J. Non-Cryst. Solids 85 (1986) 29.

    Article  CAS  Google Scholar 

  5. P. J. Bray, in “Defects in glasses”, edited by F. L. Galeener, Materials Research Society Symposium Proceedings Vol. 61 (Materials Research Society, 1986) pp. 121–133.

  6. N. J. Kreidl, Glastech. Ber. 60 (1987) 249.

    CAS  Google Scholar 

  7. G. D. Chryssikos, E. I. Kamitsos and M. A. Karakassiudes, Phys. Chem. Glasses 31 (1990) 109.

    CAS  Google Scholar 

  8. T. Takamori, in “Treatise on materials science and technology” Vol. 17, edited by M. Tomozawa and R. H. Doremus, (Academic Press, New York, 1979) pp. 173–255.

    Google Scholar 

  9. I. W. Donald, J. Mater. Sci. 28 (1993) 2841.

    Article  CAS  Google Scholar 

  10. H. L. Tuller, D. P. Button and D. R. Uhlmann, J. Non-Cryst. Solids 40 (1980) 93.

    Article  CAS  Google Scholar 

  11. M. Devaud, J-Y. Prieur and W. D. Wallace, Solid State Ionics 9 & 10 (1983) 593.

    Article  Google Scholar 

  12. N. J. Kreidl, Bull. Amer. Ceram. Soc. 63 (1984) 1394.

    Google Scholar 

  13. M. D. Ingram, Phys. Chem. Glasses 28 (1987) 215.

    CAS  Google Scholar 

  14. Y. Kutomi, A. Tomita and N. Takeuchi, J. Mater. Sci. Lett. 6 (1987) 301.

    Article  CAS  Google Scholar 

  15. I. W. Donald, J. Mater. Sci. 24 (1989) 4177.

    Article  CAS  Google Scholar 

  16. P. W. Mcmillan, “Glass ceramics” (Academic Press, London, 1979).

    Google Scholar 

  17. I. W. Donald, “Glass ceramics — an update”, Encyclopedia of Materials Science and Engineering: Supplementary Vol. 3 (Pergamon Press, Oxford, 1993), pp. 1689–1695.

    Google Scholar 

  18. S. Simon and A. L. Nicula, Phys. Status Solidi. 81 (1984) K1-K5.

    Article  CAS  Google Scholar 

  19. M. F. Fahmy and K. N. Subramanian, Phys. Chem. Glasses 28 (1987) 1.

    CAS  Google Scholar 

  20. Idem. ibid. M. F. Fahmy and K. N. Subramanian, Phys. Chem. Glasses 28 (1987) 49.

    CAS  Google Scholar 

  21. G. L. Smith, G. F. Neilson and M. C. Weinberg, ibid. 28 (1987) 257.

    CAS  Google Scholar 

  22. M. Maeda and T. Ikeda, J. Phys. Chem. Solids 49 (1988) 35–39.

    Article  CAS  Google Scholar 

  23. A. A. Goktas, G. F. Nielson and M. C. Weinberg, J. Mater. Sci. 27 (1992) 24–28.

    Article  CAS  Google Scholar 

  24. R. L. Thakur and S. Thiagarajan, Glass Ceram. Bull. 13 (1966) 33.

    Google Scholar 

  25. A. Marotta, A. Buri and F. Branda, J. Mater. Sci. 16 (1981) 341–344.

    Article  CAS  Google Scholar 

  26. A. Marotta, S. Saiello, F. Branda and A. Buri, Verres Réfract. 35 (1981) 477–480.

    CAS  Google Scholar 

  27. S. Saiello, F. Branda, A. Buri and A. Marotta, ibid. 36 (1982) 859–861.

    CAS  Google Scholar 

  28. A. Marotta, A. Buri, F. Branda and S. Saiello, in “Advances in ceramics”, Vol. 4, edited by J. H. Simmons, D. R. Uhlmann and G. H. Beall (American Ceramic Society, Columbus, 1982) pp. 146–152.

    Google Scholar 

  29. H. A. Davies, Phys. Chem. Glasses 17 (1976) 159–173.

    CAS  Google Scholar 

  30. M. J. C. Hill, Atomics Weapons Establishment, unpublished work (1989).

  31. W. Bradshaw, J. Mater. Sci. 14 (1979) 2981–2988.

    Article  CAS  Google Scholar 

  32. I. W. Donald and M. J. C. Hill, ibid. 23 (1988) 2797–2809.

    Article  CAS  Google Scholar 

  33. M. J. C. Hill and I. W. Donald, Glass Technol. 30 (1989) 123–127.

    CAS  Google Scholar 

  34. F. F. Vitman and V. P. Pukh, Indust. Lab. 29 (1963) 925–930.

    Google Scholar 

  35. J. B. Wachtman, W. Capps and J. Mandel, J. Mater. 7 (1972) 188–194.

    Google Scholar 

  36. ASTM F 394-78 (1978) 802–808.

  37. J. E. Ritter, K. Jakus, A. Batakis and N. Bandyopadhay, J. Non-Cryst. Solids 38 & 39 (1980) 419–424.

    Article  Google Scholar 

  38. J. E. Shelby, J. Amer. Ceram. Soc. 66 (1983) 225.

    Article  CAS  Google Scholar 

  39. M. Affatigato, S. Feller, E. J. Khaw, D. Feil, B. Teoh and O. Mathews, Phys. Chem. Glasses 31 (1990) 19.

    CAS  Google Scholar 

  40. B. S. R. Sastry and F. A. Hummel, J. Amer. Ceram. Soc. 42 (1959) 218.

    Google Scholar 

  41. I. W. Donald, M. J. C. Hill, B. L. Metcalfe, D. J. Bradley and A. D. Bye, Glass Techno. 34 (1993) 114.

    CAS  Google Scholar 

  42. L. Shartsis, W. Capps and S. Spinner, J. Amer. Ceram. Soc. 36 (1953) 319.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Donald, I.W., Metcalfe, B.L., Bradley, D.J. et al. The preparation and properties of some lithium borate based glasses. JOURNAL OF MATERIALS SCIENCE 29, 6379–6396 (1994). https://doi.org/10.1007/BF00353994

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00353994

Keywords

Navigation