Abstract
Electrode materials for lithium-ion batteries allow both the insertion-deinsertion of Li+ ions within their framework and redox reactions of an electroactive element. The latter thus undergoes changes in its oxidation state and possibly in its spin state as well as in the localised or metallic character of the electron spins it can carry.
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Grey, C.P., Dobson, C.M., Cheetham, A.K. and Jakeman, R.J.B. (1989) Studies of rare-earth stannates by 119Sn MAS NMR. The use of paramagnetic shift probes in the solid state. J. Am. Chem.Soc., 111 505–511.
Gee, B., Horne, C.R., Caims, E.J. and Reimer, J.A. (1998) Supertransferred hyperfine fields at 7Li: Variable temperature 7Li MAS NMR studies of LiMn2O4-based spinels. J. Phys. Chem. B, 102 10142–10149.
Maruta, G., Takeda, S., Imachi, R., Ishida, T., Nogami, T. and Yamagushi, K. (1999) Solidstate high resolution 1H and 2D NMR study of the electron spin density distribution of the hydrogen-bonded organic ferromagnet compound 4-hydroxyimino-TEMPO. J. Am. Chem. Soc., 121 424–431.
Delmas, C., Ménétrier, M., Croguennec, L., Saadoune, I., Rougier A., Pouillerie, C., Prado, G., Grüne, M. and Foumes, L. (1999) An overview of the Li(Ni,M)O2 systems: syntheses, structures and properties, Electrochemica Acta, in press.
Marichal, C., Hirschinger, J., Granger, P., Ménétrier, M., Rougier, A. and Delmas, C. (1995) 6Li and 7Li NMR in the LiNi1-yCoyO2 solid solution, Inorg. Chem, 34 1773–1778.
Saadoune, I., Ménétrier, M. and Delmas, C. (1997) Redox processes in LixNi1-yCoyO2 cobaltrich phases, J. Mater. Chem, 7 2505–2511.
Ménétrier, M., Saadoune, I., Levasseur, S. and Delmas, C. (1999) The insulator-metal transition upon lithium deintercalation from LiCoO2: electronic properties and 7Li NMR studies, J. Mater. Chem., 9 1135–1140.
Van der Ven, A., Aydinol, M.K. and Ceder, G. (1998) First-principles investigation of phase stability in LixCoO2, Pys. Rev. B, 58 2975–2987.
Levasseur, S., Ménétrier, M., Suard, E. and Delmas, C. (1999) Evidence for structural defects in non-stoichiometric HT LiCoO2, Solid State Ionics, in press.
Guérin, K., Ménétrier, M., Février-Bouvier, A., Flandrois, S., Simon, B. and Biensan, P. (1999) A 7Li NMR study of a hard carbon for lithium-ion rechargeable batteries, Solid State Ionics, In press.
Flandrois, S. and Simon, B. (1999) Carbon materials for lithium-ion rechargeable batteries, Carbon, 37 165–180.
Tatsumi, K., Conard, J., Menu, S., Lauginie, P., Sawada, Y. and Ogumi, Z. (1997) 7Li NMR sudies on a lithiated non-graphitisable carbon fibre at low temperature, Chem. Commun,. 687-688.
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© 2000 Springer Science+Business Media Dordrecht
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Ménétrier, M. (2000). 7Li NMR in Some Lithium Intercalation Compounds. In: Julien, C., Stoynov, Z. (eds) Materials for Lithium-Ion Batteries. NATO Science Series, vol 85. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4333-2_31
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DOI: https://doi.org/10.1007/978-94-011-4333-2_31
Publisher Name: Springer, Dordrecht
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