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Metal Containing Compounds: Precursors for new Reactions and Materials

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Organic Synthesis via Organometallics (OSM 4)
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Summary

The syntheses of six-membered metallacyclophosphazenes and metal containing siloxanes are described. Phosphazene and siloxane groups are isoelectronic a concept aiding in the synthesis of the target molecules. The metal containing silicones function as model compounds for metal oxides on silica surfaces. A first example of a metal containing borazine is given. Some of the compounds function as precursors for chemical vapor deposition.

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References

  1. H.W. Roesky, Synlett, 1 (1990) 651, and literature quoted herein.

    Article  Google Scholar 

  2. A. Stock, E. Pohland, Chem. Ber. 59 (1926) 2215.

    Google Scholar 

  3. H.W. Roesky, K.V. Katti, U. Seseke, M. Witt, E. Egert, R. Herbst, G.M. Sheldrick, Angew. Chem. 88 (1986) 447; Angew. Chem. Int. Ed. Engl. 25 (1986) 477.

    Google Scholar 

  4. R. Hasselbring, H.W. Roesky, M. Rietzel, M. Noltemeyer, Phosphorus, Sulfur, Silicon, in press.

    Google Scholar 

  5. R. Hasselbring, H.W. Roesky, M. Noltemeyer, Angew. Chem. in press.

    Google Scholar 

  6. H.W. Roesky, H. Voelker, M. Witt, M. Noltemeyer, Angew. Chem. 102 (1990) 712; Angew. Chem. Int. Ed. Engl. 29 (1990) 669.

    Article  CAS  Google Scholar 

  7. H.W. Roesky, T. Raubold, M. Witt, R. Bohra, M. Noltemeyer, Chem. Ber. 124 (1991) 1521.

    Article  CAS  Google Scholar 

  8. M. Witt, H.W. Roesky, D. Stalke, T. Henkel, G.M. Sheldrick, J. Chem. Soc. Dalton Trans 1991, 663.

    Google Scholar 

  9. Y. Bai, M. Noltemeyer, H.W. Roesky, Z. Naturforsch. B 46 (1991) 1357.

    Google Scholar 

  10. J.E. Hill, R.D. Profilet, P.E. Fanwick, I.P. Rothwell, Angew. Chem. 102 (1990) 713; Angew. Chem. Int. Ed. Engl. 29 (1990) 664.

    Article  CAS  Google Scholar 

  11. J.E. Hill, P.E. Fanwick, I.P. Rothwell, Inorg. Chem. 30 (1991) 1143.

    Article  CAS  Google Scholar 

  12. C.H. Winter, P.H. Sheridan, T.S. Lewkebandara, M.J. Heeg, J.W. Proscia, J. Am. Chem. Soc. 114 (1992) 1095.

    Article  CAS  Google Scholar 

  13. C.C. Cummins, C.P. Schaller, G.D. Van Duyne, P.T. Wolczanski, A.W.E. Chan, R. Hoffmann, J. Am. Chem. Soc. 113 (1991) 2985.

    Article  CAS  Google Scholar 

  14. P.J. Salsh, F.J. Hollander, R.G. Bergman, J. Am. Chem. Soc. 110 (1988) 8729.

    Article  Google Scholar 

  15. R.D. Profilet, C.H. Zambrano, P.E. Fanwick, J. J. Nash, I.P. Rothwell, Inorg. Chem. 29 (1990) 4364.

    Article  Google Scholar 

  16. Y. Bai, H.W. Roesky, M. Noltemeyer, M. Witt, Chem. Ber. 125 (1992) 825.

    Article  CAS  Google Scholar 

  17. A. Haoudi-Mazzah, A. Mazzah, H.-G. Schmidt, M. Noltemeyer, H.W. Roesky, Z. Naturforsch. 46B (1991) 587.

    Google Scholar 

  18. F. Liu, H.-G. Schmidt, M. Noltemeyer, C. Freire-Erdbrügger, G.M. Sheldrick, H.W. Roesky, Z. Naturforsch, in press.

    Google Scholar 

  19. F. Liu, H.W. Roesky, H.-G. Schmidt, M. Noltemeyer, Angew. Chem. in preparation.

    Google Scholar 

  20. A. Mazzah, A. Haoudi-Mazzah, M. Noltemeyer, H.W. Roesky, Z. Anorg. Allg. Chem. 604 (1991) 93.

    Article  CAS  Google Scholar 

  21. H.W. Roesky, A. Mazzah, D. Hesse, M. Noltemeyer, Chem. Ber. 124 (1991) 519.

    Article  CAS  Google Scholar 

  22. H.-J. Gosink, H.W. Roesky, M. Noltemeyer, H.-G. Schmidt, C. Freire-Erdbrügger, G.M. Sheldrick, Chem. Ber. in preparation

    Google Scholar 

  23. F.J. Feher, J. Am. Chem. Soc. 108 (1986) 3850.

    Article  CAS  Google Scholar 

  24. F.J. Feher, D.A. Newman, J.F. Walzer, J. Am. Chem. Soc. 111 (1989) 1741.

    Article  CAS  Google Scholar 

  25. H.W. Roesky, D. Hesse, R. Bohra, M. Noltemeyer, Chem. Ber. 124 (1991) 1913.

    Article  CAS  Google Scholar 

  26. N. Winkhofer, H.W. Roesky, M. Noltemeyer, W.T. Robinson, Angew. Chem. in press.

    Google Scholar 

  27. U. Wirringa, H.W. Roesky, H.-G. Schmidt, M. Noltemeyer, Chem. Ber. in preparation.

    Google Scholar 

  28. H.-J. Koch, H.W. Roesky, R. Bohra, M. Noltemeyer, H.-G. Schmidt, Angew. Chem. in press.

    Google Scholar 

  29. H.-J. Koch, H.W. Roesky, unpublished results.

    Google Scholar 

  30. G.P. Elliott, W.R. Roper, J.M. Waters, J. Chem. Soc. Chem. Commun. 1982, 811.

    Google Scholar 

  31. M.S. Kralik, A.L. Rheingold, R.D. Ernst, Organometallics, 6 (1987) 4118.

    Article  Google Scholar 

  32. J.R. Bleeke, Y.-F. Xie, W.-J. Peng, M.Y. Chiang, J. Am. Chem. Soc. 111 (1989) 4118.

    Article  CAS  Google Scholar 

  33. J.R. Bleeke, Y.-F. Xie, L. Bass, M.Y. Chiang, J. Am. Chem. Soc. 113 (1991) 4703.

    Article  CAS  Google Scholar 

  34. O. Gottsleben, H.W. Roesky, M. Stuke, Adv. Materials 3 (1991) 201.

    Article  CAS  Google Scholar 

  35. T. Belgardt, W. Rockensüß, H.W. Roesky, unpublished results.

    Google Scholar 

  36. U. Dembowski, M. Noltemeyer, W. Rockensüß, M. Stuke, H.W. Roesky, Chem. Ber. 123 (1990) 2335.

    Article  CAS  Google Scholar 

  37. U. Dembowski, H.W. Roesky, E. Pohl, R. Herbs-Irmer, D. Stalke, G.M. Sheldrick, Z. Anorg. Allg. Chem. in press.

    Google Scholar 

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© 1993 Friedr. Vieweg & Sohn Verlagsgesellschaft mbH, Braunschweig/Wiesbaden

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Roesky, H.W. (1993). Metal Containing Compounds: Precursors for new Reactions and Materials. In: Enders, D., Gais, HJ., Keim, W. (eds) Organic Synthesis via Organometallics (OSM 4). Vieweg+Teubner Verlag. https://doi.org/10.1007/978-3-322-84062-2_9

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  • DOI: https://doi.org/10.1007/978-3-322-84062-2_9

  • Publisher Name: Vieweg+Teubner Verlag

  • Print ISBN: 978-3-528-06481-5

  • Online ISBN: 978-3-322-84062-2

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