There are only a few examples of applications of magnesium enolates in aldol additions. A very early example of a successful employment of magnesium enolates in stereoselective aldol additions was reported by Solladie and coworkers.1,2,3 Deprotonation of sulfinyl acetate with tert-butylmagnesium bromide yielded aldol adducts with moderate to high enantioselectivities (Scheme 2.2.1).
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(2009). Magnesium Enolates. In: Mahrwald, R. (eds) Aldol Reactions. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8701-1_3
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