Silver, Palladium and Platinum Lewis Acids

doi:10.1007/978-1-4020-8701-1_12

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The first asymmetric silver-catalysed Mukaiyama reaction was reported by Yamagishi and coworkers.^1,2 They used a BINOL—AgPF₆ complex in aqueous DMF. Yanagisawa and coworkers developed an enantioselective Mukaiyama aldol approach based on the deployment of p-Tol-BINAP—AgF. Trimethoxysilyl enol ethers of ketones were reacted with non-enolizable aldehydes. The corresponding syn-configured aldol adducts were isolated with excellent enantioselectivities (Scheme 3.1.5.1).^3,4,5

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Editors and Affiliations

Institute of Chemistry, Humboldt University, Brook Taylor Str. 2, Berlin, 12 489, Germany
Rainer Mahrwald

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(2009). Silver, Palladium and Platinum Lewis Acids. In: Mahrwald, R. (eds) Aldol Reactions. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8701-1_12

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DOI: https://doi.org/10.1007/978-1-4020-8701-1_12
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-8700-4
Online ISBN: 978-1-4020-8701-1
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