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Silicon Carbide — A Survey of Synthetic Approaches, Properties and Applications

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High Performance Non-Oxide Ceramics I

Part of the book series: Structure and Bonding ((STRUCTURE,volume 101))

Abstract

The challenge to develop tailor-made precursor molecules for silicon carbide has significantly intensified the progress in synthesis of organosilicon polymers. A critical overview is presented regarding useful synthesis routes towards such molecules with appropriate chemical composition as well as controllable architecture (metal condensation of halogenosilanes or silahalogenocarbons, disproportionation of disilanes, dehydrocoupling of hydrosilanes, hydrosilylation of olefins).

Furthermore, results are summarized concerning the pathways of the pyrolytic chemical degradation of the organosilicon precursor including the structure rearrangements in the solid state.

Finally some illustrative examples of the production of net-shaped ceramic bodies are demonstrated.

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Authors and Affiliations

  1. Institut für Anorganische Chemie, TU Bergakademie Freiberg, 09596, Freiberg, Germany

    G. Roewer, U. Herzog & K. Trommer

  2. Institut für Keramische Werkstoffe, TU Bergakademie Freiberg, 09596, Freiberg, Germany

    E. Müller & S. Frühauf

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Roewer, G., Herzog, U., Trommer, K., Müller, E., Frühauf, S. (2002). Silicon Carbide — A Survey of Synthetic Approaches, Properties and Applications. In: High Performance Non-Oxide Ceramics I. Structure and Bonding, vol 101. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-45613-9_2

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