Abstract
Surface-enhanced Raman scattering (SERS) substrates play important roles for the enhancement of inelastic scattering signals. Traditional substrates such as roughened electrodes and colloidal aggregates suffer from well-known signal reproducibility issues, whereas for current dominant two-dimensional planar systems, the hot spot distributions are limited by the zero-, one- or two-dimensional plane. The introduction of a three-dimensional (3D) system such as a pyramid geometry breaks the limitation of a single Cartesian SERS-active area and extends it into the z-direction, with the tip potentially offering additional benefits of strong field enhancement and high sensitivity. However, current 3D pyramidal designs are restricted to film deposition on prepared pyramid templates or self-assembly in pyramidal molds with spherical building blocks, hence limiting their SERS effectiveness. Here, we report on the fabrication of a new class of low cost and well-defined plasmonic nanoparticle pyramid arrays from different anisotropic shaped nanoparticles using combined top-down lithography and bottom-up self-assembly approach. These pyramids exhibit novel optical scattering properties that can be exploited for the design of reproducible and sensitive SERS substrate. The SERS intensity was found to decrease drastically in accordance with a power law function as the focal planes move from the apex of the pyramid structure towards the base. In comparison to sphere-based building blocks, pyramids assembled from anisotropic rhombic dodecahedral gold nanocrystals with numerous sharp tips exhibited the strongest SERS performance.
Graphical Abstract
Macroscale pyramidal array films with plasmonic tunability as a new class of SERS substrate for sensitive detection of chemicals.
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References
Cialla D, März A, Böhme R, Theil F, Weber K, Schmitt M, Popp J. Anal Bioanal Chem. 2011;403:27–54.
Chen Y, Si KJ, Sikdar D, Tang Y, Premaratne M, Cheng W. Adv Opt Mater. 2015;3:919–24.
Si KJ, Guo P, Shi Q, Cheng W. Anal Chem. 2015;87:5263–9.
Vo-Dinh T, Yan F, Wabuyele MB. J Raman Spectrosc. 2005;36:640–7.
Kneipp K, Wang Y, Kneipp H, Perelman LT, Itzkan I, Dasari RR, Feld MS. Phys Rev Lett. 1997;78:1667–70.
Lane LA, Qian X, Nie S. Chem Rev. 2015;115:10489–529.
Schlücker S. Angew Chem Int Ed. 2014;53:4756–95.
Freeman RG, Grabar KC, Allison KJ, Bright RM, Davis JA, Guthrie AP, Hommer MB, Jackson MA, Smith PC, Walter DG, Natan MJ. Science. 1995;267:1629–32.
Lee W, Lee SY, Briber RM, Rabin O. Adv Funct Mater. 2011;21:3424–9.
Pingping Z, Shumin Y, Liansheng W, Jun Z, Zhichao Z, Bo L, Jun Z, Xuhui S. Nanotechnology. 2014;25:245301.
Betz JF, Yu WW, Cheng Y, White IM, Rubloff GW. Phys Chem Chem Phys. 2014;16:2224–39.
Stiles PL, Dieringer JA, Shah NC, Duyne RPV. Annu Rev Anal Chem. 2008;1:601–26.
Fan M, Andrade GFS, Brolo AG. Anal Chim Acta. 2011;693:7–25.
Shi Q, Si KJ, Sikdar D, Yap LW, Premaratne M, Cheng W. ACS Nano. 2016;10:967–76.
Liu H, Yang Z, Meng L, Sun Y, Wang J, Yang L, Liu J, Tian Z. J Am Chem Soc. 2014;136:5332–41.
Zhang Q, Lee YH, Phang IY, Lee CK, Ling XY. Small. 2014;10:2703–11.
Lee SY, Kim S-H, Kim MP, Jeon HC, Kang H, Kim HJ, Kim BJ, Yang S-M. Chem Mater. 2013;25:2421–6.
Alexander, T. A. In Applications of surface-enhanced Raman spectroscopy (SERs) for biosensing: an analysis of reproducible, commercially available substrates. 2005; p. 600703.
Bantz KC, Meyer AF, Wittenberg NJ, Im H, Kurtuluş Ö, Lee SH, Lindquist NC, Oh S-H, Haynes CL. Phys Chem Chem Phys. 2011;13:11551–67.
Yang J, Judson DR, Peter NC, Carlos AE, Jennings GK, Sharon MW. Nanotechnology. 2011;22:295302.
Perney NMB, García de Abajo FJ, Baumberg JJ, Tang A, Netti MC, Charlton MDB, Zoorob ME. Phys. Rev. B. 2007;76:035426.
Perney NMB, Baumberg JJ, Zoorob ME, Charlton MDB, Mahnkopf S, Netti CM. Opt Express. 2006;14:847–57.
Henzie J, Kwak E-S, Odom TW. Nano Lett. 2005;5:1199–202.
Xu Z, Jiang J, Gartia MR, Liu GL. J Phys Chem C. 2012;116:24161–70.
Chao B-K, Cheng H-H, Nien L-W, Chen M-J, Nagao T, Li J-H, Hsueh C-H. Appl Surf Sci. 2015;357(Part A):615–21.
Alba M, Pazos-Perez N, Vaz B, Formentin P, Tebbe M, Correa-Duarte MA, Granero P, Ferré-Borrull J, Alvarez R, Pallares J, Fery A, de Lera AR, Marsal LF, Alvarez-Puebla RA. Angew Chem Int Ed. 2013;52:6459–63.
Qiu H, Li Z, Gao S, Chen P, Zhang C, Jiang S, Xu S, Yang C, Li H. RSC Adv. 2015;5:83899–905.
Zhang C, Jiang SZ, Yang C, Li CH, Huo YY, Liu XY, Liu AH, Wei Q, Gao SS, Gao XG, Man BY. Sci. Rep. 2016;6:25243.
Xu Z, Wu H-Y, Ali SU, Jiang J, Cunningham BT, Liu GL. NANOP. 2011;5:053526-053526-053511.
Zhang C, Man BY, Jiang SZ, Yang C, Liu M, Chen CS, Xu SC, Qiu HW, Li Z. Appl Surf Sci. 2015;347:668–72.
Ferchichi A, Laariedh F, Sow I, Gourgon C, Boussey J. Microelectron Eng. 2015;140:52–5.
Lin W-C, Liao L-S, Chen Y-H, Chang H-C, Tsai DP, Chiang H-P. Plasmonics. 2010;6:201–6.
Chen J, Shen B, Qin G, Hu X, Qian L, Wang Z, Li S, Ren Y, Zuo L. J Phys Chem C. 2012;116:3320–8.
Zhu Z, Meng H, Liu W, Liu X, Gong J, Qiu X, Jiang L, Wang D, Tang Z. Angew Chem Int Ed. 2011;50:1593–6.
Guo P, Sikdar D, Huang X, Si KJ, Xiong W, Gong S, Yap LW, Premaratne M, Cheng W. Nanoscale. 2015;7:2862–8.
Gosálvez MA, Nieminen RM. New J Phys. 2003;5:100.
Sparacin DK, Spector SJ, Kimerling LC. J Lightwave Technol. 2005;23:2455.
Johnson PB, Christy RW. Phys Rev B. 1972;6:4370–9.
Sikdar D, Rukhlenko ID, Cheng W, Premaratne M. Nanoscale Res Lett. 2013;8:1–5.
Sikdar D, Zhu W, Cheng W, Premaratne M. Plasmonics. 2015;10:1663–73.
Niu W, Zheng S, Wang D, Liu X, Li H, Han S, Chen J, Tang Z, Xu G. J Am Chem Soc. 2009;131:697–703.
Vernon KC, Davis TJ, Scholes FH, Gómez DE, Lau D. J Raman Spectrosc. 2010;41:1106–11.
Wang Y, Lu N, Wang W, Liu L, Feng L, Zeng Z, Li H, Xu W, Wu Z, Hu W, Lu Y, Chi L. Nano Res. 2013;6:159–66.
Oo SZ, Siitonen S, Kontturi V, Eustace DA, Charlton MDB. Opt Express. 2016;24:724–31.
Lindquist NC, Nagpal P, Lesuffleur A, Norris DJ, Oh S-H. Nano Lett. 2010;10:1369–73.
Tian F, Bonnier F, Casey A, Shanahan AE, Byrne HJ. Anal Methods. 2014;6:9116–23.
Boyack R, Le Ru EC. Phys Chem Chem Phys. 2009;11:7398–405.
McLellan JM, Siekkinen A, Chen J, Xia Y. Chem Phys Lett. 2006;427:122–6.
Ko H, Singamaneni S, Tsukruk VV. Small. 2008;4:1576–99.
Haynes CL, Van Duyne RP. J Phys Chem B. 2003;107:7426–33.
Botti S, Cantarini L, Almaviva S, Puiu A, Rufoloni A. Chem Phys Lett. 2014;592:277–81.
Jiwei Q, Yudong L, Ming Y, Qiang W, Zongqiang C, Wudeng W, Wenqiang L, Xuanyi Y, Jingjun X, Qian S. Nanoscale Res Lett. 2013;8:1–6.
Acknowledgements
M.P., and W.L.C. acknowledge Discovery Grants DP110100713, DP140100883, DP120100170, and DP140100052. This work was performed in part at the Melbourne Centre for Nanofabrication (MCN) in the Victorian Node of the Australian National Fabrication Facility (ANFF). D. Sikdar acknowledges Engineering and Physical Sciences Research Council UK’s funding scheme EP/L02098X/1. The manuscript was written through contributions of all authors.
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Yang, W., Si, K.J., Guo, P. et al. Self-Assembled Plasmonic Pyramids from Anisotropic Nanoparticles for High-Efficient SERS. J. Anal. Test. 1, 335–343 (2017). https://doi.org/10.1007/s41664-017-0033-5
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DOI: https://doi.org/10.1007/s41664-017-0033-5