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Bimetal-organic-framework derived CoTiO3 mesoporous micro-prisms anode for superior stable power sodium ion batteries

双金属-有机框架材料衍生介孔微米棱柱状超高功率和稳定性钠离子电池负极

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Abstract

Durability, rate capability, capacity and tap density are paramount performance metrics for promising anode materials, especially for sodium ion batteries. Herein, a carbon free mesoporous CoTiO3 micro-prism with a high tap density (1.8 g cm−3) is newly developed by using a novel Co-Ti-bimetal organic framework (BMOF) as precursor. It is also interesting to find that the Co-Ti-BMOF derived carbon-free mesoporous CoTiO3 micro-prisms deliver a superior stable and more powerful Na+ storage than other similar reported titania, titanate and their carbon composites. Its achieved capacity retention ratio for 2,000 cycles is up to 90.1% at 5 A g−1.

摘要

负极材料的循环、 倍率、 容量和堆积密度是评价钠离子电池性能的关键指标. 为此本工作开发了一种新型的钴-钛双金属-有机框架结构材料并以其作为前躯体衍生制备了具有1.8 g cm−3高堆积密度的无碳介孔钛酸钴微米棱柱状材料. 作为钠离子电池负极材料该种材料展示了超高稳定性同时拥有比其他类似的钛氧化物、 钛酸盐及其碳基复合材料更优异的倍率性能, 其在5 A g−1的电流密度下循环2000圈后容量保持率高达90.1%.

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References

  1. Xiao Y, Lee SH, Sun YK. The application of metal sulfides in sodium ion batteries. Adv Energy Mater, 2017, 7: 1601329

    Article  Google Scholar 

  2. Kang W, Wang Y, Xu J. Recent progress in layered metal dichalcogenide nanostructures as electrodes for high-performance so-dium-ion batteries. J Mater Chem A, 2017, 5: 7667–7690

    Article  Google Scholar 

  3. Lao M, Zhang Y, Luo W, et al. Alloy-based anode materials toward advanced sodium-ion batteries. Adv Mater, 2017, 29: 1700622

    Article  Google Scholar 

  4. Liu Z, Zhang Y, Zhao H, et al. Constructing monodispersed MoSe2 anchored on graphene: a superior nanomaterial for sodium storage. Sci China Mater, 2017, 60: 167–177

    Article  Google Scholar 

  5. Zhang Q, Huang Y, Liu Y, et al. F-doped O3-NaNi1/3Fe1/3Mn1/3O2 as high-performance cathode materials for sodium-ion batteries. Sci China Mater, 2017, 60: 629–636

    Article  Google Scholar 

  6. Tao W, Xu ML, Zhu YR, et al. Structure and electrochemical performance of BaLi2−xNa x Ti6O14 (0≤x≤2) as anode materials for lithium-ion battery. Sci China Mater, 2017, 60: 728–738

    Article  Google Scholar 

  7. Fang Y, Yu XY, Lou XWD. A practical high-energy cathode for sodium-ion batteries based on uniform P2-Na0.7CoO2 microspheres. Angew Chem Int Ed, 2017, 56: 5801–5805

    Article  Google Scholar 

  8. Zhao Y, Goncharova LV, Zhang Q, et al. Inorganic–organic coating via molecular layer deposition enables long life sodium metal anode. Nano Lett, 2017, 17: 5653–5659

    Article  Google Scholar 

  9. Chen T, Liu Y, Pan L, et al. Electrospun carbon nanofibers as anode materials for sodium ion batteries with excellent cycle performance. J Mater Chem A, 2014, 2: 4117–4121

    Article  Google Scholar 

  10. Xiao L, Cao Y, Henderson WA, et al. Hard carbon nanoparticles as high-capacity, high-stability anodic materials for Na-ion batteries. Nano Energy, 2016, 19: 279–288

    Article  Google Scholar 

  11. Li Z, Bommier C, Chong ZS, et al. Mechanism of Na-ion storage in hard carbon anodes revealed by heteroatom doping. Adv Energy Mater, 2017, 7: 1602894

    Article  Google Scholar 

  12. Rahman MM, Glushenkov AM, Ramireddy T, et al. Electrochemical investigation of sodium reactivity with nanostructured Co3O4 for sodium-ion batteries. Chem Commun, 2014, 50: 5057–5060

    Article  Google Scholar 

  13. Chen J, Zhang Y, Zou G, et al. Size-tunable olive-like anatase TiO2 coated with carbon as superior anode for sodium-ion batteries. Small, 2016, 12: 5554–5563

    Article  Google Scholar 

  14. Tahir MN, Oschmann B, Buchholz D, et al. Extraordinary performance of carbon-coated anatase TiO2 as sodium-ion anode. Adv Energy Mater, 2016, 6: 1501489

    Article  Google Scholar 

  15. Zhang Y, Foster CW, Banks CE, et al. Graphene-rich wrapped petal-like rutile TiO2 tuned by carbon dots for high-performance sodium storage. Adv Mater, 2016, 28: 9391–9399

    Article  Google Scholar 

  16. Zou G, Chen J, Zhang Y, et al. Carbon-coated rutile titanium dioxide derived from titanium-metal organic framework with enhanced sodium storage behavior. J Power Sources, 2016, 325: 25–34

    Article  Google Scholar 

  17. Zhang W, Lan T, Ding T, et al. Carbon coated anatase TiO2 mesocrystals enabling ultrastable and robust sodium storage. J Power Sources, 2017, 359: 64–70

    Article  Google Scholar 

  18. Li S, Xie L, Hou H, et al. Alternating voltage induced ordered anatase TiO2 nanopores: An electrochemical investigation of sodium storage. J Power Sources, 2016, 336: 196–202

    Article  Google Scholar 

  19. Hong KJ, Kim SO. Atomic layer deposition assisted sacrificial template synthesis of mesoporous TiO2 electrode for high performance lithium ion battery anodes. Energy Storage Mater, 2016, 2: 27–34

    Article  Google Scholar 

  20. Cui Z, Li C, Yu P, et al. Reaction pathway and wiring network dependent Li/Na storage of micro-sized conversion anode with mesoporosity and metallic conductivity. J Mater Chem A, 2015, 3: 509–514

    Article  Google Scholar 

  21. Wu Y, Liu X, Yang Z, et al. Nitrogen-doped ordered mesoporous anatase TiO2 nanofibers as anode materials for high performance sodium-ion batteries. Small, 2016, 12: 3522–3529

    Article  Google Scholar 

  22. Wang N, Bai Z, Qian Y, et al. Double-walled Sb@TiO2−x nanotubes as a superior high-rate and ultralong-lifespan anode material for Na-ion and Li-ion batteries. Adv Mater, 2016, 28: 4126–4133

    Article  Google Scholar 

  23. Yan D, Yu C, Bai Y, et al. Sn-doped TiO2 nanotubes as superior anode materials for sodium ion batteries. Chem Commun, 2015, 51: 8261–8264

    Article  Google Scholar 

  24. Liao H, Xie L, Zhang Y, et al. Mo-doped gray anatase TiO2: lattice expansion for enhanced sodium storage. Electrochim Acta, 2016, 219: 227–234

    Article  Google Scholar 

  25. He H, Wang H, Sun D, et al. N-doped rutile TiO2/C with significantly enhanced Na storage capacity for Na-ion batteries. Electrochim Acta, 2017, 236: 43–52

    Article  Google Scholar 

  26. Kalubarme RS, Inamdar AI, Bhange DS, et al. Nickel-titanium oxide as a novel anode material for rechargeable sodium-ion batteries. J Mater Chem A, 2016, 4: 17419–17430

    Article  Google Scholar 

  27. Huang ZD, Zhang TT, Lu H, et al. Grain-boundary-rich mesoporous NiTiO3 micro-prism as high tap-density, super rate and long life anode for sodium and lithium ion batteries. Energy Storage Mater, 2017

    Google Scholar 

  28. Brown ZL, Smith S, Obrovac MN. Mixed transition metal titanate and vanadate negative electrode materials for Na-ion batteries. J Electrochem Soc, 2015, 162: A15–A20

    Article  Google Scholar 

  29. Guo S, Liu J, Qiu S, et al. Porous ternary TiO2/MnTiO3@C hybrid microspheres as anode materials with enhanced electrochemical performances. J Mater Chem A, 2015, 3: 23895–23904

    Article  Google Scholar 

  30. Bai X, Li T, Zhao XY, et al. Al2O3-modified Ti–Mn–O nanocomposite coated with nitrogen-doped carbon as anode material for high power lithium-ion battery. RSC Adv, 2016, 6: 40953–40961

    Article  Google Scholar 

  31. Lin YJ, Chang YH, Yang WD, et al. Synthesis and characterization of ilmenite NiTiO3 and CoTiO3 prepared by a modified Pechini method. J Non-Crystalline Solids, 2006, 352: 789–794

    Article  Google Scholar 

  32. Acharya T, Choudhary RNP. Structural, dielectric and impedance characteristics of CoTiO3. Mater Chem Phys, 2016, 177: 131–139

    Article  Google Scholar 

  33. Yilmaz G, Yam KM, Zhang C, et al. In situ transformation of MOFs into layered double hydroxide embedded metal sulfides for improved electrocatalytic and supercapacitive performance. Adv Mater, 2017, 29: 1606814

    Article  Google Scholar 

  34. Wu S, Zhu Y, Huo Y, et al. Bimetallic organic frameworks derived CuNi/carbon nanocomposites as efficient electrocatalysts for oxygen reduction reaction. Sci China Mater, 2017, 60: 654–663

    Article  Google Scholar 

  35. Zhou GW, Lee DK, Kim YH, Kim CW, Kang YS. Preparation and spectroscopic characterization of ilmenite-type CoTiO3 nanoparticles. Bull Korean Chem Soc, 2006, 27(3): 368–372

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (51402155 and 21373107), Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) (YX03002), Jiangsu National Synergistic Innovation Center for Advanced Materials (SICAM), Foundation of NJUPT (NY217077), PolyU Start-up Fund for New Recruits (No. 1-ZE8R).

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  1. These authors contributed equally to this work.

Authors and Affiliations

  1. Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, Nanjing, 210023, China

    Zhen-Dong Huang  (黄镇东), Ting-Ting Zhang  (张婷婷), Hao Lu  (陆昊), Jike Yang  (杨记可), Ling Bai  (柏玲), Yuehua Chen  (陈月花), Rui-Qing Liu  (刘瑞卿), Xiu-Jing Lin  (林秀婧), Yi Li  (李谊), Pan Li  (李盼), Xiao-Miao Feng  (冯晓苗) & Yan-Wen Ma  (马延文)

  2. Advanced Manufacturing Technology Research Centre, Department of Industrial and Systems Engineering, Hong Kong Polytechnic University, Hong Kong, China

    Xu-Sheng Yang  (杨许生)

  3. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471022, China

    Xianming Liu  (刘献明)

Authors
  1. Zhen-Dong Huang  (黄镇东)
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  3. Hao Lu  (陆昊)
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  5. Ling Bai  (柏玲)
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  6. Yuehua Chen  (陈月花)
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  9. Xiu-Jing Lin  (林秀婧)
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  10. Yi Li  (李谊)
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  11. Pan Li  (李盼)
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  12. Xianming Liu  (刘献明)
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  13. Xiao-Miao Feng  (冯晓苗)
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  14. Yan-Wen Ma  (马延文)
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Corresponding author

Correspondence to Yan-Wen Ma  (马延文).

Additional information

Zhen-Dong Huang received his PhD degree (2012) in mechanical engineering from Hong Kong University of Science and Technology (HKUST). He worked as a program-specific researcher at Kyoto University. He is currently an associate professor in the Institute of Advanced Materials at Nanjing University of Posts and Telecommunications. He keeps working on the development of high energy density nanostructured materials for various energy storage systems, such as lithium ion batteries, sodium ion batteries, magnesium batteries and supercapacitors.

Ting-Ting Zhang received her BE degree from Nanjing University of Posts & Telecommunications in 2015. Currently, she is pursuing her MS cdegree at Nanjing University of Posts & Telecommunications. Her research interest is the titanium-based nanostructure materials for compact energy storage.

Yanwen Ma received his PhD degree (2005) in physical chemistry from Nanjing University. He worked as a visiting scholar at Duke University. Now he is a professor in the Institute of Advanced Materials at Nanjing University of Posts & Telecommunications. He leads a research groups focusing on carbon-based nanomaterials for energy conversion and storage.

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Huang, ZD., Zhang, TT., Lu, H. et al. Bimetal-organic-framework derived CoTiO3 mesoporous micro-prisms anode for superior stable power sodium ion batteries. Sci. China Mater. 61, 1057–1066 (2018). https://doi.org/10.1007/s40843-017-9225-5

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