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From 1-d to 3-d Supramolecular Structures Derived from Diphenic Acid and Auxiliary Ligands

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Abstract

Four novel compounds [Co(Hdpa) 2(4,4′-bipy)2]n (1), {[Ni(dpa)(2,2′-bipy)(H2O)](H2O)}n, (2), [Ni(dpa)(im)3]n (3) and [Zn(dpa)(im)]n (4) [H2dpa = 2,4′-diphenyl-dicarboxylic acid, 4,4′-bipy = 4,4′-bipyridine, 2,2′-bipy = 2,2′-bipyridine and im = imidazole] were synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. X-ray crystallography shows that the 2,4′-diphenic acid exhibits three coordination modes to link the metal ions: μ 1 −η1: η1/μ 0 −η0: η0, μ 1−η 1: η 0/μ 2−η 1: η 1 and μ 1−η 1: η 0/μ 1−η 1: η 0. Compound 1 has a 1D supramolecular structure. Compounds 2 and 3 are 3D supramolecular structures. Compound 4 is a 2D supramolecular structure. All the compounds, 1–4, are self-assembled to form supramolecular structures through hydrogen bonding interactions.

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Acknowledgments

The authors gratefully acknowledge financial support from the National Natural Science Foundation of China (20971018).

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Authors and Affiliations

  1. Department of Chemistry, De zhou University, Shandong, 253023, People’s Republic of China

    Feng Guo, Xiuling Zhang & Baoyong Zhu

  2. Qingdao Institute of BioEnergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, People’s Republic of China

    Jianchao Qiu

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  1. Feng Guo
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  2. Xiuling Zhang
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Correspondence to Feng Guo.

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Guo, F., Zhang, X., Zhu, B. et al. From 1-d to 3-d Supramolecular Structures Derived from Diphenic Acid and Auxiliary Ligands. J Inorg Organomet Polym 20, 38–45 (2010). https://doi.org/10.1007/s10904-009-9313-5

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  • DOI: https://doi.org/10.1007/s10904-009-9313-5

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