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Synthesis and Characterization of a Novel Unsymmetrical Tetradentate Schiff Base Complex of Zinc(II) Derived from N,N′-bis (5-Bromosalicylidene) 2,3-Diaminopyridine (H2L): Crystal Structure of [Zn(II)L]Pyridine

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Abstract

Yellow crystals of [Zn(N,N′-bis (5-bromosalicylidene) 2,3-diaminopyridine)] Pyridine, [Zn(C19H11Br2N3O2)]C5H5N, have been obtained and characterized by elemental analysis, FT-IR, UV–Vis, 1H NMR spectroscopy and MALDI-TOF mass spectrometry. The structure has been determined by single crystal X-ray crystallography. The complex crystallizes in the triclinic space group P-1 with two molecules in the asymmetric unit and with unit cell dimensions a = 8.0103(3) Å, b = 12.8340(5) Å, c = 22.3682(11) Å, α = 91.715(2)°, β = 93.918(2)°, γ = 103.708(2)°. V = 2226.30(16) Å3, Z = 4, R 1 = 0.0780 and wR 2 = 0.1192. X-ray structure determination revealed that the complex consists of a [Zn(C19H11Br2N3O2)] moiety with a coordinated pyridine molecule on the metallic centre. The zinc atom adopts a distorted square pyramidal geometry as it is shown in the crystal structure.

Graphical Abstract

A single crystal description of a unsymmetrical structure, spectroscopic and characterization with 2D NMR ROESY spectrum

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Acknowledgments

The authors acknowledge gratefully Dr Lydia Brelot for the radiocrystallography facility—Institut de Chimie de Strasbourg, for single crystal X-ray.

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Authors and Affiliations

  1. Laboratoire d’Electrochimie, d’Ingénierie Moléculaire et de Catalyse Rédox (LEIMCR), Faculté des Sciences de l’Ingénieur, Université Ferhat Abbas, 19000, Sétif, Algeria

    Kamel Ouari & Ali Ourari

  2. Laboratoire de Chimie des Ligands à Architecture Contrôlée (CLAC), Institut de Chimie, UMR 7177 CNRS-ULP, BP 1032, 67070, Strasbourg, France

    Jean Weiss

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  1. Kamel Ouari
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  2. Ali Ourari
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Correspondence to Kamel Ouari.

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Ouari, K., Ourari, A. & Weiss, J. Synthesis and Characterization of a Novel Unsymmetrical Tetradentate Schiff Base Complex of Zinc(II) Derived from N,N′-bis (5-Bromosalicylidene) 2,3-Diaminopyridine (H2L): Crystal Structure of [Zn(II)L]Pyridine. J Chem Crystallogr 40, 831–836 (2010). https://doi.org/10.1007/s10870-010-9749-z

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