Active non-metal catalysts for the Oxygen Reduction Reaction (ORR) were prepared by decomposition of acetonitrile vapor at 900°C over a pure alumina support, and supports containing 2 wt% Fe or 2 wt% Ni on alumina. The exposed alumina and metal in the samples were subsequently washed away with HF acid to purify the solid carbon material. The sample prepared with iron was the most active sample for the ORR, with only 100 mV greater overpotential than a commercial 20 wt% Pt / Vulcan Carbon catalyst. However, nitrogen-containing carbon deposited on pure alumina (which contained less than 1 ppm metal contamination) was also quite active, demonstrating that platinum or iron is not required for ORR activity. Characterization by XPS and TEM revealed that the more active samples had nanostructured carbon with more edge plane exposure than the less active tube structures formed from the nickel sample.
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References
M. Lefevre J.-P. Dodelet (2003) Electrochimica Acta 48 2749–2760 Occurrence Handle1:CAS:528:DC%2BD3sXls1Sls7c%3D Occurrence Handle10.1016/S0013-4686(03)00393-1
M. Lefevre J.P. Dodelet P. Bertrand (2000) J. Phys. Chem. B 104 11238 Occurrence Handle1:CAS:528:DC%2BD3cXnsFykt78%3D Occurrence Handle10.1021/jp002444n
M. Lefevre J.P. Dodelet P. Bertrand (2002) J. Phys. Chem. B. 106 8705 Occurrence Handle1:CAS:528:DC%2BD38XlsFKmtrk%3D Occurrence Handle10.1021/jp020267f
S. Gupta D. Tryk I. Bae W. Aldred E. Yeager (1989) J. Appl. Electrochem. 19 19 Occurrence Handle1:CAS:528:DyaL1MXhvVWmsrg%3D Occurrence Handle10.1007/BF01039385
G. Faubert R. Cote D. Guay J.P. Dodelet G. Denes C. Poleunis P. Bertrand (1998) Electrochimica Acta 43 1969 Occurrence Handle1:CAS:528:DyaK1cXktVentrg%3D Occurrence Handle10.1016/S0013-4686(97)10120-7
R. Cote G. Lalande D. Guay J.P. Dodelet G. Denes (1998) J. Electrochem. Soc 145 2411 Occurrence Handle1:CAS:528:DyaK1cXksVWhtLw%3D
H. Wang, R. Cote, G. Faubert, D. Guay, J. P. Dodelet, J. Phys. Chem. B 103 (1999).
G. Lalande R. Cote D. Guay J.P. Dodelet L.T. Weng P. Bertrand (1997) Electrochimi. Acta 42 1379 Occurrence Handle1:CAS:528:DyaK2sXhvVGmtbg%3D Occurrence Handle10.1016/S0013-4686(96)00361-1
G. Faubert R. Côté J.P. Dodelet M. Lefèvre P. Bertrand (1999) Electrochimica Acta 44 2589 Occurrence Handle1:CAS:528:DyaK1MXhvFaitbo%3D Occurrence Handle10.1016/S0013-4686(98)00382-X
F. Jaouen S. Marcotte J.-P. Dodelet G. Lindbergh (2003) J. Phys. Chem. B 107 1376–1386 Occurrence Handle1:CAS:528:DC%2BD3sXksFKlsA%3D%3D Occurrence Handle10.1021/jp021634q
S. Ye A.K. Vijh (2003) Electrochem. Comm 5 272–275 Occurrence Handle1:CAS:528:DC%2BD3sXitVKrtLg%3D Occurrence Handle10.1016/S1388-2481(03)00043-2
P.H. Matter U.S. Ozkan L. Zhang (2006) J. Catal 239 83–96 Occurrence Handle1:CAS:528:DC%2BD28XitlehsbY%3D Occurrence Handle10.1016/j.jcat.2006.01.022
S. Gojkovic S. Gupta R. Savinell (1999) J. Electroanaly. Chem. 462 63–72 Occurrence Handle1:CAS:528:DyaK1MXhs1Slt7s%3D Occurrence Handle10.1016/S0022-0728(98)00390-8
P. Gouerec A. Biloul O. Contamin G. Scarbeck M. Savy J. Riga L.T. Weng P. Bertrand (1997) J. Electroanal. Chem 422 61 Occurrence Handle1:CAS:528:DyaK2sXivV2ltrY%3D Occurrence Handle10.1016/S0022-0728(96)04895-4
K. Wiesner (1986) Electrochimica Acta 31 1073–1078 Occurrence Handle10.1016/0013-4686(86)80022-6
S. Maldonado K.J. Stevenson (2004) J. Phys. Chem. B 108 11375–11383 Occurrence Handle1:CAS:528:DC%2BD2cXlsVyrt74%3D Occurrence Handle10.1021/jp0496553
S. Maldonado K.J. Stevenson (2005) J. Phys. Chem. B 109 4707–4716 Occurrence Handle1:CAS:528:DC%2BD2MXhsVals7g%3D Occurrence Handle10.1021/jp044442z
G. Faubert R. Cote D. Guay J.P. Dodlet G. Denes P. Bertrand (1998) Electrochimica Acta 43 341 Occurrence Handle1:CAS:528:DyaK1cXhslCgsw%3D%3D Occurrence Handle10.1016/S0013-4686(97)00087-X
R.T.K. Baker (1989) Carbon 27 315–323 Occurrence Handle1:CAS:528:DyaL1MXkvF2kt7w%3D Occurrence Handle10.1016/0008-6223(89)90062-6
N.M. Rodriguez (1993) J. Mater. Res 8 3233–3250 Occurrence Handle1:CAS:528:DyaK2cXmtVGjtw%3D%3D
N.M. Rodriguez A. Chambers R.T.K. Baker (1995) Langmuir 11 3862–3866 Occurrence Handle1:CAS:528:DyaK2MXotlGqtLc%3D Occurrence Handle10.1021/la00010a042
C. Park M.A. Keane (2004) J. Catal 221 386–399 Occurrence Handle1:CAS:528:DC%2BD2cXnsVynuw%3D%3D Occurrence Handle10.1016/j.jcat.2003.08.014
A.-C. Dupuis (2005) Prog. in Mater. Sci. 50 929–961 Occurrence Handle1:CAS:528:DC%2BD2MXntFGnt7c%3D Occurrence Handle10.1016/j.pmatsci.2005.04.003
R.T.K. Baker M.S. Kim A. Chambers C. Park N.M. Rodriguez (1997) Stud. in Surf. Sci. and Catal. 111 99–109 Occurrence Handle1:CAS:528:DyaK1cXjslCisrc%3D Occurrence Handle10.1016/S0167-2991(97)80144-9
T. Nakajima M. Koh (1997) Carbon 35 203 Occurrence Handle1:CAS:528:DyaK2sXhsVKgsLg%3D Occurrence Handle10.1016/S0008-6223(96)00143-1
R. Kvon G. Il’inich A. Chuvilin V. Likholobov (2000) J. Mol. Catal. A: Chem. 158 413 Occurrence Handle1:CAS:528:DC%2BD3cXkvFyks7c%3D Occurrence Handle10.1016/S1381-1169(00)00115-1
H.M. Liao R.N.S. Sodhi T.W. Coyle (1993) J. Vac. Sci. Technol. A 11 2681–2686 Occurrence Handle1:CAS:528:DyaK2cXhtlequw%3D%3D Occurrence Handle10.1116/1.578626
J.R. Pels F. Kapteijn J.A. Moulijn Q. Zhu K.M. Thomas (1995) Carbon 33 1641–1653 Occurrence Handle1:CAS:528:DyaK2MXpslaqu7w%3D Occurrence Handle10.1016/0008-6223(95)00154-6
J. Casanovas J.M. Ricart J. Rubio F. Illas J.M. Jimenez-Mateos (1996) J. Am. Chem. Soc 118 8071–8076 Occurrence Handle1:CAS:528:DyaK28Xksl2gu70%3D Occurrence Handle10.1021/ja960338m
K. Kinoshita (1988) Carbon, Electrochemical and Physiochemical Properties Wiley Interscience New York
P. Chen M.A. Fryling R.L. McCreery (1995) Analy. Chem. 67 3115–3112 Occurrence Handle1:CAS:528:DyaK2MXnsVKqtrw%3D Occurrence Handle10.1021/ac00114a004
H.H. Yang R.L. McCreery (2000) J. Electrochem. Soc. 147 3420 Occurrence Handle1:CAS:528:DC%2BD3cXmsVKrtrk%3D Occurrence Handle10.1149/1.1393915
S. Trasobares O. Stephan C. Colliex W.K. Hsu H.W. Kroto D.R.M. Walton (2002) J. Chem. Phys. 116 8966–8972 Occurrence Handle1:CAS:528:DC%2BD38XjsFKms70%3D Occurrence Handle10.1063/1.1473195
X.-L. Xie Y.-W. Mai X.-P. Zhou (2005) Mat. Sci. Eng., R: Reports R49 89–112 Occurrence Handle1:CAS:528:DC%2BD2MXmtFShs7Y%3D Occurrence Handle10.1016/j.mser.2005.04.002
M. Audier M. Coulon (1985) Carbon 23 317–323 Occurrence Handle1:CAS:528:DyaL2MXkt1Oqt7s%3D Occurrence Handle10.1016/0008-6223(85)90117-4
A.J.H.M. Kock P.K. Boxx Particlede E. Boellaard W. Klop J.W. Geus (1985) J. Catal 96 468–480 Occurrence Handle1:CAS:528:DyaL28XktVGgsg%3D%3D Occurrence Handle10.1016/0021-9517(85)90315-X
I. Alstrup (1988) J. Catal 109 241–251 Occurrence Handle1:CAS:528:DyaL1cXhsFOjtbw%3D Occurrence Handle10.1016/0021-9517(88)90207-2
A.J. Bard L.R. Faulkner (2001) Electrochemical Methods: Fundamentals and Applications John Wiley and Sons Ltd NY
K.K. Cline M.T. McDermott R.L. McCreery (1994) J. Phys. Chem 98 5314–5319 Occurrence Handle1:CAS:528:DyaK2cXivVaqtrg%3D Occurrence Handle10.1021/j100071a023
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Matter, P.H., Ozkan, U.S. Non-metal Catalysts for Dioxygen Reduction in an Acidic Electrolyte. Catal Lett 109, 115–123 (2006). https://doi.org/10.1007/s10562-006-0067-1
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DOI: https://doi.org/10.1007/s10562-006-0067-1