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Preparation of the carboxylic acid-functionalized graphene oxide/gold nanoparticles/5-amino-2-hydroxybenzoic acid as a novel electrochemical sensing platform

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Abstract

The carboxylic acid-functionalized graphene oxide/gold nanoparticles modified glassy carbon electrode has been utilized as a platform to immobilize 5-amino-2-hydroxybenzoic acid (mesalazine). The su rface structure and composition of the sensor were characterized by scanning electron microscopy. Electrocatalytic oxidation of urea on the surface of modified electrode was investigated with cyclic voltammetry, electrochemical impedance spectroscopy, and hydrodynamic voltammetry methods. The cyclic voltammetric results indicated the ability of carboxylic acid-functionalized graphene oxide gold nanoparticles modified glassy carbon electrode to catalyze the oxidation of urea. In addition, the modified electrode has short response time, low detection limit, high sensitivity, and low operation potential. Some kinetic parameters, such as the electron transfer coefficient, diffusion coefficient, and catalytic rate constant of the catalytic reaction were calculated. A sensitive amperometric method was proposed for determination of urea with advantages of fast response and good reproducibility.

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Acknowledgments

The authors gratefully acknowledge the support of this work by the Khorramabad Branch, Islamic Azad University for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Islamic Azad University, Khorramabad Branch, Khorramabad, Iran

    Azadeh Azadbakht, Amir Reza Abbasi, Zohreh Derikvand & Ziba Karimi

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  1. Azadeh Azadbakht
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  2. Amir Reza Abbasi
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  3. Zohreh Derikvand
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  4. Ziba Karimi
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Correspondence to Azadeh Azadbakht.

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Azadbakht, A., Abbasi, A.R., Derikvand, Z. et al. Preparation of the carboxylic acid-functionalized graphene oxide/gold nanoparticles/5-amino-2-hydroxybenzoic acid as a novel electrochemical sensing platform. Monatsh Chem 147, 705–717 (2016). https://doi.org/10.1007/s00706-015-1527-3

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  • DOI: https://doi.org/10.1007/s00706-015-1527-3

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