Skip to main content
Log in

Minimality via Second Variation for a Nonlocal Isoperimetric Problem

  • Published:
Communications in Mathematical Physics Aims and scope Submit manuscript

Abstract

We discuss the local minimality of certain configurations for a nonlocal isoperimetric problem used to model microphase separation in diblock copolymer melts. We show that critical configurations with positive second variation are local minimizers of the nonlocal area functional and, in fact, satisfy a quantitative isoperimetric inequality with respect to sets that are L 1-close. The link with local minimizers for the diffuse-interface Ohta-Kawasaki energy is also discussed. As a byproduct of the quantitative estimate, we get new results concerning periodic local minimizers of the area functional and a proof, via second variation, of the sharp quantitative isoperimetric inequality in the standard Euclidean case. As a further application, we address the global and local minimality of certain lamellar configurations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Adams, R.A., Fournier, J.F.: Sobolev Spaces (second edition) Pure and Applied Mathematics, 140. Amsterdam: Elsevier/Academic Press, 2003

  2. Alberti G., Choksi R., Otto F.: Uniform energy distribution for an isoperimetric problem with long-range interactions. J. Amer. Math. Soc. 22, 569–605 (2009)

    Article  MathSciNet  MATH  Google Scholar 

  3. Almgren, F.J. Jr.: Existence and regularity almost everywhere of solutions to elliptic variational problems with constraints. Mem. Amer. Math. Soc. 4, Providence, RI: Amer. Math. Soc., 1976

  4. Ambrosio, L., Fusco, N., Pallara, D.: Functions of bounded variation and free discontinuity problems. Oxford Mathematical Monographs. New York: The Clarendon Press, Oxford University Press, 2000

  5. Cagnetti F., Mora M.G., Morini M.: A second order minimality condition for the Mumford-Shah functional. Calc. Var. Part. Diff. Eqs. 33, 37–74 (2008)

    Article  MathSciNet  MATH  Google Scholar 

  6. Choksi R., Peletier M.A.: Small volume fraction limit of the diblock copolymer problem: I. Sharp-interface functional. SIAM J. Math. Anal. 42, 1334–1370 (2010)

    Article  MathSciNet  MATH  Google Scholar 

  7. Choksi R., Peletier M.A., Williams J.F.: On the phase diagram for microphase separation of diblock copolymers: an approach via a nonlocal Cahn-Hilliard functional. SIAM J. Appl. Math. 69, 1712–1738 (2009)

    Article  MathSciNet  MATH  Google Scholar 

  8. Choksi R., Sternberg P.: Periodic phase separation: the periodic Cahn-Hilliard and isoperimetric problems. Interfaces Free Bound. 8, 371–392 (2006)

    Article  MathSciNet  MATH  Google Scholar 

  9. Choksi R., Sternberg P.: On the first and second variations of a nonlocal isoperimetric problem. J. Reine angew. Math. 611, 75–108 (2007)

    MathSciNet  MATH  Google Scholar 

  10. Cicalese, M., Leonardi, G.: A selection principle for the sharp quantitative isoperimetric inequality. Arch. Ration. Mech. Anal. 206, 617–643 (2012)

    Google Scholar 

  11. Cicalese, M., Spadaro, E.: Droplet Minimizers of an Isoperimetric Problem with long-range interactions. Preprint, 2011, available at http://arxiv.org/abs/1110.0031v1 [math.AP], 2011

  12. Dal Maso, G.: An Introduction to Γ-Convergence, Basel Buston: Birkhaüser, 1993

  13. Esposito L., Fusco N.: A remark on a free interface problem with volume constraint. J. Convex Anal. 18, 417–426 (2011)

    MathSciNet  MATH  Google Scholar 

  14. Figalli A., Maggi F., Pratelli A.: A mass transportation approach to quantitative isoperimetric inequalities. Invent. Math. 182, 167–211 (2010)

    Article  MathSciNet  ADS  MATH  Google Scholar 

  15. Fusco N., Maggi F., Pratelli A.: The sharp quantitative isoperimetric inequality. Ann. of Math. 168, 941–980 (2008)

    Article  MathSciNet  MATH  Google Scholar 

  16. Fusco N., Morini M.: Equilibrium configurations of epitaxially strained elastic films: second order minimality conditions and qualitative properties of solutions. Arch. Rat. Mech. Anal. 203, 247–327 (2012)

    Article  MathSciNet  MATH  Google Scholar 

  17. van Gennip Y., Peletier M.A.: Stability of monolayers and bilayers in a copolymer-homopolymer blend model. Interfaces Free Bound. 11, 331–373 (2009)

    Article  MathSciNet  MATH  Google Scholar 

  18. Goldman, D., Muratov, C.B., Serfaty, S.: The Γ-limit of the two-dimensional Ohta-Kawasaki energy. I. Droplet density. Preprint, 2012, available at http://arxiv.org/abs/1201.0222v1 [math.ph], 2012

  19. Goldman, D., Muratov, C.B., Serfaty, S.: The Γ-limit of the two-dimensional Ohta-Kawasaki energy. II. Droplet arrangement via the renormalized energy. Preprint, 2012, available at http://arxiv.org/abs/1210.5098v1 [math.AP], 2012

  20. Grosse-Brauckmann K.: Stable constant mean curvature surfaces minimize area. Pacific. J. Math. 175, 527–534 (1996)

    MathSciNet  MATH  Google Scholar 

  21. Hadwiger H.: Gitterperiodische Punktmengen und Isoperimetrie. Monatsh. Math. 76, 410–418 (1972)

    Article  MathSciNet  MATH  Google Scholar 

  22. Howards H., Hutchings M., Morgan F.: The isoperimetric problem on surfaces. Amer. Math. Monthly 106, 430–439 (1999)

    Article  MathSciNet  MATH  Google Scholar 

  23. Knüpfer, H., Muratov, C.B.: On an isoperimetric problem with a competing non-local term. I. The planar case. Preprint, 2011

  24. Knüpfer, H., Muratov, C.B.: On an isoperimetric problem with a competing non-local term. II. The general case. Preprint, 2012.

  25. Kohn R.V., Sternberg P.: Local minimisers and singular perturbations. Proc. Roy. Soc. Edinburgh Sect. A 111, 69–84 (1989)

    Article  MathSciNet  MATH  Google Scholar 

  26. Modica L.: The gradient theory of phase transitions and minimal interface criterion. Arch. Rat. Mech. Anal. 98, 123–142 (1987)

    Article  MathSciNet  MATH  Google Scholar 

  27. Morgan F., Ros A.: Stable constant-mean-curvature hypersurfaces are area minimizing in small L 1 neighbourhoods. Interfaces Free Bound. 12, 151–155 (2010)

    Article  MathSciNet  MATH  Google Scholar 

  28. Morini, M., Sternberg, P.: Work in progress

  29. Müller S.: Singular perturbations as a selection criterion for periodic minimizing sequences. Calc. Var. Part. Diff. Eq. 1, 169–204 (1993)

    Article  MATH  Google Scholar 

  30. Muratov C.B.: Theory of domain patterns in systems with long-range interactions of Coulomb type. Phys. Rev. E 66, 066108 (2002)

    Article  MathSciNet  ADS  Google Scholar 

  31. Muratov C.B.: Droplet phases in non-local Ginzburg-Landau models with Coulomb repulsion in two dimensions. Commun. Math. Phys. 299, 45–87 (2010)

    Article  MathSciNet  ADS  MATH  Google Scholar 

  32. Muratov C.B., Osipov V.V.: General theory of instabilities for patterns with sharp interfaces in reaction-diffusion systems. Phys. Rev. E 53, 3101–3116 (1996)

    Article  MathSciNet  ADS  Google Scholar 

  33. Ohta T., Kawasaki K.: Equilibrium morphology of block copolymer melts. Macromolecules 19, 2621–2632 (1986)

    Article  ADS  Google Scholar 

  34. Ren X., Wei J.: Concentrically layered energy equilibria of the di-block copolymer problem. Eur. J. Appl. Math. 13, 479–496 (2002)

    Article  MathSciNet  MATH  Google Scholar 

  35. Ren X., Wei J.: On energy minimizers of the diblock copolymer problem. Interfaces Free Bound. 5, 193–238 (2003)

    Article  MathSciNet  MATH  Google Scholar 

  36. Ren X., Wei J.: Stability of spot and ring solutions of the diblock copolymer equation. J. Math. Phys. 45, 4106–4133 (2004)

    Article  MathSciNet  ADS  MATH  Google Scholar 

  37. Ren X., Wei J.: Wriggled lamellar solutions and their stability in the diblock copolymer problem. SIAM J. Math. Anal. 37, 455–489 (2005)

    Article  MathSciNet  MATH  Google Scholar 

  38. Ren X., Wei J.: Many droplet pattern in the cylindrical phase of diblock copolymer morphology. Rev. Math. Phys. 19, 879–921 (2007)

    Article  MathSciNet  MATH  Google Scholar 

  39. Ren X., Wei J.: Spherical solutions to a nonlocal free boundary problem from diblock copolymer morphology. SIAM J. Math. Anal. 39, 1497–1535 (2008)

    Article  MathSciNet  MATH  Google Scholar 

  40. Ross M.: Schwartz’ P and D surfaces are stable. Diff. Geom. Appl. 2, 179–195 (1992)

    Article  MATH  Google Scholar 

  41. Schoen R., Simon L.M.: A new proof of the regularity theorem for rectifiable currents which minimize parametric elliptic functionals. Indiana Univ. Math. J. 31, 415–434 (1982)

    Article  MathSciNet  MATH  Google Scholar 

  42. Simon, L.M.: Lectures on geometric measure theory. In: Proceedings of the Centre for Mathematical Analysis, Australian National University, 3, Canberra: Aust. Nat. Univ., 1983

  43. Spadaro E.N.: Uniform energy and density distribution: diblock copolymers’ functional. Interfaces Free Bound. 11, 447–474 (2009)

    Article  MathSciNet  MATH  Google Scholar 

  44. Sternberg P., Topaloglu I.: On the global minimizers of a nonlocal isoperimetric problem in two dimensions. Interfaces Free Bound. 13, 155–169 (2011)

    Article  MathSciNet  MATH  Google Scholar 

  45. Tamanini I.: Boundaries of Caccioppoli sets with Hölder-continuous normal vector. J. Reine Angew. Math. 334, 27–39 (1982)

    MathSciNet  MATH  Google Scholar 

  46. Tamanini I.: Regularity results for almost minimal oriented hypersurfaces in \({\mathbb{R}^n}\) . Quaderni del Dipartimento di Matematica dell Università di Lecce 1, 1–92 (1984)

    Google Scholar 

  47. Thomas E.L., Anderson D.M., Henkee C.S., Hoffman D.: Periodic area-minimizing surfaces in block copolymers. Nature 334, 598–601 (1988)

    Article  ADS  Google Scholar 

  48. Topaloglu I.: On a nonlocal isoperimetric problem on the two-sphere. Comm. Pure Appl. Anal. 12, 597–620 (2013)

    Article  MathSciNet  MATH  Google Scholar 

  49. White B.: A strong minimax property of nondegenerate minimal submanifolds. J. Reine Angew. Math. 457, 203–218 (1994)

    MathSciNet  MATH  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. Fusco.

Additional information

Communicated by P. Constantin

Dedicated to Sergio Spagnolo on his 70th birthday

Rights and permissions

Reprints and permissions

About this article

Cite this article

Acerbi, E., Fusco, N. & Morini, M. Minimality via Second Variation for a Nonlocal Isoperimetric Problem. Commun. Math. Phys. 322, 515–557 (2013). https://doi.org/10.1007/s00220-013-1733-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00220-013-1733-y

Keywords

Navigation