Skip to main content
SpringerLink
Log in

Magnetic properties of one-dimensional charge transfer conductors: Pressure effects

  • V. Experimental Investigations on TTF-TCNQ and its Derivatives
  • Conference paper
  • First Online:
Organic Conductors and Semiconductors

Part of the book series: Lecture Notes in Physics ((LNP,volume 65))

Abstract

We report a systematic investigation under pressure of spin susceptibility, nuclear relaxation rate and temperature dependence of the resistivity in the charge transfer salts TTF-TCNQ, TMTTF-TCNQ and HMTSF-TCNQ. The very large pressure dependences observed in the TTF-TCNQ family, which cannot be explained solely by the band broadening point to the picture of a magnetism governed by the properties of a one dimensional strongly correlated electron gas. An interpretation of our data in terms of the Hubbard model for one dimensional itinerant magnetism provides an estimation of the ratio electron-electron repulsion to band width U/4t ≈ 1 in TTF-TCNQ at ambient pressure. The effects of correlations tend to become weaker for the selenium compounds, in particular for HMTSF-TCNQ, or as pressure is applied to the TTF-TCNQ family.

It is suggested that pressure enhances the screening of electron-electron repulsion via the excitonic mechanism.

This work is part of a more general study of the electronic properties of one-dimensional conductors, supported partly by a CNRS ATP no. A206 and partly by a DGRST Contract no. 75-7-0820.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. D. Jérome and M. Weger, see review article in the Proceedings of the Summer School 1976 on One dimensional conductors, H. E. Keller Editor, Plenum Press, New York 1977.

    Google Scholar 

  2. D. Jérome, W. Müller and M. Weger, J. Physique Lett. 35, L–77 /1974/.

    Google Scholar 

  3. J. R. Cooper, D. Jérome, M. Weger and S. Etemad, J.Physique Lett. 36, L–219 /1975/.

    Google Scholar 

  4. J. R. Cooper, D. Jérome, E. Etemad and E. M. Engler, /to be published/.

    Google Scholar 

  5. M. Thielemans, R. Deltour, D. Jérome and J. R. Cooper, Solid State Comm. 19, 21 /1976/.

    Google Scholar 

  6. G. Soda, D. Jérome, M. Weger, Communication at the Conference on One dimensional conductors, Siófok, 1976; also to be published.

    Google Scholar 

  7. W. H. G. Müller and D. Jérome, J-Physique Lett. 35, L–103 /1976/.

    Google Scholar 

  8. W. H. Müller, H. Niedoba and D. Jérome, Solid State Comm. 16, 655 /1975/.

    Google Scholar 

  9. B. Horovitz, H. Gutfreund, M. Weger, Phys. Rev. B12, 3174 /1975/.

    Google Scholar 

  10. J. R. Cooper, M. Weger, D. Jérome, D. Lefur, K. Bechgaard, A. N. Bloch and D. O. Cowan, Solid State Comm. 19, 749 /1976/.

    Google Scholar 

  11. R. Peierls, Quantum Theory of Solids, Oxford University Press, 1955.

    Google Scholar 

  12. A. J. Epstein, S. Etemad, A. F. Garito and A.J. Heeger, Solid State Comm. 9, 1803 /1971/.

    Google Scholar 

  13. E. F. Rybaczewski, A. F. Garito, A. J. Heeger and E. Ehrenfreund, Phys. Rev. Lett. 34, 524 /1975/.

    Google Scholar 

  14. E. F. Rybaczewski-L. S. Smith, A. F. Garito, A. J. Heeger and B. G. Silbernagel, Phys. Rev. /B/ /to be published/.

    Google Scholar 

  15. A. N. Bloch, D. O. Cowan, K. Bechgaard, R. E. Pyle, R. H. Banks and T. O. Poehler, Phys. Rev. Lett. 34, 1561 /1975/.

    Google Scholar 

  16. J. P. Ferraris, T. O. Poehler, A. N. Bloch and D. O. Cowan, Tetrahedron Lett. 27, 2553 /1973/.

    Google Scholar 

  17. D. W. Hone and P. M. Richards, Ann. Rev. Materials Sci. 4, 337 /1974/.

    Google Scholar 

  18. D. Hone, C. Scherer and F. Borsa, Phys. Rev. B9, 965 /1975/.

    Google Scholar 

  19. J. Villain, J. Physique Lett. 36, L–173 /1975/.

    Google Scholar 

  20. F. Devreux, Phys. Rev. B13, 4651 /1976/.

    Google Scholar 

  21. F. Devreux and M. Nechtschein, Solid State Comm. 16, 275 /1975/.

    Google Scholar 

  22. A. Abragam, Nuclear Magnetism, Clarendon Press, Oxford 1961, p. 264.

    Google Scholar 

  23. G. Soda, D. Jérome, M. Weger, J. M. Fabre and L. Giral, Solid State Comm. 18, 1417 /1976/.

    Google Scholar 

  24. J. Gallice, J. P. Blanc, H. Robert, J. Alizon, private communication, Laboratoire d'Electronique, Université de Clermont-Ferrand; also report at Conference on One dimensional conductors, Siófok, 1976.

    Google Scholar 

  25. G. Soda, D. Jérome, M. Weger, K. Bechgaard and E,. Pedersen, Solid State Comm. /in press/.

    Google Scholar 

  26. J. Winter, Nuclear Magnetic Resonance in Metals, Clarendon Press 1971.

    Google Scholar 

  27. The preparation of TTF-TCNQ and TMTTF-TCNQ is the matter of a report P. Calas, J.M. Fabre, M. Khalife-El-Saleh, A. Mas, E. Torreilles, L. Giral, C. R. Acad. Sci. 1975, 2810, 1037 and 901

    Google Scholar 

  28. A. J. Berlinsky, J. F. Carolan, L. Weiler, Solid State Comm. 15, 795 /1974/.

    Google Scholar 

  29. A. A. Bright, A. F. Garito and A. J. Heeger, Phys. Rev. B10, 1328 /1974/.

    Google Scholar 

  30. A. J. Heeger and A. F. Garito, in Low Dimensional Cooperative Phenomena, ed. H. J. Keller, Plenum Press, New York, 1975.

    Google Scholar 

  31. F. Denoyer, R. Comés, A. F. Garito and A. J. Heeger, Phys. Rev. Lett. 35, 445 /1975/.

    Google Scholar 

  32. J. Gallice, J. Alizon, J. P. Blanc, H. Robert and G. Berthet, Université de Clermont-Ferrand, Private communication; also to be published.

    Google Scholar 

  33. S. K. Khanna, E. Ehrenfreund, A. F. Garito and A. J. Heeger, Phys. Rev. B10, 2205 /1974/.

    Google Scholar 

  34. H. Niedoba, H. Launois, D. Brinkmann and H. U. Keller, J. Physique Lett. 35, L–157 /1974/.

    Google Scholar 

  35. H. Launois and H. Niedoba, in Low Dimensional Cooperative Phenomena, ed. H. J. Keller, Plenum Press, New York, 1975.

    Google Scholar 

  36. P. A. Lee, T. M. Rice and P. W. Anderson, Phys. Rev. Lett. 31, 462 /1973/.

    Google Scholar 

  37. A. Bjelis and S. Barišić, J. Physique 36, L–169 /1975/.

    Google Scholar 

  38. C. Berthier, D. Jérome, G. Soda, C. Weyl, L. Zuppiroli, J. M. Fabre and L. Giral, Mol. Cryst. Liq. Cryst. 32, 261 /1976/.

    Google Scholar 

  39. C. Berthier, J. R. Cooper, D. Jérome, D. Soda, C. Weyl, J. M. Fabre and L. Giral, Mol. Cryst. Liq. Cryst. 32, 267 /1976/.

    Google Scholar 

  40. D. Jérome and J. R. Cooper, /to be published/.

    Google Scholar 

  41. K. Holczer, /personal communication/.

    Google Scholar 

  42. R. Comés, S. M. Shapiro, G. Shirane, A. G. Farito and A. J. Heeger, Phys. Rev. Lett. 35, 1518 /1975/; H. A. Mook and C. R. Watson, Phys. Rev. Lett. 801 /1976/.

    Google Scholar 

  43. B. Welber, E. M. Engler, P. M. Grant and P. E. Seiden, Bull. Am. Phys. Soc. 35, 311 /1976/.

    Google Scholar 

  44. J. Ferraris, D. O. Cowan, V. Walatka, J. H. Perlstein, J. Am. Chem. Soc. 95, 948 /1973/

    Google Scholar 

  45. R. P. Groff, A. Suna, R. E. Merrifield, Phys. Rev. Lett. 33, 418 /1974/.

    Google Scholar 

  46. S. Etemad, T. Penney, E. M. Engler, B. A. Scott, P. E. Seiden, Phys. Rev. Lett. 34, 741 /1975/.

    Google Scholar 

  47. S. Etemad, /personal communication/.

    Google Scholar 

  48. J. C. Scott, A. F. Garito and A. J. Heeger, Phys. Rev. B10, 3131, /1974/.

    Google Scholar 

  49. C. Weyl, E. M. Engler, K. Bechgaard, G. Jehanno and S. Etemad, Solid State Comm. 19, 925 /1976/.

    Google Scholar 

  50. P. E. Seiden, G. Cabib, Phys. Rev. B13, 1846 /1976/.

    Google Scholar 

  51. M. Weger, Solid State Comm. 19, 1149 /1976/.

    Google Scholar 

  52. J. R. Cooper, M. Weger, G. Delplanque, D. Jérome and K. Bechgaard, J. Physique Lett. /to be published/

    Google Scholar 

  53. J. C. Bonner and M. E. Fisher, Phys. Rev. 135, A640, /1964/.

    Google Scholar 

  54. J. P. Pouget, H. Launois, T. M. Rice, P. Dernier, A. Gossard, G. Villeneuve and P. Hagenmuller, Phys. Rev. B10, 1801 /1974/.

    Google Scholar 

  55. H. Shiba and P. A. Pincus, Phys. Rev. B5, 1966 /1972/.

    Google Scholar 

  56. H. Shiba, Phys. Rev. B6, 930 /1972/.

    Google Scholar 

  57. Y. Tomkiewicz, B. A. Scott, L. J. Tao and R. S. Title, Phys. Rev. Lett. 32, 1363 /1974/.

    Google Scholar 

  58. Y. Tomkiewicz, A. R. Taranko and J. B. Torrance, Phys. Rev. Lett. 36, 751 /1976/.

    Google Scholar 

  59. A. J. Epstein, S. Etemad, A. F. Garito and A. J. Heeger, Phys. Rev. B5, 952 /1972/.

    Google Scholar 

  60. T. E. Phillips, T. J. Kistenmacher, A. N. Bloch and D. O. Cowan, JCS Chem. Comm. 334/1976

    Google Scholar 

  61. O. H. LeBlanc, J. Chem. Phys. 42, 4307 /1965/.

    Google Scholar 

  62. P. M. Chaikin, A. F. Garito and A. J. Heeger, J. Chem. Phys. 58, 2336 /1973/.

    Google Scholar 

  63. A. F. Garito and A. J. Heeger, Acc. Chem. Research. 7, 232 /1974/.

    Google Scholar 

  64. D. E. Schafer, G. A. Thomas and F. Wudt, Phys. Rev. B12, 5532 /1975/.

    Google Scholar 

  65. P. G. de Gennes and J. Friedel, J. Phys. Chem. Solids 4, 71 /1958/.

    Google Scholar 

  66. D. L. Mills and P. Lederer, J. Phys. Chem. Solids 27, 1805 /1966/.

    Google Scholar 

  67. R. Jullien, M. T. Béal-Monod and B. Coqblin, Phys. Rev. B9, 1441 /1974/.

    Google Scholar 

  68. Y. Tomkiewicz, E. M. Engler and T. D. Schultz, Phys.Rev. Lett. 35, 456 /1975/.

    Google Scholar 

  69. J. B. Torrance, B. A. Scott and F. B. Kaufman, Solid State Comm. 17, 1369 /1975/.

    Google Scholar 

  70. P. M. Richards in Low Dimensional Cooperative Phenomna, ed. H. J. Keller, Plenum Press, New York 1975.

    Google Scholar 

  71. P. A. Pincus in Low Dimensional Cooperative Phenomena, ed. H. J. Keller, Plenum Press, New York 1975.

    Google Scholar 

  72. I. F. Shchegolev, Phys. Stat. Sol. /a/ 12, 9 /1972/.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Physique des Solides, Université Paris-Sud, 91405, Orsay, France

    D. Jérome

  2. Laboratoire de Chimie Organique Structurale, USTL, 34060, Montpellier, France

    L. Giral

Authors
  1. D. Jérome
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. Giral
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

L. Pál G. Grüner A. Jánossy J. Sólyom

Rights and permissions

Reprints and permissions

Copyright information

© 1977 Akadémiai Kiadó

About this paper

Cite this paper

Jérome, D., Giral, L. (1977). Magnetic properties of one-dimensional charge transfer conductors: Pressure effects. In: Pál, L., Grüner, G., Jánossy, A., Sólyom, J. (eds) Organic Conductors and Semiconductors. Lecture Notes in Physics, vol 65. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0012392

Download citation

  • DOI: https://doi.org/10.1007/BFb0012392

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-08255-2

  • Online ISBN: 978-3-540-37342-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation