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Kinetics of the homogeneous oxidation of hydrogen by platinum(II) and platinum(IV) chloro complexes in aqueous solution

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Abstract

The kinetics of the homogeneous oxidation of hydrogen in the Pt(II)−Pt(IV)−Cl−−H2O system has been studied for the first time in conditions permitting to avoid the formation of Pt-black. It is shown that platinum (II) [Pt(II)Cli(H2O)4-i, where i=1, 2, 2], is active in the reaction, whereas the PtCl 2−4 complex and platinum(IV) do not react with hydrogen.

Abstract

В условиях, позволяющнх избежать образование Pt-черни, впервые изучена кинетика гомогенного окисления H2 в системе PtII−PtIV−Cl−−H2O. В реакции активна платина(II) (PtIICli(H2O)4-i, где i=1, 2, 3); комплекс PtCl 2−4 и платина(IV) не реагируют с водородом.

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References

  1. B. James: Homogeneous Hydrogenation. Mir, Moskva 1976.

    Google Scholar 

  2. E. S. Rudakov, A. P. Yaroshenko, V. V. Zamashchikov: React. Kinet. Catal. Lett.,11, 183 (1979).

    Google Scholar 

  3. E. S. Rudakov, A. P. Yaroshenko, V. V. Zamashchikov: React. Kinet. Catal. Lett.,17, 7 (1981).

    Google Scholar 

  4. V. P. Tretyakov, E. S. Rudakov: Metal Complex Catalysis, p. 63. Naukova Dumka, Kiev 1977.

    Google Scholar 

  5. N. F. Goldshleger, M. B. Tyabin, A. E. Shilov, A. A. Shteinman: Zh. Fiz. Khim.,43, 2174 (1969).

    Google Scholar 

  6. D. V. Sokolskii, S. S. Segizbaeva, Ya. A. Dorfman: Z. Org. Khim.,6, 893 (1970).

    Google Scholar 

  7. V. A. Golodov, A. B. Fasman, D. V. Sokolskii: Z. Vses. Khim. Ob-va,9, 351 (1964).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Physical Organic and Carbon Chemistry, Donetsk, USSR

    V. V. Zamashchikov, E. S. Rudakov & A. P. Yaroshenko

Authors
  1. V. V. Zamashchikov
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  2. E. S. Rudakov
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  3. A. P. Yaroshenko
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Zamashchikov, V.V., Rudakov, E.S. & Yaroshenko, A.P. Kinetics of the homogeneous oxidation of hydrogen by platinum(II) and platinum(IV) chloro complexes in aqueous solution. React Kinet Catal Lett 22, 39–43 (1983). https://doi.org/10.1007/BF02064803

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  • DOI: https://doi.org/10.1007/BF02064803

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