Abstract
The mass spectra of four guaianolides with epoxy groups of C1–C2 have been studied. A mechanism is proposed for the formation of the main ions. The origin of the secondary fragments has been confirmed by measurements of elementary compositions.
Similar content being viewed by others
Literature cited
S. M. Kupchan, J. M. Cassady, and J. E. Kelsey, J. Am. Chem. Soc.,88, 5292 (1966).
L. Tsai, R. J. Highet, and W. Herz, J. Org. Chem.,34, 945 (1969).
P. I. Zakharov, R. I. Evstratova, and K. S. Rybalko, Khim. Prir. Soedin., 587 (1971).
M. A. Irwin and T. A. Geissman, Phytochemistry,12, 863 (1973).
T. Asawa and D. Taylor, Tetrahedron Lett.,13, 1169 (1977).
M. I. Yusupov, Sh. Z. Kasymov, G. P. Sidyakin, and U. Rakhmankulov, Khim. Prir. Soedin., 579 (1979).
M. S. Yusupov, A. Mallabaev, Sh. Z. Kasymov, and G. P. Sidyakin, Khim. Prir. Soedin., 580 (1979).
U. A. Abdullaev, Ya. V. Rashkes, and S. Yu. Yunusov, Khim. Prir. Soedin., 125 (1975).
U. A. Abdullaev, Ya. V. Rashkes, S. Z. Kasymov, and G. P. Sidyakin, Khim. Prir. Soedin., 636 (1980).
Additional information
Institute of the Chemistry of Plant Substances of the Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 796–800, November–December, 1980.
Rights and permissions
About this article
Cite this article
Abdullaev, U.A., Rashkes, Y.V., Yusupov, M.I. et al. Fragmentation of some 1,2-epoxyguaianolides. Chem Nat Compd 16, 568–571 (1980). https://doi.org/10.1007/BF00564860
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00564860