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Differential Phonon Spectrometrics (DPS)

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Solvation Dynamics

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 121))

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Abstract

An incorporation of the hydrogen bond cooperativity theory to the DPS strategy and surface stress (contact angle) detection could resolve the solvation bonding and nonbonding dynamics and solute capabilities. The enabled information includes bond length and stiffness transition, electron polarization, and the fraction of bonds transformed from the mode of ordinary water to the hydration shells. A combination of the DPS and the ultrafast IR spectroscopy would be more revealing towards solute-solvent and solute-solute molecular interactions, solute capabilities, and solution properties. The DPS is focused on the solvation O:H–O segmental cooperative bonding dynamics and the ultrafast IR on molecular motion dynamics by measuring phonon relaxation time.

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Authors and Affiliations

  1. School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore, Singapore

    Prof. Dr. Chang Q Sun

  2. Yangtze Normal University, 408100, Chongqing, China

    Prof. Dr. Chang Q Sun

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  1. Prof. Dr. Chang Q Sun
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Correspondence to Chang Q Sun .

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Sun, C.Q. (2019). Differential Phonon Spectrometrics (DPS). In: Solvation Dynamics. Springer Series in Chemical Physics, vol 121. Springer, Singapore. https://doi.org/10.1007/978-981-13-8441-7_2

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