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Sustainable Chemicals: A Model for Practical Substitution

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Book cover Detox Fashion

Part of the book series: Textile Science and Clothing Technology ((TSCT))

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Abstract

The textile industry sees currently a fast development of legal and voluntary restrictions of chemicals content in textile products. However, the on-going phase-out work focuses on evaluating the environmental and health aspects of chemicals. The technical performance in the end application for the chemical does not receive the same attention. In addition, many research projects committed to evaluating hazardous substances and their possible alternatives also neglects the technical performance. The technical performance is left to the companies to evaluate. This may lead to inefficiency in the substitution process and also have the consequence that companies never dare to take the step to practical substitution, at least not in a proactive way. This chapter presents a model for practical substitution, developed and evaluated in several case studies, whereof two in the textile field: water and soil repellent textile coating materials and flame retarded textiles. From the general lessons learnt, an improved substitution methodology with widespread applicability has been defined.

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Notes

  1. 1.

    Chemical Abstracts Service Registry Numbers.

  2. 2.

    http://www.enfiro.eu/, http://cordis.europa.eu/result/rcn/56829_en.html.

  3. 3.

    http://supfes.eu/.

  4. 4.

    http://www.enfiro.eu/, http://cordis.europa.eu/result/rcn/56829_en.html.

  5. 5.

    http://supfes.eu/.

  6. 6.

    The term “long-chain PFAS” has been defined by OECD (2013) as:

    1. i.

      PFCAs with 7 and more perfluoroalkyl carbons, such as PFOA (with 8 carbons or C8 PFCA) and PFNA (with 9 carbons or C9 PFCA);

    2. ii.

      PFSAs with 6 and more perfluoroalkyl carbons, such as PFHxS (with 6 perfluoroalkyl carbons, or C6 PFSA) and PFOS (with 8 perfluoroalkyl carbons or C8 PFSA); and

    3. iii.

      Substances that have the potential to degrade to long-chain PFCAs or PFSAs, i.e. precursors such as PASF- and fluorotelomer-based compounds.

  7. 7.

    http://www.enfiro.eu/, http://cordis.europa.eu/result/rcn/56829_en.html.

  8. 8.

    Additive means that the flame retardant is only physically bound to the flame retardant material, unlike the reactive flame retardants that are chemically bound.

References

  • AAFA (2015) AAFA restricted substance list (WWW Document). https://www.wewear.org/rsl/. Accessed 26 Oct 2015

  • AFIRM (2015) AFIRM supplier toolkit

    Google Scholar 

  • Andersson H, Harder R, Peters G, Cousins I (2014) SUPFES: environmental risk assessment on short-chain per- and polyfluoroalkyl substances applied to land in municipal sewage sludge. In: 6th international workshop on per- and polyfluorinated alkyl substances—PFASs. Idstein, Germany

    Google Scholar 

  • Backe WJ, Day TC, Field JA (2013) Zwitterionic, cationic, and anionic fluorinated chemicals in aqueous film forming foam formulations and groundwater from U.S. Military bases by nonaqueous large-volume injection HPLC-MS/MS. Environ Sci Technol 47(10):5226–5234

    Google Scholar 

  • Baumann H, Tillman A-M (2004) The Hitchhiker’s guide to LCA. Studentlitteratur, Lund, Sweden

    Google Scholar 

  • Bergman Å, Heindel J, Jobling S, Kidd K, Zoeller RT (2013) State of the science of endocrine disrupting chemicals, 2012. Toxicol Lett. United Nations environment programme and the World Health Organization, New York and Geneva. doi:10.1016/j.toxlet.2012.03.020

  • BLUESIGN® (2017) BLUESIGN ® (WWW Document). http://www.bluesign.com/. Accessed 24 Aug 2013

  • ChemSec (2017) SIN list (WWW Document). URL Canadian Hazardous Products Act (Phthalates regulation SOR/ 2010-298). Accessed 20 Mar 2016

    Google Scholar 

  • China Ministry of Environmental Protection (MEP) (2010) Provisions on the environmental administration of new chemical substances in China. Order No. 7 of the Ministry of Environmental Protection (MEP). China

    Google Scholar 

  • Clean Production Action (2014) GreenScreen® hazard criteria (WWW Document). http://www.greenscreenchemicals.org/info/guidance-and-method-documents-downloads:GreenScreen®. Accessed 31 Jan 2017

  • Dubois A, Gadde L-E (2002) Systematic combining: an abductive approach to case research. J Bus Res 55:553–560

    Article  Google Scholar 

  • Ecolabel Index (2016) Ecolabel index (WWW Document). http://www.ecolabelindex.com/ecolabels/?st=category,textiles. Accessed 24 Aug 2013

  • European Chemicals Bureau (2007) Review on production processes of decabromodiphenyl ether (decaBDE) used in polymeric applications in electrical and electronic equipment, and assessment of the availability of potential alternatives to decaBDE. Brussels, Belgium

    Google Scholar 

  • Commission European (2008) Regulation (EC) No 1272/2008 of the European parliament and of the council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending regulation (EC). Off J Eur, Union 353

    Google Scholar 

  • Commission European (2006) Regulation (EC) No 1907/2006 of the European parliament and the council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European chemicals agency, amending directive 1999/45/E. Off J Eur Union L396:0001–0851

    Google Scholar 

  • Commission European (2011) Directive 2011/65/EU of the European parliament and of the council of 8 June 2011 on the restriction of the use of certain hazardous substances in electrical and electronic equipment. Off J Eur Union L174:88–110

    Google Scholar 

  • GOTS, 2017. Global Organic Textile Standard (GOTS)

    Google Scholar 

  • Government of India (2012) Draft national chemicals policy (Draft NCP-2012)

    Google Scholar 

  • Holmquist H, Schellenberger S, van der Veen I, Peters GM, Leonards PEG, Cousins I (2016) Properties, performance and associated hazards of state-of-the-art durable water repellent (DWR) chemistry for textile finishing. Environ Int 91:251–264

    Article  CAS  Google Scholar 

  • Herzke D, Olsson E, Posner S (2012) Perfluoroalkyl and polyfluoroalkyl substances (PFASs) in consumer products in Norway—A pilot study. Chemosphere 88(8):980–987. https://doi.org/10.1016/j.chemosphere.2012.03.035

  • Howard P, Muir DCG (2010) Identifying new persistent and bioaccumulative organics among chemicals in commerce. Environ Sci Technol 2277

    Google Scholar 

  • Knepper TP, Frömel T, Gremmel C, van Driezum I, Weil H, Vestergren R, Cousins IT (2014) Understanding the exposure pathways of per- and polyfluoralkyl substances (PFASs) via use of PFASs-containing products—risk estimation for man and environment. Texte 47/2014. Dessau-Roßlau, Germany

    Google Scholar 

  • Leonards P (2011) Life cycle assessment of environment-compatible flame retardants (Prototypical Case Study), ENFIRO. NORMAN Network of Reference Laboratories for Monitoring Emerging Environmental Pollutants New Bulletin 1–20

    Google Scholar 

  • Munn K (2011) The chemicals in products project: case study of the textiles sector. Switzerland, Geneva

    Google Scholar 

  • Norwegian Pollution Control Authority (SFT) (2009) Guidance on alternative flame retardants to the use of commercial pentabromodiphenylether. Oslo, Norway

    Google Scholar 

  • OECD (2013). OECD/UNEP Global PFC Group. Synthesis paper on per- and polyfluoronated chemicals (PFCs)

    Google Scholar 

  • OECD (2015) Substitution and alternatives assessment toolbox (SAAT) (WWW Document). www.oecdsaatoolbox.org/. Accessed 26 Oct 2015)

  • OEKO-TEX® Association (2017) OEKO-TEX® standard 100 (WWW Document). https://www.oeko-tex.com. Accessed 24 Aug 2013)

  • Olsson E, Posner S, Roos S, Wilson K (2009) Kartläggning av kemikalieanvändning i kläder. Mölndal, Sweden

    Google Scholar 

  • Outdoor Industry Association (2014) Chemicals Management Module (CMM) (WWW Document). https://outdoorindustry.org/advocacy/corporate-responsibility/chemicals-management-module/. Accessed 1 June 2016

  • Posner S (2009) ENFIRO. Life cycle assessment of environment-compatible flame retardants. WP2 prioritization and selection

    Google Scholar 

  • Posner S, Roos S, Brunn Poulsen P, Jörundsdottir H, Gunnlaugsdottir H, Trier X, Astrup Jensen A, Katsogiannis A, Herzke D, Bonefeld-Jörgensen E, Jönsson C, Pedersen G, Ghisari M, Jensen S (2013) Per- and polyfluorinated substances in the Nordic Countries. TemaNord, Nordic Council of Ministers. doi:10.6027/TN2013-542

    Google Scholar 

  • Quinete N, Orata F, Maes A, Gehron M, Bauer K, Moreira I, Wilken RD (2010) Degradation studies of new substitutes for perfluorinated surfactants. Arch Environ Contam Toxicol 59:20–30

    Article  CAS  Google Scholar 

  • Roos S (2016) Advancing life cycle assessment of textile products to include textile chemicals. Chalmers University of Technology, Inventory data and toxicity impact assessment

    Google Scholar 

  • Roos S (2015) Towards sustainable use of chemicals in the textile industry: how life cycle assessment can contribute. Chalmers University of Technology, Gothenburg

    Google Scholar 

  • Roos S, Jönsson C, Posner S (2017) Nordic textile initiative—report on labelling of chemicals in textiles. Denmark, Copenhagen

    Google Scholar 

  • SAC (2017) Sustainable Apparel Coalition (SAC) (WWW Document). http://apparelcoalition.org/the-higg-index/. Accessed 24 Aug 2013

  • South Korean Ministry of the Environment (2011) Act on the registration and evaluation of chemicals (K-REACH). South Korea

    Google Scholar 

  • Swedish Chemicals Agency (2014) Chemicals in textiles—risks to human health and the environment. KemI Report 6/14. Stockholm, Sweden

    Google Scholar 

  • Swedish Chemicals Agency (2007) The substitution principle. Stockholm, Sweden

    Google Scholar 

  • Swedish Chemicals Agency (2006) Hexabromocyclododecane (HBCDD) and tetrabromobisphenol-A (TBBPA). Government Commission Report, Stockholm, Sweden

    Google Scholar 

  • Swedish Chemicals Agency (2004a) KemI Rapport 6/04—Information om varors innehåll av farliga kemiska ämnen. Sundbyberg, Sweden

    Google Scholar 

  • Swedish Chemicals Agency (2004b) Survey and technical assessment of alternatives to decabromodiphenyl ether (decaBDE) in textile applications. Stockholm, Sweden

    Google Scholar 

  • Swedish Chemicals Group/Swedish Textile Importer’s Association (2016) Chemicals guidance. Mölndal, Sweden

    Google Scholar 

  • UNECE (2006) Overview of existing information on PFOS production, use, emissions and pathways to the environment and cost/benefits with alternatives/substitutes. Bern, Switzerland

    Google Scholar 

  • UNEP (2006) Strategic approach to international chemicals management (SAICM). Switzerland, Geneva

    Google Scholar 

  • UNEP, POPS, POPRC.8, INF, 17 (2012) Technical paper on the identification and assessment of alternatives to the use of perfluorooctane sulfonic acid in open applications. Switzerland, Geneva

    Google Scholar 

  • United Nations (2002) Report of the world summit on sustainable development, Reissued edn. United Nations publications, New York

    Google Scholar 

  • van Leeuwen SPJ, van Velzen MJM, Swart CP, van der Veenm I, Traag WA, de Boer J (2009) Halogenated contaminants in farmed salmon, trout, tilapia, pan- gasius, and shrimp. Environ Sci Technol 43:4009–4015

    Google Scholar 

  • Van Der Veen I, Weiss JM, Hanning AC, De Boer J, Leonards PEG (2016) Development and validation of a method for the quantification of extractable perfluoroalkyl acids (PFAAs) and perfluorooctane sulfonamide (FOSA) in textiles. Talanta 147:8–15. doi:10.1016/j.talanta.2015.09.021

    Article  Google Scholar 

  • Waaijers SL, Kong D, Hendriks HS, de Wit CA, Cousins IT, Westerink RHS, Leonards PEG, Kraak MHS, Admiraal W, de Voogt P, Parsons JR (2013) Persistence, bioaccumulation, and toxicity of halogen-free flame retardants. Rev Environ Contam Toxicol 222:1–71

    CAS  Google Scholar 

  • Wang D-G, Norwood W, Alaee M, Byer JD, Brimble S (2013a) Review of recent advances in research on the toxicity, detection, occurrence and fate of cyclic volatile methyl siloxanes in the environment. Chemosphere 93:711–725

    Article  CAS  Google Scholar 

  • Wang Z, Cousins IT, Scheringer M, Hungerbühler K (2013b) Fluorinated alternatives to long-chain perfluoroalkyl carboxylic acids (PFCAs), perfluroalkane sulfonic acids (PFSAs) and their potential precursors. Environ Int 60:242–248

    Google Scholar 

  • Weiss JM, Van der Veen I, De Boer J, Van Leeuwen SPJ, Cofino W, Crum S (2013) Analytical improvements shown over four interlaboratory studies of perfluoroalkyl substances in environmental and food samples. TrAC—Trends in Analytical Chemistry 43:204–216. https://doi.org/10.1016/j.trac.2012.10.005

  • ZDHC (2014) Roadmap to Zero Discharge of Hazardous Chemicals (ZDHC) (WWW Document). http://www.roadmaptozero.com/. Accessed 1 June 2014

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Correspondence to Sandra Roos .

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Jönsson, C., Posner, S., Roos, S. (2018). Sustainable Chemicals: A Model for Practical Substitution. In: Muthu, S. (eds) Detox Fashion. Textile Science and Clothing Technology. Springer, Singapore. https://doi.org/10.1007/978-981-10-4876-0_1

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  • DOI: https://doi.org/10.1007/978-981-10-4876-0_1

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