Abstract
Toxic and dangerous types of waste materials including chemical weapons need to be inertized prior to their final disposal. This can be done by dispersion and encapsulation or solidification of the total waste stream in inert matrices like cement. A different strategy is the separation of critical ingredients by adsorption on adequate substrates like carbon or by absorption in suitable liquids. The most efficient strategy, however, is the complete destruction of all toxic compounds. For inorganic species this requires a respeciation into compounds of acceptable properties. For organic compounds the best strategy in this respect is the total oxidation into carbon dioxide, CO2, and water, H2O. This goal may be reached in different ways depending on the methods chosen for destruction. The physical and chemical parameters as well as the temperature of the applied processes can vary in wide ranges.
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References
Angenend, FJ. & Trondt, L. (1990), Schadstoffinput — Schadstoffoutput, VGB Kraftwerkstechnik, 70, 36.
Anton, F. (1995), Das Siemens-KWU-Schwelbrennverfahren — Stoffliche und energetische Verwendungen von Restmüll, VDl-Berichte Nr. 1192, 349.
Berwein, H.-J. & Erlecke, J. (1990), Einsatzmöglichkeiten der Verschwelung als Homogenisierungsstufe in der thermischen Abfallverwertung. In Müllverbrennung und Umwelt 4 (Thomé-Kozmiensky, K.J., ed.), Berlin: EF-Verlag, 225.
Bilitewski, Härdtle, Marek (1985), Grundlage der Pyrolyse von Rohstoffen. In: Pyrolyse von Abfällen (Thomé-Kozmiensky, K.J., ed.), EF-Verlag, Berlin, 1 – 77.
Braun, H. (1992), Problemelement Quecksilber — von der Spezifizierung über kontinuierliche Emissionsüberwachung zur Prozeßsteuerung, In Symposium 25 Jahre LIT, 5 Jahre TAMARA, KfK Report 5000, 77.
Brunner, P.H. & Mönch, H.. (1986), The Flux of Metals Through Municipal Solid Waste Incinerators, Waste Management & Research, 4, 105.
Buttker, B., Rabe, W. & Müller, J (1993), Kurzbericht über erste Erfahrungen der Verwertung von Reststoffen in der Festbettdruckvergasung in Schwarze Pumpe. VDI Bildungswerk, Mannheim 27./28.1.93.
Comfére, W. (1985), Niedertemperaturpyrolyse, BKMI-Verfahren. In Pyrolyse von Abfällen (Thomé- Kozmiensky, K.J., ed.), Berlin: EF-Verlag, 142.
Dannecker, W. & Hemschemeier, H. (1990), Level of activated-coke technology for flue gas dust collection behind refuse destruction plants looking at the problem frpom the special aspects of dioxin separation. In Organohalogen Compounds, Vol. 4, Dioxin 90 — EPRl-Seminar (Hutzinger, O. & Fiedler K, ed.), Ecoinforma Press, Bayreuth, 1990, 267.
Fichtel, K. (1987), Bericht über die Müllpyrolyse-Anlage Burgau. In Müllverbrennung und Umwelt 2 (Thomé-Kozmiensky, K.J., ed.), Berlin: EF-Verlag, 662–678.
Häßler, G. (1995), Thermoselect. Verlag Karl Görner, Karlsruhe.
Hagenmaier, H., Kraft, M., Brunner, H. & Haag, R. (1987), Catalytic effects of Fly Ash from Waste Incineration Facilities on the Formation and Decomposition of Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofuranes, Environmental Science and Technology, 21, 1080.
Hiraoka, M., Takeda, N., Okajima, S., Kasakura, T. & Imoto, Y. (1989), Catalytic Destruction of PCDDs in Flue Gas, Chemosphere, 19, 361.
Hunsinger, H., Kreisz, S. & Vogg, H. (1995), Formation of Chlorinated Aromatic Compounds in the Raw Gas of Municipal Solid Waste Incineration Plants, DIOXIN 95, 15th Symposium on chlorinated Dioxins and Related Compounds, Edmonton, CDN, Short Papers, 343.
International Ash Working Group (IAWG): A.J. Chandler, T.T. Eighmy, J. Haïtien, O. Hjelmar, D.S. Kosson, S.E. Sawell, H.A. van der Sloot, J. Vehlow (1997), Municipal Solid Waste Incinerator Residues, Elsevier, Amsterdam-Lausanne-New York-Oxford-Shannon-Tokyo.
Jekel, M, Ritz, J. & Vater, C. (1992), Abwässer und deren Behandlung. In Müllverbrennung und Umwelt 5 (Thomé-Kozmiensky, K.J., ed.), Berlin: EF-Verlag, 375.
Johnke, B. (1994), Schlackeverwertung und -entsorgung unter Beachtung der Vorgaben gesetzlicher und technischer Regelungen, Beihefte zu Müll und Abfall, 31, 200.
Kaminsky, W., Sinn, H. & Janning, J. (1979), Technische Prototypen für die Altreifen- und Kunststoffpyrolyse, Chem.-Ing.-Tech., 51, 419.
Körte H.-J. (1994), NEUTREC Verfahren: Trockenverfahren für die Rauchgasreinigung mit Natriumbicarbonat und Recycling der entstehenden Natriumverbindungen. In VDI- Handbuch, BW43–59–06.
Kreisz, S., Hunsinger, H. & Vogg, H. (1995), Technical Plastics as PCDD/F Absorbers, DIOXIN 95, I5th Symposium on chlorinated Dioxins and Related Compounds, Edmonton, CDN, Short Papers 443.
Kürzinger, K. & Stephan, R. (1989), Hydrochloric Acid and Gypsum (Sulphuric Acid) as Utilizable End Products Obtained from the KRC Process for Cleaning Flue Gases from Incinerators. In Recycling International (Thomé-Kozmiensky, K.J., ed.), Berlin: EF-Verlag, 1224.
Lenz, S (1979), Optimale Abfallnutzung durch neuartige Pyrolyseverfahren, Umwelt, 4,291.
Mätzing, H., Namba, H. & Tokunaga, O. (1993), Kinetics of S02 removal from flue gas by electron beam technique, Radiation Physics and Chemistry, 42, 673.
Nielsen, K.K. & Nøller, J.T. (1989), Reduction of Chlorinated Dioxins and Furanes in the Flue Gas from Incinerators with Spray Absorbers and Electrostatic Precipitators, Chemosphere, 19, 367.
Paur, H.R. (1992), Removal of volatile hydrocarbons from industrial offgas. In Electron Beam and Electrical Discharge Processing (Penetrante, B.M., ed.) Berlin, Springer Verlag, 77.
Paur, H.R. & Mätzing, H. (1993), Electron beam induced purification of dilute off gases from industrial processes and automobile tunnels, Radiation Physics and Chemistry, 42, 719.
Reeck, G., Schröder, W. & Schetter, G. (1991), Zukunftsorientierte Abfallverbrennung in der MVA Ludwigshafen, Müll und Abfall, 23, 661.
Sattler, K (1982), Umweltschutz, Entsorgungstechnik. Würzburg: Vogel Verlag.
Schingnitz, M. & Fritz, P. (1997), Integration von Abfall- und Energiewirtschaft durch Anwendung des NOELL-Konversionsverfahrens, Chemie Ingenieur Technik, 69, 820 – 824.
South Coast Air Quality Management District (SCAQMD) (1991), The SCAQMD Screening, Report.
Stahlberg, R. & Feuerriegel, U. (1995), Das THERMO SELECT-Verfahren zur Energie- und Rohstoffgewinnung -Konzept, Verfahren, Kosten -, VDI-Berichte Nr. 1192, 319.
Tchobanoglons, G., Theisen, H. & Ellassen, R. (1977), Solid Wastes. New York: McGraw Hill Inc..
Vehlow, J. (1996), Simple, reliable and yet efficient — modern trends in waste incineration. UTA Technology and Environment, 2/96, 144.
Vogg, H. & Stieglitz, L. (1986), Thermal Behaviour of PCDD/PCDF in Fly Ash from Municipal Incinerators, Chemosphere, 15, 1373.
Vogg, H., Hunsinger, H. & Stieglitz, L. (1990), Contribution to Solving the Problem of Dioxins Generated during Waste Incineration, Chemical Engineering Technology, 13, 221.
Vogg, H., Hunsinger, H., Merz, A., Stieglitz, L. & Vehlow, J. (1991), Head-end-Techniken zur Dioxinminderung. VDI Berichte Nr. 895, 193.
Vogg, H. (1992), Abfallverbrennung — Fakten und Perspektiven, BWK/TÜ/UT-Special, Okt. 1992, M14.
Volkman, Y., Vehlow, J. & Vogg, H. (1991), Improvement of Flue Gas Cleaning Concepts in MSWI and Utilization of By-Products. In Waste Materials in Construction (Goumans, J.J.J., van der Shot, H.A. & Albers, Th.G., ed.), Amsterdam: Elsevier Publishers, 145.
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Vehlow, J. (1998). Cleaning of Gaseous Products from Thermal Waste Treatment. In: Holm, F.W. (eds) Effluents from Alternative Demilitarization Technologies. NATO Science Series, vol 22. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5310-2_5
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DOI: https://doi.org/10.1007/978-94-011-5310-2_5
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