Abstract
A Lennard-Jones potential is used to derive for mulaefor the potential of interaction between shell macro molecules and gas atoms. Calculations are carried as far as thespherical symmetry approximation. The potential of interaction determines the stability of a shell topological compound. When the distance R between a shell molecule and a gas atom is equal the radius 1 of the outer shell, the potential is the highest and determines a barrier, which must be lower than an energy of the trapped / by the shell molecule / atom to be released.
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References
M. Maciejewski,J Macromol.Sci.-Chem 17, 689 (1982).
T. Matsuura, Y. Taketani and S Sourirajan, inSynthetic Membranes, vol. 2, A.F. Turbak, Ed.; American Chemical Society, Washington D.C. 1981, paper 19.
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© 1984 D. Reidel Publishing Company
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Maciejewski, M., Jezierski, J. (1984). Thermodynamic Properties of a Shell Molecule-Gas Particles System. In: Atwood, J.L., Davies, J.E.D., Osa, T. (eds) Clathrate Compounds, Molecular Inclusion Phenomena, and Cyclodextrins. Advances in Inclusion Science, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5376-5_46
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DOI: https://doi.org/10.1007/978-94-009-5376-5_46
Publisher Name: Springer, Dordrecht
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