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Stoffliche Nutzung von Braunkohle pp 813–831Cite as

Korrosionsverhalten metallischer Werkstoffe in schwefelhaltigen Gasen mit niedrigem Sauerstoffpartialdruck im Temperaturbereich 500–700 °C

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Zusammenfassung

Ausgewählte austenitische Stähle und Nickelbasislegierungen wurden im Hinblick auf ihr Korrosionsverhalten bei 700 °C in einem H2-H2O-H2S-Modellgas untersucht. Werkstoffe, die unter diesen Bedingungen die geringsten Korrosionsraten aufwiesen, wurden detailliert bezüglich der Temperaturabhängigkeit der Korrosionsraten bei 500–700 °C erprobt. Dabei zeigten Alloy 693, 625 und 740 eine anomale Temperaturabhängigkeit der Korrosionsraten, während alloy HR-160 bei allen Temperaturen sehr geringe Korrosionsraten aufwies. Bei Grundlagenuntersuchungen an Modelllegierungen zeigte sich, dass hohe Co-Zusätze zu binären NiCr-Legierungen die Korrosionsraten deutlich reduzieren und bei 650 sowie 700 °C zur Bildung von Cr-Oxidschichten führten. Zusätze von Ti oder Si in einer NiCrCo-Modelllegierung förderten die Cr-Oxidbildung bei niedrigen Temperaturen (500–600 °C). Auch Zusätze von Nb zu einer binären NiCr-Modelllegierung bewirkten im Gegensatz zu Zusätzen von Mo eine Reduzierung der Korrosionsraten durch Bildung Nb-reicher intermetallischer Phasen an der Schicht/Legierungs-Grenzfläche. Allerdings trat dieser positive Effekt lediglich bei den höchsten Versuchstemperaturen (650 und 700 °C) auf.

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Author information

Authors and Affiliations

  1. Forschungszentrum Jülich GmbH, IEK-2, 52428, Jülich, Deutschland

    Joanna Zurek

  2. Forschungszentrum Jülich GmbH, IEK-2, 52428, Jülich, Deutschland

    Elham Hejrani

  3. Institut für Energie- und Klimaforschung, Forschungszentrum Jülich GmbH, IEK-2, 52428, Jülich, Deutschland

    Michael Müller

  4. Forschungszentrum Jülich GmbH, IEK-2, 52428, Jülich, Deutschland

    Willem J. Quadakkers

Authors
  1. Joanna Zurek
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  2. Elham Hejrani
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  4. Willem J. Quadakkers
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Correspondence to Joanna Zurek .

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Editors and Affiliations

  1. Inst. für Energieverfahrenstechnik und Chemieingenieurwesen, TU Bergakademie Freiberg, Freiberg, Germany

    Steffen Krzack

  2. Inst. für Energieverfahrenstechnik und Chemieingenieurwesen, TU Bergakademie Freiberg, Freiberg, Germany

    Heiner Gutte

  3. Inst. für Energieverfahrenstechnik und Chemieingenieurwesen, TU Bergakademie Freiberg, Freiberg, Germany

    Bernd Meyer

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Zurek, J., Hejrani, E., Müller, M., Quadakkers, W.J. (2018). Korrosionsverhalten metallischer Werkstoffe in schwefelhaltigen Gasen mit niedrigem Sauerstoffpartialdruck im Temperaturbereich 500–700 °C. In: Krzack, S., Gutte, H., Meyer, B. (eds) Stoffliche Nutzung von Braunkohle. Springer Vieweg, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-46251-5_32

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  • DOI: https://doi.org/10.1007/978-3-662-46251-5_32

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  • Publisher Name: Springer Vieweg, Berlin, Heidelberg

  • Print ISBN: 978-3-662-46250-8

  • Online ISBN: 978-3-662-46251-5

  • eBook Packages: Computer Science and Engineering (German Language)

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