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Infrared Spectroscopy

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Phonons: Theory and Experiments II

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 65))

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Abstract

The chapter starts with a discussion of the principles of sepctrometers used in the infrared and far-infrared region. Reflectivity and transmission spectra of selected crystals serve to illustrate the experimental information. Methods are presented for the evaluation of optical constants, i.e. ε 1(ω) and ε 2(ω), from the observed reflectivity and transmission data. We then discuss the Kramers-Kronig relations and certain sum rules relevant for lattice vibrations. It follows a classical study of the interaction of lattice vibrations with light (polaritons) and the propagation of light in crystals. Finally, we present a discussion of one- and multi-phonon absorption processes on the basis of the quantum mechanical treatment of the dielectric constant. An extensive theoretical treatment of infrared absorption and Raman scattering by phonons of non-metals containing complementary aspects has been presented by Bilz, Strauch and Wehner [2.1].

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Authors and Affiliations

  1. Brown Boveri Research Center, CH-5045, Baden-Dättwil, Switzerland

    Dr. Peter Brüesch

  2. Ecole Polytechnique Fédérale de Lausanne, CH-1015, Lausanne, Switzerland

    Dr. Peter Brüesch

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  1. Dr. Peter Brüesch
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© 1986 Springer-Verlag Berlin Heidelberg

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Brüesch, P. (1986). Infrared Spectroscopy. In: Phonons: Theory and Experiments II. Springer Series in Solid-State Sciences, vol 65. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-52263-5_2

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  • DOI: https://doi.org/10.1007/978-3-642-52263-5_2

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-52265-9

  • Online ISBN: 978-3-642-52263-5

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