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Optical Properties of 3d-Ions in Crystals: Spectroscopy and Crystal Field Analysis pp 29–94Cite as

Exchange charge model of crystal field for 3d ions

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Abstract

In the second chapter of the book the authors present the results of theoretical studies ofthe energy levels schemes of all 3dn (n=1, 9) ionsin various crystals at the substitutionalsites. Systematic calculations are described in all details; they include the overlap integrals between the impurityions’ and ligands’ wave functions; the crystal field parameters calculations, and diagonalization of the crystal field Hamiltonians for each considered case. The calculated results arediscussed and compared with experimental data and with similar results from literature. The chapter also contains a comprehensive literature review on the properties of 3d-ions doped crystals.

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  1. Institute of Physics, University of Tartu, Riia 142, Tartu, 51014, Estonia

    M. G. Brik

  2. Departments of Physics, West University of Timisoara, Bd. V. Parvan 4, 300223, Timisoara, Romania

    N. M. Avram & C. N. Avram

  3. Academy of Romanian Scientists, Splaiul Independentei 54, 050094, Bucharest, Romania

    N. M. Avram

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    Nicolae M. Avram

  2. Institute of Physics, University of Tartu, Riia 142, Tartu, 51014, Estonia

    Mikhail G. Brik

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Brik, M.G., Avram, N.M., Avram, C.N. (2013). Exchange charge model of crystal field for 3d ions. In: Avram, N.M., Brik, M.G. (eds) Optical Properties of 3d-Ions in Crystals: Spectroscopy and Crystal Field Analysis. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-30838-3_2

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