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Quasi-Chemical Representation

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Invariant Manifolds for Physical and Chemical Kinetics

Part of the book series: Lecture Notes in Physics ((LNP,volume 660))

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Abstract

In Chap. 5 we have used the second law of thermodynamics, the existence of the entropy, in order to equip the problem of constructing the slow invariant manifolds with a geometric structure. The requirement of the entropy growth (universally, for all reduced models) restricts significantly the form of the projectors (5.25).

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Authors and Affiliations

  1. Multidisciplinary Research Institute 213 Department of Mathematics, University of Leicester, University Road, LE1 7RH, Leicester, United Kingdom

    Alexander N. Gorban

  2. Institute of Computational Modeling, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia

    Alexander N. Gorban

  3. Institut für Energietechnik, Clausiusstrasse 33 ETH Zentrum, CLT A 6, 8092, Zürich, Switzerland

    Ilya V. Karlin

  4. Institute of Computational Modeling, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia

    Ilya V. Karlin

Authors
  1. Alexander N. Gorban
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  2. Ilya V. Karlin
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N. Gorban, A., V. Karlin, I. Quasi-Chemical Representation. In: Invariant Manifolds for Physical and Chemical Kinetics. Lecture Notes in Physics, vol 660. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-31531-5_7

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  • DOI: https://doi.org/10.1007/978-3-540-31531-5_7

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-22684-0

  • Online ISBN: 978-3-540-31531-5

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

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