Skip to main content

Dielectric Materials for Microelectronics

  • Chapter
  • First Online:
Springer Handbook of Electronic and Photonic Materials

Part of the book series: Springer Handbooks ((SHB))

Abstract

Dielectrics are an important class of thin-film electronic materials for microelectronics. Applications include a wide swathe of device applications, including active devices such as transistors and their electrical isolation, as well as passive devices, such as capacitors . In a world dominated by Si-based device technologies, the properties of thin-film dielectric materials span several areas. Most recently, these include high-permittivity applications, such as transistor gate and capacitor dielectrics, as well as low-permittivity materials, such as inter-level metal dielectrics, operating at switching frequencies in the gigahertz regime for the most demanding applications.

This chapter provides a survey of the various dielectric material systems employed to address the very substantial challenge associated with the scaling Si-based integrated circuit technology. A synopsis of the challenge of device scaling is followed by an examination of the dielectric materials employed for transistors, device isolation, memory and interconnect technologies. This is presented in view of the industry roadmap which captures the consensus for device scaling (and the underlying economics) – the International Technology Roadmap for Semiconductors.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 229.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 299.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. H.-S. P. Wong: In: ULSI Devices, ed. by C.Y. Chang, S.M. Sze (Wiley, New York 2000) Chap. 3

    Google Scholar 

  2. S. Wolf: Silicon Processing for the VLSI Era, Vol. 3 (Lattice, Sunset Beach 1995)

    Google Scholar 

  3. E. Nicollian, J. Brews: MOS Physics and Technology (Wiley, New York 1982)

    Google Scholar 

  4. S.M. Sze: Physics of Semiconductor Devices, 2nd edn. (Wiley, New York 1981)

    Google Scholar 

  5. G. Moore: Electronics 38, 8 (1965), Also see: http://www.intel.com/labs/index.htm

    Google Scholar 

  6. G. Moore: Tech. Dig. Int. Electron. Dev. Meet. (IEEE, Washington DC 1975) p. 11

    Google Scholar 

  7. ITRS: http://itrs2.net/2013-itrs.html/ (2013)

  8. A. Huang: IEEE Spectrum 52, 42 (2015)

    Google Scholar 

  9. D. Hutcheson: Transistors by the numbers, IEEE Spectrum 52(4), 33 (2015)

    Google Scholar 

  10. R.F. Service: Science 323, 1000 (2010)

    Google Scholar 

  11. C.L. Hinkle, E.M. Vogel, P.D. Ye, R.M. Wallace: Curr. Opin. Solid State Mater. Sci. 15, 188 (2011)

    CAS  Google Scholar 

  12. S.C. Sun: IEEE Tech. Dig. Int. Electron. Dev. Meet., Washington DC (1997) p. 765

    Google Scholar 

  13. W. Haensch, E.J. Nowack, R.H. Dennard, P.M. Solomon, A. Bryant, O.H. Dokumaci, A. Kumar, X. Wang, J.B. Johnson, M.V. Fischetti: IBM J. Res. Dev. 50(4/5), 339 (2006)

    CAS  Google Scholar 

  14. G. Wilk, R.M. Wallace, J.M. Anthony: J. Appl. Phys. 89(10), 5243 (2001)

    CAS  Google Scholar 

  15. M.T. Bohr: IEEE Tech. Dig. Int. Electron. Dev. Meet., Washington DC (1995) p. 241

    Google Scholar 

  16. T. Hori: Gate Dielectrics and MOS ULSI’s, Series in Electronics and Photonics, Vol. 34 (Springer, Berlin 1997)

    Google Scholar 

  17. A. Chatterjee, M. Rodder, I.-C. Chen: IEEE Trans. Electron. Dev. 45, 1246 (1998)

    Google Scholar 

  18. I-C. Chen, W. Liu: In: ULSI Devices, ed. by C.Y. Chang, S.M. Sze (Wiley, New York 2000) Chap. 10

    Google Scholar 

  19. R. Dennard, F. Gaensslen, H.-N. Yu, V.L. Rideout, E. Bassous, A.R. LeBlanc: J. Solid State Circuits SC-9, 256 (1974)

    Google Scholar 

  20. R. Dennard, F. Gaensslen, E. Walker, P. Cook: J. Solid State Circuits SC-14, 247 (1979)

    Google Scholar 

  21. D. Frank, R.H. Dennard, E. Nowak, P.M. Solomon, Y. Taur, H.-S.P. Wong: Proc. IEEE 89, 259 (2001)

    CAS  Google Scholar 

  22. S. Thompson, P. Packan, M. Bohr: Intel Technol. J. Q 3, 223 (1998)

    Google Scholar 

  23. S.O. Kasap: Principles of Electronic Materials and Devices, 3rd edn. (McGraw–Hill, New York 2005)

    Google Scholar 

  24. R. Ramesh: Thin Film Ferroelectric Materials and Devices (Kluwer, Boston 1997)

    Google Scholar 

  25. D.-S. Yoon, J.S. Roh, H.K. Baik, S.-M. Lee: Crit. Rev. Solid State Mater. Sci. 27, 143 (2002)

    CAS  Google Scholar 

  26. B. Bivari: IEEE Tech. Dig. Int. Electron. Dev. Meet. (1996) p. 555

    Google Scholar 

  27. S. Wolf: Silicon Processing for the VLSI Era, Vol. 4 (Lattice, Sunset Beach 2002)

    Google Scholar 

  28. S. Wolf: Silicon Processing for the VLSI Era, Vol. 1 (Lattice, Sunset Beach 1986)

    Google Scholar 

  29. S. Wolf: Silicon Processing for the VLSI Era, Vol. 2 (Lattice, Sunset Beach 1990)

    Google Scholar 

  30. J. Robertson, R.M. Wallace: Mater. Sci. Eng. R 88, 1 (2015)

    Google Scholar 

  31. S. Banerjee, B. Streetman: In: ULSI Devices, ed. by C.Y. Chang, S.M. Sze (Wiley, New York 2000) Chap. 4

    Google Scholar 

  32. R. Rios, N. D. Arora: IEEE Tech. Dig. Int. Electron. Dev. Meet., San Francisco (1994) p. 613

    Google Scholar 

  33. Y.-C. King, C. Hu, H. Fujioka, S. Kamohara: Appl. Phys. Lett. 72, 3476 (1998)

    CAS  Google Scholar 

  34. K. Yang, Y.-C. King, C. Hu: Symp. VLSI Tech. Tech. Dig. Papers, Kyoto (1999) p. 77

    Google Scholar 

  35. C.Y. Wong, J.Y. Sun, Y. Taur, C.S. Oh, R. Angelucci, B. Davari: IEEE Tech. Dig. Int. Electron. Dev. Meet., San Francisco (1988) p. 238

    Google Scholar 

  36. A.C. Diebold, D. Venables, Y. Chabal, D. Muller, M. Weldon, E. Garfunkel: Mater. Sci. Semicond. Proc. 2, 104 (1999)

    Google Scholar 

  37. Z.H. Lu, J.P. McCaffrey, B. Brar, G.D. Wilk, R.M. Wallace, L.C. Feldman, S.P. Tay: Appl. Phys. Lett. 71, 2764 (1997)

    CAS  Google Scholar 

  38. E.M. Vogel, K.Z. Ahmed, B. Hornung, W.K. Henson, P.K. McLarty, G. Lucovsky, J.R. Hauser, J.J. Wortman: IEEE Trans. Electron. Dev. 45, 1350 (1998)

    CAS  Google Scholar 

  39. M.L. Green, E.P. Gusev, R. Degraeve, E.L. Garfunkel: J. Appl. Phys. 90, 2057 (2001)

    CAS  Google Scholar 

  40. D.K. Schroder: Semiconductor Material and Device Characterization, 2nd edn. (Wiley, New York 1998)

    Google Scholar 

  41. C.R. Helms, E.H. Poindexter: Rep. Prog. Phys. 57, 791 (1994)

    CAS  Google Scholar 

  42. R. Hummel: Electronic Properties of Materials, 2nd edn. (Springer, New York 1993)

    Google Scholar 

  43. W.R. Runyan, K.E. Bean: Semiconductor Integrated Circuit Processing Technology (Addison-Wesley, New York 1990)

    Google Scholar 

  44. F.J. Himpsel, F.R. McFeely, A. Taleb-Ibrahimi, J.A. Yarmoff, G. Hollinger: Phys. Rev. B 38, 6084 (1988)

    CAS  Google Scholar 

  45. S.T. Pantilides: The Physics of SiO and its Interfaces (Pergamon, New York 1978)

    Google Scholar 

  46. G. Lucovsky, S.T. Pantilides, F.L. Galeener: The Physics of MOS Insulators (Pergamon, New York 1980)

    Google Scholar 

  47. C.R. Helms, B.E. Deal: The Physics and Chemistry of SiO and the Si–SiO Interface (Plenum, New York 1988)

    Google Scholar 

  48. P. Balk (Ed.): The Si–SiO 2 System , Material Science Monographs (Elsevier, New York 1988) p. 32

    Google Scholar 

  49. C.R. Helms, B.E. Deal: The Physics and Chemistry of SiO and the Si–SiO Interface, Vol. 2 (Plenum, New York 1993)

    Google Scholar 

  50. H.Z. Massoud, E.H. Poindexter, C.R. Helms: The Physics of SiO and its Interfaces – 3, Vol. 96-1 (Electrochemical Society, Pennington 1996)

    Google Scholar 

  51. R.A.B. Devine: The Physics and Technology of Amorphous SiO (Plenum, New York 1988) p. 2

    Google Scholar 

  52. E. Garfunkel, E. Gusev, A. Vul: Fundamental Aspects of Ultrathin Dielectrics on Si-based Devices, NATO Science Series, Vol. 3/47 (Kluwer, Nowell 1998)

    Google Scholar 

  53. R.A.B. Devine, J.-P. Duraud, E. Dooryhee: Structure and Imperfections in Amorphous and Crystalline Silicon Dioxide (Wiley, New York 2000)

    Google Scholar 

  54. H.Z. Massoud, I.J.R. Baumvol, M. Hirose, E.H. Poindexter: The Physics of SiO and its Interfaces – 4, Vol. PV2000-2 (Electrochemical Society, Pennington 2000)

    Google Scholar 

  55. A. Bongiorno, A. Pasquarello: Mater. Sci. Eng. B 96, 102 (2002)

    Google Scholar 

  56. J.H. Oh, H.W. Yeom, Y. Hagimoto, K. Ono, M. Oshima, N. Hirashita, M. Nywa, A. Toriumi, A. Kakizaki: Phys. Rev. B 63, 205310 (2001)

    Google Scholar 

  57. G. Dolino: In: Structure and Imperfections in Amorphous and Crystalline Silicon Dioxide, ed. by R.A.B. Devine, J.-P. Duraud, E. Dooryhee (Wiley, New York 2000) Chap. 2

    Google Scholar 

  58. L.W. Hobbs, C.E. Jesurum, B. Berger: In: Structure and Imperfections in Amorphous and Crystalline Silicon Dioxide, ed. by R.A.B. Devine, J.-P. Duraud, E. Dooryhee (Wiley, New York 2000) Chap. 1

    Google Scholar 

  59. A. Bongiorno, A. Pasquarello: Appl. Phys. Lett. 83, 1417 (2003)

    CAS  Google Scholar 

  60. F. Mauri, A. Pasquarello, B.G. Pfrommer, Y.-G. Yoon, S.G. Louie: Phys. Rev. B 62, R4786 (2000)

    CAS  Google Scholar 

  61. W.H. Zachariasen: J. Am. Chem. Soc. 54, 3841 (1932)

    CAS  Google Scholar 

  62. P. Balk: J. Nanocryst. Sol. 187, 1 (1995)

    CAS  Google Scholar 

  63. F.J. Grunthaner, P.J. Grunthaner: Mater. Sci. Rep. 1, 65 (1986)

    CAS  Google Scholar 

  64. A. Stirling, A. Pasquerello: Phys. Rev. B 66, 24521 (2002)

    Google Scholar 

  65. G. Hollinger, F.R. Himpsel: Phys. Rev. B 28, 3651 (1983)

    CAS  Google Scholar 

  66. G. Hollinger, F.R. Himpsel: Appl. Phys. Lett. 44, 93 (1984)

    CAS  Google Scholar 

  67. T. Hattori: Crit. Rev. Solid State Mater. Sci. 20, 339 (1995)

    CAS  Google Scholar 

  68. F. Rochet, Ch. Poncey, G. Dufour, H. Roulet, C. Guillot, F. Sirotti: J. Non-Cryst. Solids 216, 148 (1997)

    CAS  Google Scholar 

  69. D.A. Muller, T. Sorsch, S. Moccio, F.H. Baumann, K. Evans-Lutterodt, G. Timp: Nature 399, 758 (1999)

    CAS  Google Scholar 

  70. I.J.R. Baumvol: Surf. Sci. Rep. 36, 1 (1999)

    CAS  Google Scholar 

  71. J.J. Lander, J. Morrison: J. Appl. Phys. 33, 2089 (1962)

    CAS  Google Scholar 

  72. F.W. Smith, G. Ghidini: J. Electrochem. Soc. 129, 1300 (1982)

    CAS  Google Scholar 

  73. K. Wurm, R. Kliese, Y. Hong, B. Röttger, Y. Wei, H. Neddermeyer, I.S.T. Tsong: Phys. Rev. B 50, 1567 (1994)

    CAS  Google Scholar 

  74. J. Seiple, J.P. Pelz: Phys. Rev. Lett. 73, 999 (1994)

    CAS  Google Scholar 

  75. J. Seiple, J.P. Pelz: J. Vac. Sci. Technol. A 13, 772 (1995)

    CAS  Google Scholar 

  76. Y. Wei, R.M. Wallace, A.C. Seabaugh: J. Appl. Phys. 81, 6415 (1997)

    CAS  Google Scholar 

  77. E.P. Gusev, H.C. Lu, T. Gustafsson, E. Garfunkel: Phys. Rev. B 52, 1759 (1995)

    CAS  Google Scholar 

  78. B.E. Deal, A.S. Grove: J. Appl. Phys. 36, 3770 (1965)

    CAS  Google Scholar 

  79. J.D. Plummer: Silicon oxidation kinetics-from Deal-Grove to VLSI process models. In: The Physics of SiO and its Interfaces – 3, Vol. 96-1, ed. by H.Z. Massoud, E.H. Poindexter, C.R. Helms (Electrochemical Society, Pennington 1996) p. 129

    Google Scholar 

  80. P. Balk: Trans. IEEE 53, 2133 (1965)

    Google Scholar 

  81. G. Abowitz, E. Arnold, J. Ladell: Phys. Rev. Lett. 18, 543 (1967)

    CAS  Google Scholar 

  82. B.E. Deal, M. Sklar, A.S. Grove, E.H. Snow: J. Electrochem. Soc. 114, 266 (1967)

    CAS  Google Scholar 

  83. E. Arnold, J. Ladell, G. Abowitz: Appl. Phys. Lett. 13, 413 (1968)

    CAS  Google Scholar 

  84. R.R. Razouk, B.E. Deal: J. Electrochem. Soc. 126(9), 1573 (1979)

    CAS  Google Scholar 

  85. J.H. Weil, J.R. Bolton, J.E. Wertz: Electron Paramagnetic Resonance: Elementary Theory and Practical Applications (Wiley, New York 1994)

    Google Scholar 

  86. P.J. Caplan, J.N. Helbert, B.E. Wagner, E.H. Poindexter: Surf. Sci. 54, 33 (1976)

    CAS  Google Scholar 

  87. E.H. Poindexter, P.J. Caplan: Prog. Surf. Sci. 14, 201 (1983)

    CAS  Google Scholar 

  88. E.H. Poindexter, P.J. Caplan: J. Vac. Sci. Technol. A 6, 390 (1988)

    Google Scholar 

  89. J.F. Conley: Mater. Res. Soc. Symp. Proc. 428, 293 (1996)

    CAS  Google Scholar 

  90. J.F. Conley, P.M. Lenahan: A review of electron spin resonance spectroscopy of defects in thin film SiO2 on Si. In: The Physics of SiO2 and its Interfaces – 3 , Vol. 96-1, ed. by H.Z. Massoud, E.H. Poindexter, C.R. Helms (Electrochemical Society, Pennington 1996) p. 214

    Google Scholar 

  91. P.M. Lenahan, J.F. Conley: J. Vac Sci. Technol. B 16, 2134 (1998)

    CAS  Google Scholar 

  92. A.G. Revesz, B. Goldstein: Surf. Sci. 14, 361 (1969)

    CAS  Google Scholar 

  93. Y. Nishi: J. Appl. Phys. 10, 52 (1971)

    CAS  Google Scholar 

  94. I. Shiota, N. Miyamoto, J.-I. Nishizawa: J. Appl. Phys. 48, 2556 (1977)

    CAS  Google Scholar 

  95. E.H. Poindexter, E.R. Ahlstrom, P.J. Caplan: In: The Physics of SiO2and its Interfaces, ed. by S.T. Pantilides (Pergamon, New York 1978) p. 227

    Google Scholar 

  96. P.J. Caplan, E.H. Poindexter, B.E. Deal, R.R. Razouk: J. Appl. Phys. 50, 5847 (1979)

    CAS  Google Scholar 

  97. G.J. Gerardi, E.H. Poindexter, P.J. Caplan, N.M. Johnson: Appl. Phys. Lett. 49, 348 (1986)

    CAS  Google Scholar 

  98. D. Sands, K.M. Brunson, M.H. Tayarani-Najaran: Semicond. Sci. Technol. 7, 1091 (1992)

    CAS  Google Scholar 

  99. K.L. Brower: Phys. Rev. B 38, 9657 (1988)

    CAS  Google Scholar 

  100. K.L. Brower: Phys. Rev. B 42, 3444 (1990)

    CAS  Google Scholar 

  101. A. Stesmans, V.V. Afanas’ev: J. Appl. Phys. 83, 2449 (1998)

    CAS  Google Scholar 

  102. A. Stesmans, V.V. Afanas’ev: J. Phys. Condens. Matter 10, L19 (1998)

    CAS  Google Scholar 

  103. A. Stesmans, V.V. Afanas’ev: Micro. Eng. 48, 116 (1999)

    Google Scholar 

  104. A. Stesmans, B. Nouwen, V. Afanas’ev: Phys. Rev. B 58, 15801 (1998)

    CAS  Google Scholar 

  105. E.H. Poindexter, P.J. Caplan: In: Insulating Films on Semiconductors, ed. by M. Schulz, G. Pensl (Springer, Berlin, Heidelberg 1981) p. 150

    Google Scholar 

  106. M. Shulz, G. Pensl: Insulating Films on Semiconductors (Springer, New York 1981)

    Google Scholar 

  107. P.J. Caplan, E.H. Poindexter, B.E. Deal, R.R. Razouk: In: The Physics of MOS Insulators, ed. by G. Lucovsky, S.T. Pantilides, F.L. Galeener (Pergamon, New York 1980) p. 306

    Google Scholar 

  108. W.H. Brattain, J. Bardeen: Bell Syst. Tech. J. 13, 1 (1953)

    Google Scholar 

  109. W.L. Brown: Phys. Rev. 91, 518 (1953)

    CAS  Google Scholar 

  110. E.N. Clarke: Phys. Rev. 91, 756 (1953)

    CAS  Google Scholar 

  111. H.R. Huff: J. Electrochem. Soc. 149, S35 (2002)

    CAS  Google Scholar 

  112. J.T. Law: J. Phys. Chem. 59, 67 (1955)

    CAS  Google Scholar 

  113. J.T. Law, E.E. Francois: J. Phys. Chem. 60, 353 (1956)

    CAS  Google Scholar 

  114. J.T. Law: J. Phys. Chem. 61, 1200 (1957)

    CAS  Google Scholar 

  115. J.T. Law: J. Appl. Phys. 32, 600 (1961)

    CAS  Google Scholar 

  116. P. Balk: Microelectron. Eng. 48, 3 (1999)

    CAS  Google Scholar 

  117. E. Kooi: Philips Res. Rep. 20, 578 (1965)

    CAS  Google Scholar 

  118. P. Balk: Electrochem. Soc. Ext. Abstr. 14(109), 237 (1965)

    Google Scholar 

  119. P. Balk: Electrochem. Soc. Ext. Abs. 14(111), 29 (1965)

    Google Scholar 

  120. P. Balk: J. Electrochem. Soc. 112, 185C (1965)

    Google Scholar 

  121. E. Kooi: Philips Res. Rep. 21, 477 (1966)

    CAS  Google Scholar 

  122. A. Stesmans: Appl. Phys. Lett. 68, 2076 (1996)

    CAS  Google Scholar 

  123. A. Stesmans, V. Afanas’ev: Micro. Eng. 36, 201 (1997)

    CAS  Google Scholar 

  124. K.L. Brower, S.M. Myers: Appl. Phys. Lett. 57, 162 (1999)

    Google Scholar 

  125. A. Stesmans: Phys. Rev. B 48, 2418 (1993)

    CAS  Google Scholar 

  126. A.G. Revesz: J. Electrochem. Soc. 126, 122 (1979)

    CAS  Google Scholar 

  127. G.J. Gerardi, E.H. Poindexter: J. Electronchem. Soc. 136, 588 (1989)

    CAS  Google Scholar 

  128. T.R. Oldham, F.B. McLean, H.E. Boesch Jr., J.M. McGarrity: Semicond. Sci. Technol. 4, 986 (1989)

    CAS  Google Scholar 

  129. A. Stesmans, V. Afanas’ev: Phys. Rev. B 54, 11129 (1996)

    Google Scholar 

  130. E. Wu, B. Linder, J. Stathis, W. Lai: IEEE Tech. Dig. Int. Electron. Dev. Meet., Washington DC (2003) p. 919

    Google Scholar 

  131. D.A. Buchanan: IBM J. Res. Devel. 43, 245 (1999)

    CAS  Google Scholar 

  132. Y. Wu, G. Lucovsky, Y.-M. Lee: IEEE Trans. Electron. Dev. 47, 1361 (2000)

    CAS  Google Scholar 

  133. M. Hillert, S. Jonsson, B. Sundman: Z. Metallkd. 83, 648 (1992)

    CAS  Google Scholar 

  134. D.M. Brown, P.V. Gray, F.K. Heumann, H.R. Philipp, E.A. Taft: J. Electrochem. Soc. 115, 311 (1968)

    CAS  Google Scholar 

  135. E.H. Poindexter, W.L. Warren: J. Electrochem. Soc. 142, 2508 (1995)

    CAS  Google Scholar 

  136. J.T. Yount, P.M. Lenahan, P.W. Wyatt: J. Appl. Phys. 74, 5867 (1993)

    CAS  Google Scholar 

  137. K. Kushida-Abdelghafar, K. Watanabe, T. Kikawa, Y. Kamigaki, J. Ushio: J. Appl. Phys. 92, 2475 (2002)

    CAS  Google Scholar 

  138. G. Lucovsky, T. Yasuda, Y. Ma, S. Hattangady, V. Misra, X.-L. Xu, B. Hornung, J.J. Wortman: J. Non-Cryst. Solids 179, 354 (1994)

    CAS  Google Scholar 

  139. S.V. Hattangady, H. Niimi, G. Lucovsky: Appl. Phys. Lett. 66, 3495 (1995)

    CAS  Google Scholar 

  140. S.V. Hattangady, R. Kraft, D.T. Grider, M.A. Douglas, G.A. Brown, P.A. Tiner, J.W. Kuehne, P.E. Nicollian, M.F. Pas: IEEE Tech. Dig. Int. Electron. Dev. Meet., San Francisco (1996) p. 495

    Google Scholar 

  141. H. Yang, G. Lucovsky: Tech. Dig. Int. Electron. Dev. Meet., Washington DC (1999) p. 245

    Google Scholar 

  142. J.P. Chang, M.L. Green, V.M. Donnelly, R.L. Opila, J. Eng Jr., J. Sapjeta, P.J. Silverman, B. Weir, H.C. Lu, T. Gustafsson, E. Garfunkel: J. Appl. Phys. 87, 4449 (2000)

    CAS  Google Scholar 

  143. S. Guha, E. Cartier, N.A. Bojarczuk, J. Bruley, L. Gignac, J. Karasinski: J. Appl. Phys. 90, 512 (2001)

    CAS  Google Scholar 

  144. S. Miyazaki: J. Vac. Sci. Technol. B 19, 2212 (2001)

    CAS  Google Scholar 

  145. J. Robertson, C.W. Chen: Appl. Phys. Lett. 74, 1168 (1999)

    CAS  Google Scholar 

  146. J. Robertson: J. Vac. Sci. Technol. B 18, 1785 (2000)

    CAS  Google Scholar 

  147. J. Robertson: J. Non-Cryst. Solids 303, 94 (2002)

    CAS  Google Scholar 

  148. H.Y. Yu, M.F. Li, B.J. Cho, C.C. Yeo, M.S. Joo, D.-L. Kwong, J.S. Pan, C.H. Ang, J.Z. Zheng, S. Ramanathan: Appl. Phys. Lett. 81, 376 (2002)

    CAS  Google Scholar 

  149. D.G. Schlom, J.H. Haeni: Mater. Res. Soc. Bull. 27(3), 198 (2002)

    CAS  Google Scholar 

  150. E. Zhu, T.P. Ma, T. Tamagawa, Y. Di, J. Kim, R. Carruthers, M. Gibson, T. Furukawa: IEEE Tech. Dig. Int. Electron. Dev. Meet. (IEEE, Washington DC 2001) p. 20.4.1.

    Google Scholar 

  151. G.D. Wilk, M.L. Green, M.-Y. Ho, B.W. Busch, T.W. Sorsch, F.P. Klemens, B. Brijs, R.B. van Dover, A. Kornblit, T. Gustafsson, E. Garfunkel, S. Hillenius, D. Monroe, P. Kalavade, J.M. Hergenrother: IEEE Tech. Dig. VLSI Symp., Honolulu (2002) p. 88

    Google Scholar 

  152. H. Nohira, W. Tsai, W. Besling, E. Young, J. Petry, T. Conard, W. Vandervorst, S. De Gendt, M. Heyns, J. Maes, M. Tuominen: J. Non-Cryst. Solids 303, 83 (2002)

    CAS  Google Scholar 

  153. M.R. Visokay, J.J. Chambers, A.L.P. Rotondaro, A. Shanware, L. Colombo: Appl. Phys. Lett. 80, 3183 (2002)

    CAS  Google Scholar 

  154. M.S. Akbar, S. Gopalan, H.-J. Cho, K. Onishi, R. Choi, R. Nieh, C.S. Kang, Y.H. Kim, J. Han, S. Krishnan, J.C. Lee: Appl. Phys. Lett. 82, 1757 (2003)

    CAS  Google Scholar 

  155. K. Torii, T. Aoyama, S. Kamiyama, Y. Tamura, S. Miyazaki, H. Kitajima, T. Arikado: Tech. Dig. VLSI Symp., Honolulu (2004) p. 112

    Google Scholar 

  156. R.M. Wallace, G. Wilk: Mater. Res. Soc. Bull. 27(3), 192 (2002), also see this focus issue for reviews of other aspects on gate dielectric issues

    CAS  Google Scholar 

  157. R.M. Wallace, G. Wilk: Critical Rev. Solid State Mater. Sci. 28, 231 (2003)

    CAS  Google Scholar 

  158. G.D. Wilk, R.M. Wallace: Appl. Phys. Lett. 74, 2854 (1999)

    CAS  Google Scholar 

  159. G.D. Wilk, R.M. Wallace: Appl. Phys. Lett. 76, 112 (2000)

    CAS  Google Scholar 

  160. R.M. Wallace, R.A. Stolz, G.D. Wilk: Zirconium and/or hafnium silicon-oxynitride gate, US Patents 6013553, 6020243, 6291866, 6291867 (2000)

    Google Scholar 

  161. G.D. Wilk, R.M. Wallace, J.M. Anthony: J. Appl. Phys. 87, 484 (2000)

    CAS  Google Scholar 

  162. A.L.P. Rotondaro, M.R. Visokay, J.J. Chambers, A. Shanware, R. Khamankar, H. Bu, R.T. Laaksonen, L. Tsung, M. Douglas, R. Kuan, M.J. Bevan, T. Grider, J. McPherson, L. Colombo: Symp. VLSI Technol. Tech. Dig. Papers, Honolulu (2002) p. 148

    Google Scholar 

  163. R. Chau, S. Datta, M. Doczy, B. Doyle, J. Kavalieros, M. Metz: IEEE Elec. Dev. Lett. 25(6), 408 (2004)

    CAS  Google Scholar 

  164. T. Poletti: Biggest advances in chips in 40 years, EE-Times, January 26 2007

    Google Scholar 

  165. D. Scansen: 45nm: What Intel didn’t tell you, EE Times, June 23 2008

    Google Scholar 

  166. Y.-C. Yeo: Thin Solids Films 462-3, 34 (2004)

    Google Scholar 

  167. M.V. Fischetti, D.A. Nuemayer, E.A. Cartier: J. Appl. Phys. 90, 4587 (2001)

    CAS  Google Scholar 

  168. R.M.C. de Almeida, I.J.R. Baumvol: Surf. Sci. Rep. 49, 1 (2003)

    Google Scholar 

  169. M. Quevedo-Lopez, M. El-Bouanani, M.J. Kim, B.E. Gnade, M.R. Visokay, A. LiFatou, M.J. Bevan, L. Colombo, R.M. Wallace: Appl. Phys. Lett. 81, 1609 (2002)

    CAS  Google Scholar 

  170. M. Quevedo-Lopez, M. El-Bouanani, M.J. Kim, B.E. Gnade, M.R. Visokay, A. LiFatou, M.J. Bevan, L. Colombo, R.M. Wallace: Appl. Phys. Lett. 82, 4669 (2003)

    CAS  Google Scholar 

  171. M.-Y. Ho, H. Gong, G.D. Wilk, B.W. Busch, M.L. Green, W.H. Lin, A. See, S.K. Lahiri, M.E. Loomans, P.I. Räisänen, T. Gustafsson: Appl. Phys. Lett. 81, 4218 (2002)

    CAS  Google Scholar 

  172. S. Guha, E.P. Gusev, H. Okorn-Schmidt, M. Copel, L.Å. Ragnarsson, N.A. Bojarczuk: Appl. Phys. Lett. 81, 2956 (2002)

    CAS  Google Scholar 

  173. Y.-C. Yeo, T.-J. King, C. Hu: J. Appl. Phys. 92, 7266 (2002)

    CAS  Google Scholar 

  174. I.S. Jeon, J. Lee, P. Zhao, P. Sivasubramani, T. Oh, H.J. Kim, D. Cha, J. Huang, M.J. Kim, B.E. Gnade, J. Kim, R.M. Wallace: IEEE Tech. Dig. Int. Electron. Dev. Meet. (IEEE, San Francisco 2004)

    Google Scholar 

  175. P.C. Fazan: Integr. Ferroelectr. 4, 247 (1994)

    CAS  Google Scholar 

  176. H. Schichijo: In: ULSI Devices, ed. by C.Y. Chang, S.M. Sze (Wiley, New York 2000) Chap. 7

    Google Scholar 

  177. P.J. Harrop, D.S. Campbell: Thin Solid Films 2, 273 (1968)

    CAS  Google Scholar 

  178. D.-S. Kil, H.-S. Song, K.-J. Lee, K. Hong, J.-H. Kim, K.-S. Park, S.-J. Yeom, J.-S. Roh, N.-J. Kwak, H.-C. Sohn, J.-W. Kim, S.-W. Park: Symp. VLSI Technology Digest of Technical Papers (2006) p. 38

    Google Scholar 

  179. For example, see Texas Instruments FRAM products at: http://www.ti.com/lsds/ti/microcontrollers_16-bit_32-bit/msp/ultra-low_power/msp430frxx_fram/what_is_fram.page?DCMP=FRAM&HQS=fram

  180. G.F. Derbenwick, A.F. Isaacson: IEEE Circuits Dev. 20, 20 (2001)

    Google Scholar 

  181. S. S. Chung, P.-Y. Chiang, G. Chou, C.-T. Huang, P. Chen, C.-H. Chu, C.C.-H. Hsu: Tech. Dig. Int. Electron. Dev. Meet. (IEEE, Washington DC 2003) p. 26.6.1.

    Google Scholar 

  182. B. De Salvo: Tech. Dig. Int. Electron. Dev. Meet. (IEEE, Washington DC 2003) p. 26.1.1.

    Google Scholar 

  183. A.R. Krauss, A. Dhote, O. Auciello, J. Im, R. Ramesh, A. Aggarwal: Integr. Ferroelectr. 27, 147 (1999)

    Google Scholar 

  184. J. Im, O. Auciello, A.R. Krauss, D.M. Gruen, R.P.H. Chang, S.H. Kim, A.I. Kingon: Appl. Phys. Lett. 74, 1162 (1999)

    CAS  Google Scholar 

  185. N. Poonawala, V.P. Dravid, O. Auciello, J. Im, A.R. Krauss: J. Appl. Phys. 87, 2227 (2000)

    CAS  Google Scholar 

  186. T. Mikolajick, C. Dehm, W. Hartner, I. Kasko, M.J. Kastner, N. Nagel, M. Moert, C. Mazure: Microelect. Rel. 41, 947 (2001)

    Google Scholar 

  187. H. Kohlstedt, Y. Mustafa, A. Gerber, A. Petraru, M. Fitsilis, R. Meyer, U. Böttger, R. Waser: Microelec. Eng. 80, 296 (2005)

    CAS  Google Scholar 

  188. A. Chowdhury, J. Kim, R.M. Wallace: Proc. IEEE 8th Ann. Non-Volatile Mem. Tech. Symp. (2007) p. 48

    Google Scholar 

  189. Y. Shacham-Diamand, T. Osaka, M. Datta, T. Ohba (Eds.): Advanced Nanoscale ULSI Interconnects: Fundamentals and Applications (Springer Science+Business Media, New York 2009)

    Google Scholar 

Download references

Acknowledgements

RMW gratefully acknowledges the many discussions and hard work of his colleagues and students engaged in gate-stack research. This work is supported in part by the Erik Jonsson Distinguished Chair at the University of Texas at Dallas.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Robert M. Wallace .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2017 Springer International Publishing AG

About this chapter

Cite this chapter

Wallace, R.M. (2017). Dielectric Materials for Microelectronics. In: Kasap, S., Capper, P. (eds) Springer Handbook of Electronic and Photonic Materials. Springer Handbooks. Springer, Cham. https://doi.org/10.1007/978-3-319-48933-9_27

Download citation

Publish with us

Policies and ethics