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Thermal Analysis pp 87–92Cite as

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Enthalpimetric Measurements in Solid-Solid Reactions. III. The Uranylnitrate-Phenylurea System

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Abstract

Solid UO2(NO3)2.6H2O, at suitable temperature, reacts with solid Phenylurea (Ph). By using a 1:2 stoichiometric ratio UO2(NO3)2Ph2 is obtained. This compound for reaction with Ph gives several other complexes. DSC is used to study the reactions: UO2(NO3)2Phn + mPh → UO2(NO3)2Phn+m (where n = 2÷5 m = 1÷4; n+m =3÷6). The enthalpic values were determined and rationalized.

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References

  1. P. S. Gentile and L. S. Campisi, J. Inorg. Nucl. Chem. 27 (1965) 2291.

    Article  Google Scholar 

  2. P.S. Gentile and T. L. Mao, J. Inorg. Nucl. Chem. 27 (1965) 867.

    Article  Google Scholar 

  3. P. S. Gentile and L. H. Talley, J. Am. Chem. Soc. 79 (1957) 4296.

    Article  Google Scholar 

  4. G. Cohn, Chem. Rev. 42 (1948) 527.

    Article  Google Scholar 

  5. F. Feigl, L. I. Miranda and H. A. Suter, J. Chem. Educ. 21 (1944) 18.

    Article  Google Scholar 

  6. G. Siracusa, A. Seminara, V. Cucinotta and S. Gurrieri, Thermochim. Acta 23 (1978) 109.

    Article  Google Scholar 

  7. L. Abate and G. Siracusa, Thermochim. Acta 23 (1978) 157.

    Google Scholar 

  8. A. V. Nikolaev, A. A. Opalovsky and V. E. Fedorov, Thermal Analysis, Vol. 2, p. 793, Ed. R. F. Schwenker and P. D. Garn Academic Press, 1969.

    Google Scholar 

  9. G. Siracusa and L. Abate, in press on Thermochim. Acta.

    Google Scholar 

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Authors and Affiliations

  1. Istituto Dipartimentale di Chimica e Chimica Industriale, l’Università di Catania, Viale A. Doria, 8, 95125, Catania, Italy

    G. Siracusa, L. Abate & S. Gurrieri

Authors
  1. G. Siracusa
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  2. L. Abate
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  3. S. Gurrieri
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Editor information

Editors and Affiliations

  1. Institut für Werkstoffkunde, Universität Braunschweig, Federal Republic of Germany

    W. Hemminger

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© 1980 Springer Basel AG

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Siracusa, G., Abate, L., Gurrieri, S. (1980). Enthalpimetric Measurements in Solid-Solid Reactions. III. The Uranylnitrate-Phenylurea System. In: Hemminger, W. (eds) Thermal Analysis. Birkhäuser, Basel. https://doi.org/10.1007/978-3-0348-6736-8_12

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  • DOI: https://doi.org/10.1007/978-3-0348-6736-8_12

  • Publisher Name: Birkhäuser, Basel

  • Print ISBN: 978-3-0348-6737-5

  • Online ISBN: 978-3-0348-6736-8

  • eBook Packages: Springer Book Archive

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