Abstract
Understanding the characteristic of adsorbent media is important to assess their compositions, particle size, morphology and the functional group. In this study, limestone was selected as adsorbent media in removing iron (Fe) and manganese (Mn) in groundwater. The characteristic of limestone was analysed using XRD, XRF, FTIR, FESEM and surface area analyser. Analysis on minerals composition detected that limestone that has been used in this study contain major portion of CaCO3 (97.91%) and can be classified as high purity limestone. Based on the FTIR analysis of the raw limestone, it shows that the presence of hydroxyl group with O–H stretching is a favourable group of Fe and Mn adsorption. In addition, some crack between calcites connection and voids were found on the SEM image of raw limestone sample. Comparatively, the surface morphology of limestone after adsorption process presented that more crystal grains (ferrihydrite particle) were completely covered to the surface of limestone. A new manganese oxide (MnOx) also appeared at 585 cm−1 through Mn stretching, proving the occurrence of Mn adsorption process in groundwater. Therefore, limestone has the capability to remove Fe and Mn for groundwater and provide good filter media for heavy metal groundwater treatment. Due to the superior characteristic of limestone, this media offers a good alternative for Fe and Mn removal in groundwater.
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References
Aredes S, Klein B, Pawlik M (2013) The removal of arsenic from water using natural iron oxide minerals. J Clean Prod 60:71–76
Atieh MA, Bakather OY, Al-Tawbini B, Bukhari AA, Abuilaiwi FA, Fettouhi MB (2010) Effect of carboxylic functional group functionalized on carbon nanotubes surface on the removal of lead from water. Bioinorg Chem Appl
Aziz HA, Yusoff MS, Adlan MN, Adnan NH, Alias S (2004) Physico-chemical removal of iron from semi-aerobic landfill leachate by limestone filter. Waste Manag 24(4):353–358
Aziz HA, Adlan MN, Ariffin KS (2008) Heavy metals (Cd, Pb, Zn, Ni, Cu and Cr(III)) removal from water in Malaysia: post treatment by high quality limestone. Bioresour Technol 99(6):1578–1583
Aziz HA, Smith PG (1992) The influence of pH and coarse media on manganese precipitation from water. Water Res 26(6):853–855
Bhatnagar A, Sillanpää M, Witek-Krowiak A (2015) Agricultural waste peels as versatile biomass for water purification—a review. Chem Eng J 270(2015):244–271
Chakravarty S, Dureja V, Bhattacharyya G, Maity S, Bhattacharjee S (2002) Removal of arsenic from groundwater using low cost ferruginous manganese ore. Water Res 36(3):625–632
Guo H, Stüben D, Berner Z (2007) Adsorption of arsenic (III) and arsenic(V) from groundwater using natural siderite as the adsorbent. J Colloid Interf Sci 315(1):47–53
Hussain S, Aziz HA, Isa MH, Adlan MN, Asaari FAH (2007) Physico-chemical method for ammonia removal from synthetic wastewater using limestone and GAC in batch and column studies. Biores Technol 98(4):874–880
Lopez JA, González F, Bonilla FA, Zambrano G, Gómez ME (2010) Synthesis and characterization of Fe3O4 magnetic nanofluid. Revista Latinoamericana de Metalurgia Materiales 30(60):60–66
Mitchell C (2011) High purity limestone quest. Ind Min, pp 48–51
Parikh SJ, Chorover J (2005) FTIR spectroscopic study of biogenic Mn-oxide formation by Pseudomonas putida GB-1. Geomicrob J 22(5):207–218
Rath SS, Singh S, Rao DS, Nayak BB, Mishra BK (2017) Adsorption of heavy metals on a complex Al-Si-O bearing mineral system: insights from theory and experiments. Sep Purif Technol 186:28–38
Tebo BM, Bargar JR, Clement BG, Dick GJ, Murray KJ, Parker D, Verity R, Webb SM (2004) Biogenic manganese oxides: properties and mechanisms of formation. Ann Rev Earth Planet Sci 32:287–328
Tseng R (2007) Physical and chemical properties and adsorption type of activated carbon prepared from plum kernels by NaOH activation 147:1020–1027
Wang Y, Sikora S, Kim H, Boyer TH, Bonzongo J-C, Townsend TG (2013) Effects of solution chemistry on the removal reaction between calcium carbonate-based materials and Fe(II). Sci Total Environ 443:717–724
Zhang Y, Sun Q, Geng J (2017) Microstructural characterization of limestone exposed to heat with XRD SEM and TG-DSC. Mater Charact 134(March):285–295
Žic M, Ristić M, Musić S (2007) 57Fe Mössbauer, FT-IR and FE SEM investigation of the formation of hematite and goethite at high pH values. J Mol Struct 834:141–149
Acknowledgements
The authors would like to thank the Long-term Research Grant Scheme (LRGS) under Protection of Drinking Water for Society: Source of Abstraction Treatment for the financial support for the research. The authors thank to the Universiti Sains Malaysia and Universiti Teknologi MARA Cawangan Pulau Pinang for their helps and support in this research.
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Akbar, N.A., Aziz, H.A., Adlan, M.N. (2020). Characteristic Study of Physical and Chemical Properties of Limestone Subjected to Adsorption of Fe and Mn in Groundwater. In: Mohamed Nazri, F. (eds) Proceedings of AICCE'19. AICCE 2019. Lecture Notes in Civil Engineering, vol 53. Springer, Cham. https://doi.org/10.1007/978-3-030-32816-0_43
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