Abstract
Generally, organic/inorganic nanocomposites consist of organic polymers incorporated with inorganic fillers in nanoscale. They integrate the benefits of the inorganic materials (e.g. thermal and chemical stability, stiffness) and the organic polymers (e.g., dielectric, flexibility, processability, and ductility). Recently, polymer-Si nanocomposites have received considerable attention and have been applied in many different applications. Proton-exchange membrane fuel cells (PEMFCs) have appeared as an environmentally friendly device to meet the energy demands of the recent years. Nafion® is a commonly recognized and commercialized membrane which offers exceptional electrochemical attributes below 80 °C, and under extremely humidified environments. Nevertheless, a reduction in the proton conductivity of Nafion® over 80 °C and decreased humidity, as well as expensive membrane price, has motivated the progress of novel membranes. The incorporation of fillers, particularly nano-sized Si particulates, to the polymeric matrix was employed to partially resolve the problems. Thus, this account will provide a broad summary of the methods and techniques employed for the nanocomposites preparation as well as a short explanation about their properties, characterizations, and applications. In-depth explanations of particular subjects can be found in related references.
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Rezakazemi M, Shahidi K, Mohammadi T (2012) Hydrogen separation and purification using crosslinkable PDMS/zeolite A nanoparticles mixed matrix membranes. Int J Hydrogen Energy 37:14576–14589
Rezakazemi M, Sadrzadeh M, Mohammadi T, Matsuura T (2017) Methods for the preparation of organic–inorganic nanocomposite polymer electrolyte membranes for fuel cells. In: Inamuddin D, Mohammad A, Asiri AM (eds) Organic-inorganic composite polymer electrolyte membranes: preparation, properties, and fuel cell applications. Springer International Publishing, Cham, pp 311–325
Baheri B, Shahverdi M, Rezakazemi M, Motaee E, Mohammadi T (2015) Performance of PVA/NaA mixed matrix membrane for removal of water from ethylene glycol solutions by pervaporation. Chem Eng Commun 202:316–321
Shahverdi M, Baheri B, Rezakazemi M, Motaee E, Mohammadi T (2013) Pervaporation study of ethylene glycol dehydration through synthesized (PVA–4A)/polypropylene mixed matrix composite membranes. Polym Eng Sci 53:1487–1493
Rezakazemi M, Ebadi Amooghin A, Montazer-Rahmati MM, Ismail AF, Matsuura T (2014) State-of-the-art membrane based CO2 separation using mixed matrix membranes (MMMs): an overview on current status and future directions. Prog Polym Sci 39 817–861
Rostamizadeh M, Rezakazemi M, Shahidi K, Mohammadi T (2013) Gas permeation through H2-selective mixed matrix membranes: Experimental and neural network modeling. Int J Hydrogen Energy 38:1128–1135
Rezakazemi M, Mohammadi T (2013) Gas sorption in H2-selective mixed matrix membranes: Experimental and neural network modeling. Int J Hydrogen Energy 38:14035–14041
Rezakazemi M, Dashti A, Asghari M, Shirazian S (2017) H2-selective mixed matrix membranes modeling using ANFIS, PSO-ANFIS, GA-ANFIS. Int J Hydrogen Energy 42:15211–15225
Rezakazemi M, Shahidi K, Mohammadi T (2012) Sorption properties of hydrogen-selective PDMS/zeolite 4A mixed matrix membrane. Int J Hydrogen Energy 37:17275–17284
Rezakazemi M, Vatani A, Mohammadi T (2015) Synergistic interactions between POSS and fumed silica and their effect on the properties of crosslinked PDMS nanocomposite membranes. RSC Adv 5:82460–82470
Rezakazemi M, Vatani A, Mohammadi T (2016) Synthesis and gas transport properties of crosslinked poly(dimethylsiloxane) nanocomposite membranes using octatrimethylsiloxy POSS nanoparticles. J Nat Gas Sci Eng 30:10–18
Zou H, Wu S, Shen J (2008) Polymer/silica nanocomposites: preparation, characterization, properties, and applications. Chem Rev 108:3893–3957
Rezakazemi M, Maghami M, Mohammadi T (2018) High loaded synthetic hazardous wastewater treatment using lab-scale submerged ceramic membrane bioreactor. Periodica Polytech, Chem Eng 62:299–304
Schadler LS, Kumar SK, Benicewicz BC, Lewis SL, Harton SE (2007) Designed interfaces in polymer nanocomposites: a fundamental viewpoint. MRS Bull 32:335–340
Rezakazemi M, Shahverdi M, Shirazian S, Mohammadi T, Pak A (2011) CFD simulation of water removal from water/ethylene glycol mixtures by pervaporation. Chem Eng J 168:60–67
Rezakazemi M, Sadrzadeh M, Matsuura T (2018) Thermally stable polymers for advanced high-performance gas separation membranes. Prog Energy Combust Sci 66:1–41
Mura F, Silva R, Pozio A (2007) Study on the conductivity of recast Nafion®/montmorillonite and Nafion®/TiO 2 composite membranes. Electrochim Acta 52:5824–5828
Park KT, Jung UH, Choi DW, Chun K, Lee HM, Kim SH (2008) ZrO 2–SiO 2/Nafion® composite membrane for polymer electrolyte membrane fuel cells operation at high temperature and low humidity. J Power Sources 177:247–253
Aparicio M, Mosa J, Etienne M, Durán A (2005) Proton-conducting methacrylate–silica sol–gel membranes containing tungstophosphoric acid. J Power Sources 145:231–236
Di Vona M, Sgreccia E, Donnadio A, Casciola M, Chailan J, Auer G, Knauth P (2011) Composite polymer electrolytes of sulfonated poly-ether-ether-ketone (SPEEK) with organically functionalized TiO 2. J Membr Sci 369:536–544
Zhengbang W, Tang H, Mu P (2011) Self-assembly of durable Nafion/TiO 2 nanowire electrolyte membranes for elevated-temperature PEM fuel cells. J Membr Sci 369:250–257
Rezakazemi M, Zhang Z (2018) 2.29 Desulfurization Materials A2—Dincer, Ibrahim. In: Comprehensive energy systems. Elsevier, Oxford, pp 944–979
Hashemi F, Rowshanzamir S, Rezakazemi M (2012) CFD simulation of PEM fuel cell performance: Effect of straight and serpentine flow fields. Math Comput Model 55:1540–1557
Cong H, Radosz M, Towler BF, Shen Y (2007) Polymer–inorganic nanocomposite membranes for gas separation. Sep Purif Technol 55:281–291
Ajayan PM, Schadler LS, Braun PV (2006) Nanocomposite science and technology. Wiley
Xing D, He G, Hou Z, Ming P, Song S (2011) Preparation and characterization of a modified montmorillonite/sulfonated polyphenylether sulfone/PTFE composite membrane. Int J Hydrogen Energy 36:2177–2183
Cho Y-H, Kim S-K, Kim T-H, Cho Y-H, Lim JW, Jung N, Yoon W-S, Lee J-C, Sung Y-E (2011) Preparation of MEA with the polybenzimidazole membrane for high temperature PEM fuel cell. Electrochem Solid-State Lett 14:B38–B40
Tago T, Kuwashiro N, Nishide H (2007) Preparation of acid-functionalized poly (phenylene oxide) s and poly (phenylene sulfone) and their proton conductivity. Bulletin of the Chem Soc Jpn 80:1429–1434
Sodeifian G, Raji M, Asghari M, Rezakazemi M, Dashti A (2018) Polyurethane-SAPO-34 mixed matrix membrane for CO2/CH4 and CO2/N2 separation. Chin J Chem Eng
Rezakazemi M, Razavi S, Mohammadi T, Nazari AG (2011) Simulation and determination of optimum conditions of pervaporative dehydration of isopropanol process using synthesized PVA–APTEOS/TEOS nanocomposite membranes by means of expert systems. J Membr Sci 379:224–232
Gómez-Romero P, Sanchez C, Functional hybrid materials. Wiley (2006)
Zhang S, Xu T, Wu C (2006) Synthesis and characterizations of novel, positively charged hybrid membranes from poly (2, 6-dimethyl-1, 4-phenylene oxide). J Membr Sci 269:142–151
Wu C, Xu T, Yang W (2005) Synthesis and characterizations of novel, positively charged poly (methyl acrylate)–SiO 2 nanocomposites. Eur Polymer J 41:1901–1908
Saito R, Kobayashi S-I, Hayashi H, Shimo T (2007) Surface hardness and transparency of poly(methyl methacrylate)-silica coat film derived from perhydropolysilazane. J Appl Polym Sci 104:3388–3395
Shen L, Du Q, Wang H, Zhong W, Yang Y (2004) In situ polymerization and characterization of polyamide-6/silica nanocomposites derived from water glass. Polym Int 53:1153–1160
Ding X, Jiang Y, Yu K, Hari B, Tao N, Zhao J, Wang Z (2004) Silicon dioxide as coating on polystyrene nanoparticles in situ emulsion polymerization. Mater Lett 58:1722–1725
Laugel N, Hemmerlé J, Porcel C, Voegel J-C, Schaaf P, Ball V (2007) Nanocomposite silica/polyamine films prepared by a reactive layer-by-layer deposition. Langmuir 23:3706–3711
Grund S, Kempe P, Baumann G, Seifert A, Spange S (2007) Nanocomposites prepared by twin polymerization of a single-source monomer. Angew Chem Int Ed 46:628–632
Suffner J, Schechner G, Sieger H, Hahn H (2007) In-situ coating of silica nanoparticles with acrylate-based polymers. Chem Vap Deposition 13:459–464
Senkevich JJ, Desu SB (1999) Near-room-temperature thermal chemical vapor deposition of poly(chloro-p-xylylene)/SiO2 nanocomposites. Chem Mater 11:1814–1821
Mishra AK, Chattopadhyay S, Rajamohanan P, Nando GB (2011) Effect of tethering on the structure-property relationship of TPU-dual modified Laponite clay nanocomposites prepared by ex-situ and in-situ techniques. Polymer 52:1071–1083
Seo W, Sung Y, Han S, Kim Y, Ryu O, Lee H, Kim WN (2006) Synthesis and properties of polyurethane/clay nanocomposite by clay modified with polymeric methane diisocyanate. J Appl Polym Sci 101:2879–2883
Mishra AK, Rajamohanan P, Nando GB, Chattopadhyay S (2011) Structure–property of thermoplastic polyurethane–clay nanocomposite based on covalent and dual-modified Laponite. Adv Sci Lett 4:65–73
Mishra A, Nando G, Chattopadhyay S (2008) Exploring preferential association of laponite and cloisite with soft and hard segments in TPU-clay nanocomposite prepared by solution mixing technique. J Polym Sci, Part B: Polym Phys 46:2341–2354
Aparicio M, Durán A (2004) Hybrid organic/inorganic sol-gel materials for proton conducting membranes. J Sol-Gel Sci Technol 31:103–107
Aparicio M, Castro Y, Duran A (2005) Synthesis and characterisation of proton conducting styrene-co-methacrylate–silica sol–gel membranes containing tungstophosphoric acid. Solid State Ionics 176:333–340
Tillet G, Boutevin B, Ameduri B (2011) Chemical reactions of polymer crosslinking and post-crosslinking at room and medium temperature. Prog Polym Sci 36:191–217
Lin B, Cheng S, Qiu L, Yan F, Shang S, Lu J (2010) Protic ionic liquid-based hybrid proton-conducting membranes for anhydrous proton exchange membrane application. Chem Mater 22:1807–1813
Darbandi M, Thomann R, Nann T (2007) Hollow silica nanospheres: in situ, semi-in situ, and two-step synthesis. Chem Mater 19:1700–1703
Stöber W, Fink A, Bohn E (1968) Controlled growth of monodisperse silica spheres in the micron size range. J Colloid Interface Sci 26:62–69
Bronstein LM, HCD, Kim G (Ed) (2004) Dekker encyclopedia of nanoscience and nanotechnology. Taylor & Francis, New York, pp 1–10
Osseo-Asare K, Arriagada F (1990) Preparation of SiO2 nanoparticles in a non-ionic reverse micellar system. Colloids Surf 50:321–339
Vassiliou AA, Papageorgiou GZ, Achilias DS, Bikiaris DN (2007) Non-Isothermal Crystallisation Kinetics of In Situ Prepared Poly (ε-caprolactone)/Surface-Treated SiO2 Nanocomposites. Macromol Chem Phys 208:364–376
Jana SC, Jain S (2001) Dispersion of nanofillers in high performance polymers using reactive solvents as processing aids. Polymer 42:6897–6905
Nalwa HS (2003) Handbook of organic-inorganic hybrid materials and nanocomposites. In: Zhang MQR, MZ, Friedrich K (Ed) American Scientific Publishers, California, pp 113–150
Blum FD (2004) Encyclopedia of polymer science and technology, concise. In: Kroschwitz JI (Ed) Wiley, pp 38–50
Gomes D, Buder I, Nunes SP (2006) Sulfonated silica-based electrolyte nanocomposite membranes. J Polym Sci, Part B: Polym Phys 44:2278–2298
Wu T-M, Chu M-S (2005) Preparation and characterization of thermoplastic vulcanizate/silica nanocomposites. J Appl Polym Sci 98:2058–2063
Ahn SH, Kim SH, Lee SG (2004) Surface-modified silica nanoparticle–reinforced poly(ethylene 2, 6-naphthalate). J Appl Polym Sci 94:812–818
Lai YH, Kuo MC, Huang JC, Chen M (2007) On the PEEK composites reinforced by surface-modified nano-silica. Mater Sci Eng, A 458:158–169
Rong MZ, Zhang MQ, Zheng YX, Zeng HM, Walter R, Friedrich K (2001) Structure–property relationships of irradiation grafted nano-inorganic particle filled polypropylene composites. Poly 42:167–183
Rong MZ, Zhang MQ, Zheng YX, Zeng HM, Friedrich K (2001) Improvement of tensile properties of nano-SiO2/PP composites in relation to percolation mechanism. Polymer 42:3301–3304
Wu CL, Zhang MQ, Rong MZ, Friedrich K (2002) Tensile performance improvement of low nanoparticles filled-polypropylene composites. Compos. Sci. Technol. 62:1327–1340
Zhang MQ, Rong MZ, Zhang HB, Friedrich K (2003) Mechanical properties of low nano-silica filled high density polyethylene composites. Polym Eng Sci 43:490–500
Wu CL, Zhang MQ, Rong MZ, Friedrich K (2005) Silica nanoparticles filled polypropylene: effects of particle surface treatment, matrix ductility and particle species on mechanical performance of the composites. Compos. Sci. Technol. 65:635–645
Ruan WH, Huang XB, Wang XH, Rong MZ, Zhang MQ (2006) Effect of drawing induced dispersion of nano-silica on performance improvement of poly(propylene)-based nanocomposites. Macromol Rapid Commun 27:581–585
Zhu Y, Li Z, Zhang D, Tanimoto T (2006) PET/SiO2 nanocomposites prepared by cryomilling. J Polym Sci, Part B: Polym Phys 44:1161–1167
Zhu Y-G, Li Z-Q, Zhang D, Tanimoto T (2006) Thermal behaviors of poly(ethylene terephthalate)/SiO2 nanocomposites prepared by cryomilling. J Polym Sci, Part B: Polym Phys 44:1351–1356
Petrovicova E, Knight R, Schadler L, Twardowski T (2000) Nylon 11/silica nanocomposite coatings applied by the HVOF process. II. Mechanical and barrier properties. J. Appl. Polym. Sci. 78:2272–2289
Petrovicova E, Knight R, Schadler L, Twardowski T (2000) Nylon 11/silica nanocomposite coatings applied by the HVOF process. I. Microstructure and morphology. J. Appl. Polym. Sci. 77:1684–1699
Schadler LS, Laut KO, Smith RW, Petrovicova E (1997) Microstructure and mechanical properties of thermally sprayed silica/nylon nanocomposites. J Therm Spray Technol 6:475–485
Jafari H, Emami S, Mahmoudi Y (2017) Numerical investigation of dual-stage high velocity oxy-fuel (HVOF) thermal spray process: a study on nozzle geometrical parameters. Appl Therm Eng 111:745–758
Sinha Ray S, Okamoto M (2003) Polymer/layered silicate nanocomposites: a review from preparation to processing. Prog. Polym. Sci. 28:1539–1641
Shang X-Y, Zhu Z-K, Yin J, Ma X-D (2002) Compatibility of soluble polyimide/silica hybrids induced by a coupling agent. Chem Mater 14:71–77
Kashiwagi T, Morgan AB, Antonucci JM, VanLandingham MR, Harris RH, Awad WH, Shields JR (2003) Thermal and flammability properties of a silica–poly(methylmethacrylate) nanocomposite. J Appl Polym Sci 89:2072–2078
Crosby AJ, Lee JY (2007) Polymer Nanocomposites: the “Nano” effect on mechanical properties. Polym Rev 47:217–229
Mammeri F, Bourhis EL, Rozes L, Sanchez C (2005) Mechanical properties of hybrid organic-inorganic materials. J Mater Chem 15:3787–3811
Lach R, Kim G-M, Michler GH, Grellmann W, Albrecht K (2006) Indentation fracture mechanics for toughness assessment of PMMA/SiO2 nanocomposites. Macromol Mater Eng 291:263–271
Joseph J, Tseng C-Y, Hwang B-J (2011) Phosphonic acid-grafted mesostructured silica/Nafion hybrid membranes for fuel cell applications. J Power Sources 196:7363–7371
Kumar GG, Kim A, Nahm KS, Elizabeth R (2009) Nafion membranes modified with silica sulfuric acid for the elevated temperature and lower humidity operation of PEMFC. IJHE 34:9788–9794
Choi Y, Kim Y, Kim HK, Lee JS (2010) Direct synthesis of sulfonated mesoporous silica as inorganic fillers of proton-conducting organic–inorganic composite membranes. J Membr Sci 357:199–205
Choi J, Wycisk R, Zhang W, Pintauro PN, Lee KM, Mather PT (2010) High Conductivity Perfluorosulfonic Acid Nanofiber Composite Fuel-Cell Membranes. Chemsuschem 3:1245–1248
Kim Y, Choi Y, Kim HK, Lee JS (2010) New sulfonic acid moiety grafted on montmorillonite as filler of organic–inorganic composite membrane for non-humidified proton-exchange membrane fuel cells. J Power Sources 195:4653–4659
Bébin P, Caravanier M, Galiano H (2006) Nafion®/clay-SO 3 H membrane for proton exchange membrane fuel cell application. J Membr Sci 278:35–42
Buquet CL, Fatyeyeva K, Poncin-Epaillard F, Schaetzel P, Dargent E, Langevin D, Nguyen QT, Marais S (2010) New hybrid membranes for fuel cells: plasma treated laponite based sulfonated polysulfone. J Membr Sci 351:1–10
Choi J, Lee KM, Wycisk R, Pintauro PN, Mather PT (2010) Sulfonated polysulfone/POSS nanofiber composite membranes for PEM fuel cells. JElS 157:B914–B919
Zhang Y, Wang S, Xiao M, Bian S, Meng Y (2009) The silica-doped sulfonated poly (fluorenyl ether ketone) s membrane using hydroxypropyl methyl cellulose as dispersant for high temperature proton exchange membrane fuel cells. IJHE 34:4379–4386
Liu Y-L (2009) Preparation and properties of nanocomposite membranes of polybenzimidazole/sulfonated silica nanoparticles for proton exchange membranes. J Membr Sci 332:121–128
Quartarone E, Magistris A, Mustarelli P, Grandi S, Carollo A, Zukowska G, Garbarczyk J, Nowinski J, Gerbaldi C, Bodoardo S (2009) Pyridine-based PBI composite membranes for PEMFCs. Fuel Cells 9:349–355
Cui X, Zhong S, Wang H (2007) Organic–inorganic hybrid proton exchange membranes based on silicon-containing polyacrylate nanoparticles with phosphotungstic acid. J Power Sources 173:28–35
Adjemian K, Lee S, Srinivasan S, Benziger J, Bocarsly A (2002) Silicon oxide nafion composite membranes for proton-exchange membrane fuel cell operation at 80–140 C. JElS 149:A256–A261
Pereira F, Vallé K, Belleville P, Morin A, Lambert S, Sanchez C (2008) Advanced mesostructured hybrid silica−nafion membranes for high-performance PEM fuel cell. Chem Mater 20:1710–1718
Mulmi S, Park CH, Kim HK, Lee CH, Park HB, Lee YM (2009) Surfactant-assisted polymer electrolyte nanocomposite membranes for fuel cells. J Membr Sci 344:288–296
Shao Z-G, Joghee P, Hsing I-M (2004) Preparation and characterization of hybrid Nafion–silica membrane doped with phosphotungstic acid for high temperature operation of proton exchange membrane fuel cells. J Membr Sci 229:43–51
Chang J-H, Park JH, Park G-G, Kim C-S, Park OO (2003) Proton-conducting composite membranes derived from sulfonated hydrocarbon and inorganic materials. J Power Sources 124:18–25
Wilhelm M, Jeske M, Marschall R, Cavalcanti WL, Tölle P, Köhler C, Koch D, Frauenheim T, Grathwohl G, Caro J (2008) New proton conducting hybrid membranes for HT-PEMFC systems based on polysiloxanes and SO 3 H-functionalized mesoporous Si-MCM-41 particles. J Membr Sci 316:164–175
Kim YM, Choi SH, Lee HC, Hong MZ, Kim K, Lee H-I (2004) Organic–inorganic composite membranes as addition of SiO2 for high temperature-operation in polymer electrolyte membrane fuel cells (PEMFCs). Electrochim Acta 49:4787–4796
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Rezakazemi, M., Dashti, A., Hajilary, N., Shirazian, S. (2019). Organic/Silica Nanocomposite Membranes Applicable to Green Chemistry. In: Inamuddin, Thomas, S., Kumar Mishra, R., Asiri, A. (eds) Sustainable Polymer Composites and Nanocomposites. Springer, Cham. https://doi.org/10.1007/978-3-030-05399-4_22
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