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Effect of Solute on the Nucleation and Propagation of Ice

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Book cover Water Relationships in Foods

Part of the book series: Advances in Experimental Medicine and Biology ((AEMB,volume 302))

Abstract

Using the emulsion technique, we have studied nucleation of ice in aqueous solutions containing silver iodide or Pseudomonas syringae. Using a Differential Scanning Calorimeter (DSC), we determined characteristic temperatures of nucleation, and also rates of nucleation at selected temperatures. The freezing point depression induced by added solute is linearly related to the lowering of both homogeneous and heterogeneous nucleation temperature. Nucleation kinetics depend on a fifth power function of the temperature. Solute is found to affect the parameters of this relationship in different ways, dependent upon the nature of the catalytic site for ice nucleation. We have also studied the effect of composition on the linear propagation velocity (LPV) of ice in undercooled solutions contained in a U-tube. We have determined velocities in a range of concentrations of sugar solution at the same undercooling, and also as a function of undercooling. The role of added polymer has also been investigated. It is affected by the sugar concentration.

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© 1991 Springer Science+Business Media New York

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Charoenrein, S., Goddard, M., Reid, D.S. (1991). Effect of Solute on the Nucleation and Propagation of Ice. In: Levine, H., Slade, L. (eds) Water Relationships in Foods. Advances in Experimental Medicine and Biology, vol 302. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0664-9_9

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  • DOI: https://doi.org/10.1007/978-1-4899-0664-9_9

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-0666-3

  • Online ISBN: 978-1-4899-0664-9

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