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The Use of Ammonium Perchlorate with the Hydrogen-Argon-Entrained Air Flame in Atomic Absorption Spectroscopy

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Developments in Applied Spectroscopy

Part of the book series: Developments in Applied Spectroscopy ((DAIS,volume 8))

Abstract

The use of ammonium perchlorate increased the usefulness of the hydrogenargon-entrained air (H2AA) flame. Arsenic, lead, tin, copper, bismuth, cobalt, iron, nickel, antimony, zinc, and selenium were studied. Copper, cobalt, iron, and nickel gave no signal in the relatively low temperature of the H2AA flame. The presence of ammonium perchlorate produced a signal which allowed these elements to be readily detected with a response greater than is obtained with an acetylene-air flame. The presence of a copper, iron, or nickel matrix obliterates the signal from elements studied in the H2AA flame. The presence of ammonium perchlorate does not completely eliminate the matrix effect.

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References

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Author information

Authors and Affiliations

  1. Paul D. Merica Research Laboratory, The International Nickel Company, Inc., Sterling Forest, Suffern, New York, USA

    Keith E. Burke & C. H. Albright

Authors
  1. Keith E. Burke
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  2. C. H. Albright
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Editor information

Editors and Affiliations

  1. Research Laboratories, Illinois Institute of Technology, Chicago, Illinois, USA

    E. L. Grove

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© 1970 Chicago Section of the Society for Applied Spectroscopy

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Burke, K.E., Albright, C.H. (1970). The Use of Ammonium Perchlorate with the Hydrogen-Argon-Entrained Air Flame in Atomic Absorption Spectroscopy. In: Grove, E.L. (eds) Developments in Applied Spectroscopy. Developments in Applied Spectroscopy, vol 8. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-7962-1_3

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  • DOI: https://doi.org/10.1007/978-1-4684-7962-1_3

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4684-7964-5

  • Online ISBN: 978-1-4684-7962-1

  • eBook Packages: Springer Book Archive

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