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Trace Metal Analysis by Gas Chromatography

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Developments in Applied Spectroscopy

Part of the book series: Developments in Applied Spectroscopy ((DAIS,volume 8))

Abstract

Gas chromatography offers a promising new approach to the quantitative and qualitative analyses for trace amounts of metals. This technique has excellent potential because of its high sensitivity and the low cost of instrumentation. The method utilizes the formation of metal complexes, e.g., fluorinated chelates which are volatile and stable enough for gas chromatographic separation and measurement. Some of these metal chelates can be detected at extremely low concentrations, e.g., at the 10−13-g level by using the electron capture detector which is very sensitive to fluorinated metal chelates. The significance of this research is its potential use in medicine, chemistry, environmental health, and metallurgy, where the presence or absence of ultratrace amounts of metals can be extremely important.

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References

  1. H. Freiser, Anal. Chem. 31, 1440 (1959).

    Article  CAS  Google Scholar 

  2. R. S. Juvet and F. M. Wachi, ibid. 32, 290 (1960).

    CAS  Google Scholar 

  3. F. M. Wachi, Thesis, University of Illinois, L. C. Card No. Mic. 59–2061 (1969).

    Google Scholar 

  4. R. S. Juvet and R. L. Fisher, Anal. Chem. 38, 1860 (1966).

    Article  CAS  Google Scholar 

  5. M. Lederer, Nature 176, 462 (1955).

    Article  CAS  Google Scholar 

  6. W. W. Brandt, Gas Chromatography (1960)

    Google Scholar 

  7. R. P. W. Scott, ed., Butterworths, Washington (1960), p. 305.

    Google Scholar 

  8. J. Janak, ibid, p. 306.

    Google Scholar 

  9. W. J. Biermann and H. Gesser, Anal. Chem. 32, 1525 (1960).

    Article  CAS  Google Scholar 

  10. W. D. Ross, Anal. Chem. 35, 1596 (1963).

    Article  CAS  Google Scholar 

  11. W. D. Ross and R. E. Sievers, Gas Chromatography (1966), A. Littlewood, ed., The Institute of Petroleum, London (1967), p. 272.

    Google Scholar 

  12. W. D. Ross and G. Wheeler, Jr., Anal. Chem. 35, 1596 (1964).

    Article  Google Scholar 

  13. W. D. Ross, R. E. Sievers and G. Wheeler, Jr., Anal. Chem. 37, 598 (1965).

    Article  CAS  Google Scholar 

  14. W. D. Ross and R. E. Sievers, Talanta 15, 87 (1967).

    Article  Google Scholar 

  15. R. W. Moshier and J. E. Schwarberg, Talanta, 13, 445 (1966).

    Article  CAS  PubMed  Google Scholar 

  16. W. G. Scribner, W. J. Treat, J. D. Weis, and R. W. Moshier, Anal. Chem. 37, 1136 (1965).

    Article  CAS  Google Scholar 

  17. G. P. Morie and T. R. Sweet, Anal. Chim. Acta 34, 314 (1966).

    Article  CAS  Google Scholar 

  18. G. P. Morie and T. R. Sweet, Anal. Chem. 37, 1552 (1965).

    Article  CAS  Google Scholar 

  19. T. Fuginaga, T. Kuwamoto, and Y. Ono, Nippon Kagaku Zasshi 86, 1294 (1965).

    Article  Google Scholar 

  20. R. E. Sievers, B. W. Ponder, M. L. Morris, and R. W. Moshier, Inorg. Chem, 2, 693 (1963).

    Article  CAS  Google Scholar 

  21. R. W. Moshier and R. E. Sievers, Gas Chromatography of Metal Chelates, Pergamon Press, Oxford (1965).

    Google Scholar 

  22. W. G. Scribner, M. J. Borchers, and W. J. Treat, Anal. Chem. 38, 1779 (1966).

    Article  CAS  Google Scholar 

  23. W. G. Scribner and A. M. Kotechi, Anal. Chem. 37, 1304 (1965).

    Article  CAS  Google Scholar 

  24. R. E. Sievers, J. W. Connolly, and W. D. Ross, J. Gas Chrom. 5, 241 (1967).

    Article  CAS  Google Scholar 

  25. W. D. Ross and R. E. Sievers, Anal. Chem. 41, 1109 (1969).

    Article  CAS  Google Scholar 

  26. M. L. Taylor, E. L. Arnold, and R. E. Sievers, Anal. Letters 1, 735 (1968).

    CAS  Google Scholar 

  27. b. M. L. Taylor and E. L. Arnold (private communication).

    Google Scholar 

  28. J. Savory, P. Mushak, and F. W. Sunderman, Tr., Advences in Chromatography, A. Zlatkis, ed., Preston Technical Abstracts, Evanston (1960), p. 181.

    Google Scholar 

  29. J. Savory, P. Mushak, N. O. Roszel, and F. W. Sunderman, Jr., Fed. Proc. 27, 3154, 177 (1968).

    Google Scholar 

  30. C. Genty, C. Houin, and R. Schott, Proceedings 7th Int. Symp. on Gas Chromatography, Copenhagen, Institute of Petroleum, June 1968, Paper 9.

    Google Scholar 

  31. W. D. Ross and R. E. Sievers (unpublished data).

    Google Scholar 

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© 1970 Chicago Section of the Society for Applied Spectroscopy

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Ross, W.D., Sievers, R.E. (1970). Trace Metal Analysis by Gas Chromatography. In: Grove, E.L. (eds) Developments in Applied Spectroscopy. Developments in Applied Spectroscopy, vol 8. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-7962-1_16

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  • DOI: https://doi.org/10.1007/978-1-4684-7962-1_16

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4684-7964-5

  • Online ISBN: 978-1-4684-7962-1

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