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Chemical Alteration

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Encyclopedia of Geoarchaeology

Part of the book series: Encyclopedia of Earth Sciences Series ((EESS))

Definitions

Authigenic minerals: Minerals forming in situ within sediments.

Chemical equilibrium: The state of a chemical reaction where the concentration of reactants and products is constant.

Cementation: Formation of new minerals that fill the pore spaces within a sediment.

Diagenesis: All of the processes that act to modify sediments after deposition.

Dissolution: Removal in solution of all or part of previously existing mineral.

Oxidation-reduction (redox): All reactions that involve changes in the oxidation number. Some oxidation reactions can be described as the combination of a substance with oxygen.

pH: A measure of the acidity or basicity of an aqueous solution. The mathematical definition of this is the negative decimal logarithm of the concentration of the hydronium cation (H3O+) in a solution.

Recrystallization: Change in size or shape of a crystal of a given mineral with no change in its chemical composition or mineralogy.

Saturation: The point at which a solution of a...

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Bibliography

  • Albert, R. M., Shahack-Gross, R., Cabanes, D., Gilboa, A., Lev-Yadun, S., Portillo, M., Sharon, I., Boaretto, E., and Weiner, S., 2008. Phytolith-rich layers from the Late Bronze and Iron Ages at Tel Dor (Israel): mode of formation and archaeological significance. Journal of Archaeological Science, 35(1), 57–75.

    Article  Google Scholar 

  • Amit, R., Simhai, O., Ayalon, A., Enzel, Y., Matmon, A., Crouvi, O., Porat, N., and McDonald, E., 2011. Transition from arid to hyper-arid environment in the southern Levant deserts as recorded by early Pleistocene cummulic Aridisols. Quaternary Science Reviews, 30(3–4), 312–323.

    Article  Google Scholar 

  • Berna, F., Matthews, A., and Weiner, S., 2004. Solubilities of bone mineral from archaeological sites: the recrystallization window. Journal of Archaeological Science, 31(7), 867–882.

    Article  Google Scholar 

  • Bertran, P., and Raynal, J.-P., 1991. Apport de la micromorphologie à l’étude archéologique du village médiéval de Saint-Victor de Massiac (Cantal). Revue archéologique du Centre de la France, 30(30), 137–150.

    Article  Google Scholar 

  • Burroni, D., Donahue, R. E., Pollard, A. M., and Mussi, M., 2002. The surface alteration features of flint artefacts as a record of environmental processes. Journal of Archaeological Science, 29(11), 1277–1287.

    Article  Google Scholar 

  • Cabanes, D., and Albert, R. M., 2011. Microarchaeology of a collective burial: Cova des Pas (Minorca). Journal of Archaeological Science, 38(5), 1119–1126.

    Article  Google Scholar 

  • Canti, M. G., 1997. An investigation of microscopic calcareous spherulites from herbivore dungs. Journal of Archaeological Science, 24(3), 219–231.

    Article  Google Scholar 

  • Canti, M. G., 1999. The production and preservation of faecal spherulites: animals, environment and taphonomy. Journal of Archaeological Science, 26(3), 251–258.

    Article  Google Scholar 

  • Cerling, T. E., Wynn, J. G., Andanje, S. A., Bird, M. I., Korir, D. K., Levin, N. E., Mace, W., Macharia, A. N., Quade, J., and Remien, C. H., 2011. Woody cover and hominin environments in the past 6 million years. Nature, 476(7358), 51–56.

    Article  Google Scholar 

  • Cohen-Ofri, I., Weiner, L., Boaretto, E., Mintz, G., and Weiner, S., 2006. Modern and fossil charcoal: aspects of structure and diagenesis. Journal of Archaeological Science, 33(3), 428–439.

    Article  Google Scholar 

  • Courty, M. A., Goldberg, P., and Macphail, R., 1989. Soils and Micromorphology in Archaeology. Cambridge: Cambridge University Press.

    Google Scholar 

  • Donner, H. E., and Lynn, W. C., 1989. Carbonate, halide, sulfate, and sulfide minerals. In Dixon, J. B., and Weed, S. B. (eds.), Minerals in Soil Environments, 2nd edn. Madison: Soil Science Society of America. SSSA Book Series, 1, pp. 279–330.

    Google Scholar 

  • Ford, D., 1997. Dating and paleo-environmental studies of speleothems. In Hill, C. A., and Forti, P. (eds.), Cave Minerals of the World, 2nd edn. Huntsville: National Speleological Society, pp. 271–284.

    Google Scholar 

  • Fraysse, F., Pokrovsky, O. S., Schott, J., and Meunier, J.-D., 2009. Surface chemistry and reactivity of plant phytoliths in aqueous solutions. Chemical Geology, 258(3–4), 197–206.

    Article  Google Scholar 

  • Gebhardt, A., and Langohr, R., 1999. Micromorphological study of construction materials and living floors in the medieval motte of Werken (West Flanders, Belgium). Geoarchaeology, 14(7), 595–620.

    Article  Google Scholar 

  • Gillieson, D. S., 1996. Caves: Processes, Development, and Management. Oxford: Blackwell.

    Book  Google Scholar 

  • Goldberg, P., and Berna, F., 2010. Micromorphology and context. Quaternary International, 214(1–2), 56–62.

    Article  Google Scholar 

  • Goldberg, P., and Macphail, R. I., 2006. Practical and Theoretical Geoarchaeology. Malden: Blackwell.

    Google Scholar 

  • Goldberg, P., Laville, H., Meignen, L., and Bar-Yosef, O., 2007. Stratigraphy and geoarchaeological history of Kebara Cave, Mount Carmel. In Bar-Yosef, O., and Meignen, L. (eds.), Kebara Cave, Mt. Carmel, Israel: The Middle and Upper Paleolithic Archaeology, Part I. Cambridge, MA: Harvard University, Peabody Museum of Archaeology and Enthnology. American School of Prehistoric Research Bulletin, 49, pp. 49–89.

    Google Scholar 

  • Hedges, R. E. M., and Millard, A. R., 1995. Bones and groundwater: towards the modelling of diagenetic processes. Journal of Archaeological Science, 22(2), 155–164.

    Article  Google Scholar 

  • Hill, C. A., and Forti, P., 1997. Cave Minerals of the World, 2nd edn. Huntsville: National Speleological Society.

    Google Scholar 

  • Karkanas, P., 2010. Preservation of anthropogenic materials under different geochemical processes: a mineralogical approach. Quaternary International, 210(1–2), 63–69.

    Article  Google Scholar 

  • Karkanas, P., and Goldberg, P., 2010. Phosphatic features. In Stoops, G., Marcelino, V., and Mees, F. (eds.), Interpretation of Micromorphological Features of Soils and Regoliths. Amsterdam: Elsevier, pp. 521–541.

    Chapter  Google Scholar 

  • Karkanas, P., and Stratouli, G., 2008. Neolithic lime plastered floors in Drakaina Cave, Kephalonia Island, Western Greece: evidence of the significance of the site. Annual of the British School at Athens, 103, 27–41.

    Article  Google Scholar 

  • Karkanas, P., Bar-Yosef, O., Goldberg, P., and Weiner, S., 2000. Diagenesis in prehistoric caves: the use of minerals that form in situ to assess the completeness of the archaeological record. Journal of Archaeological Science, 27(10), 915–929.

    Article  Google Scholar 

  • Karkanas, P., Shahack-Gross, R., Ayalon, A., Bar-Matthews, M., Barkai, R., Frumkin, A., Gopher, A., and Stiner, M., 2007. Evidence for habitual use of fire at the end of the Lower Paleolithic: site-formation processes at Qesem Cave, Israel. Journal of Human Evolution, 53(2), 197–212.

    Article  Google Scholar 

  • Krauskopf, K. B., 1979. Introduction to Geochemistry, 2nd edn. New York: McGraw-Hill.

    Google Scholar 

  • Luedtke, B. E., 1992. An Archaeologist’s Guide to Chert and Flint. Los Angeles: Institute of Archaeology, University of California. Archaeological Research Tools, 7.

    Google Scholar 

  • Macphail, R. I., Cruise, G. M., Allen, M. J., Linderholm, J., and Reynolds, P., 2004. Archaeological soil and pollen analysis of experimental floor deposits; with special reference to Butser Ancient Farm, Hampshire, UK. Journal of Archaeological Science, 31(2), 175–191.

    Article  Google Scholar 

  • Marín Arroyo, A. B., Landete Ruiz, M. D., Vidal Bernabeu, G., Seva Román, R., Gonzáles Morales, M. R., and Straus, L. G., 2008. Archaeological implications of human-derived manganese coatings: a study of blackened bones in El Mirón Cave, Cantabrian Spain. Journal of Archaeological Science, 35(3), 801–813.

    Article  Google Scholar 

  • McGowan, G., and Prangnell, J., 2006. The significance of vivianite in archaeological settings. Geoarchaeology, 21(1), 93–111.

    Article  Google Scholar 

  • Mercier, N., Valladas, H., Joron, J. L., Schiegl, S., Bar-Yosef, O., and Weiner, S., 1995. Thermoluminescence dating and the problem of geochemical evolution of sediments. A case study: the Mousterian levels at Hayonim. Israel Journal of Chemistry, 35(2), 137–141.

    Article  Google Scholar 

  • Nahon, D. B., 1991. Introduction to the Petrology of Soils and Chemical Weathering. New York: Wiley.

    Google Scholar 

  • Nordt, L. C., 2001. Stable C and O isotopes in soils: applications for archaeological research. In Goldberg, P., Holliday, V. T., and Ferring, C. R. (eds.), Earth-Sciences and Archaeology. New York: Kluwer/Plenum Publishers, pp. 419–445.

    Chapter  Google Scholar 

  • Pickering, R., and Kramers, J. D., 2010. Re-appraisal of the stratigraphy and determination of new U-Pb dates for the Sterkfontein hominin site, South Africa. Journal of Human Evolution, 59(1), 70–86.

    Article  Google Scholar 

  • Pickering, R., Hancox, P. J., Lee-Thorp, J. A., Grün, R., Mortimer, G. E., McCulloch, M., and Berger, L. R., 2007. Stratigraphy, U-Th chronology, and paleoenvironments at Gladysvale Cave: insights into the climatic control of South African hominin-bearing cave deposits. Journal of Human Evolution, 53(5), 602–619.

    Article  Google Scholar 

  • Piperno, D. R., 1988. Phytolith Analysis: An Archaeological and Geological Perspective. San Diego: Academic.

    Google Scholar 

  • Poch, R. M., Artieda, O., Herrero, J., and Lebedeva-Verba, M., 2010. Gypsic features in soils and sediments. In Stoops, G., Marcelino, V., and Mees, F. (eds.), Interpretation of Micromorphological Features of Soils and Regoliths. Amsterdam: Elsevier, pp. 195–216.

    Chapter  Google Scholar 

  • Regev, L., Zukerman, A., Hitchcock, L., Maeir, A. M., Weiner, S., and Boaretto, E., 2010. Iron age hydraulic plaster from tell Es-Safi/Gath, Israel. Journal of Archaeological Science, 37(12), 3000–3009.

    Article  Google Scholar 

  • Retallack, G. J., 2001. Soils of the Past. An Introduction to Paleopedology, 2nd edn. Oxford: Blackwell Science.

    Google Scholar 

  • Shahack-Gross, R., and Finkelstein, I., 2008. Subsistence practices in an arid environment: a geoarchaeological investigation in an Iron Age site, the Negev Highlands, Israel. Journal of Archaeological Science, 35(4), 965–982.

    Article  Google Scholar 

  • Shahack-Gross, R., Bar-Yosef, O., and Weiner, S., 1997. Black-coloured bones in Hayonim Cave, Israel: differentiating between burning and oxide staining. Journal of Archaeological Science, 24(5), 439–446.

    Article  Google Scholar 

  • Shahack-Gross, R., Berna, F., Karkanas, P., and Weiner, S., 2004. Bat guano and preservation of archaeological remains in cave sites. Journal of Archaeological Science, 31(9), 1259–1272.

    Article  Google Scholar 

  • Sheppard, P. J., and Pavlish, L. A., 1992. Weathering of archaeological cherts: a case study from the Solomon Islands. Geoarchaeology, 7(1), 41–53.

    Article  Google Scholar 

  • Simpson, I. A., Perdikaris, S., Cook, G., Campbell, J. L., and Teesdaly, W. J., 2000. Cultural sediment analyses and transitions in early fishing activity at Langenesværet, VesterÃ¥len, Northern Norway. Geoarchaeology, 15(8), 743–763.

    Article  Google Scholar 

  • Weiner, S., 2010. Microarchaeology: Beyond the Visible Archaeological Record. New York: Cambridge University Press.

    Book  Google Scholar 

  • Weiner, S., and Bar-Yosef, O., 1990. States of preservation of bones from prehistoric sites in the Near East: a survey. Journal of Archaeological Science, 17(2), 187–196.

    Article  Google Scholar 

  • Weiner, S., Goldberg, P., and Bar-Yosef, O., 1993. Bone preservation in Kebara Cave, Israel using on-site fourier transform infrared spectrometry. Journal of Archaeological Science, 20(6), 613–627.

    Article  Google Scholar 

  • Wright, V. P., and Tucker, M. E., 1991. Calcretes: an introduction. In Wright, V. P., and Tucker, M. E. (eds.), Calcretes. Oxford: Blackwell. International Association of Sedimentologists, Reprint Series, 2, pp. 1–22.

    Chapter  Google Scholar 

  • Zhou, J., and Chafetz, H. S., 2009. Biogenic caliches in Texas: the role of organisms and effect of climate. Sedimentary Geology, 222(3–4), 207–225.

    Article  Google Scholar 

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Correspondence to Panagiotis Karkanas .

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Karkanas, P. (2017). Chemical Alteration. In: Gilbert, A.S. (eds) Encyclopedia of Geoarchaeology. Encyclopedia of Earth Sciences Series. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-4409-0_126

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