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Stratospheric Ozone Depletion and Greenhouse Gases since the International Geophysical Year: F. Sherwood Rowland and the Evolution of Earth Science

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Globalizing Polar Science
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Abstract

In preparation for the International Geophysical Year (IGY), the British Antarctic Survey (BAS) of the Royal Society set up a research station near Halley Bay (named in honor of noted astronomer Edmond Halley). During the IGY, the Halley Bay station played a critical role in discovering the polar vortex above the Antarctic and, nearly 30 years later, provided important evidence for massive loss of stratospheric ozone within the vortex that could be attributed to the release of anthropogenic chlorofluorocarbons (CFCs) into the atmosphere. These findings provided the experimental confirmation for the theoretical predictions made in the mid-1970s by F. Sherwood Rowland and his colleague, Mario Molina. Discovery of this “ozone hole” in 1985, made possible by the Dobson spectrometers set up during the IGY, led to the swift enactment of the important intergovernmental treaty brokered by the United Nations, known as the Montreal Protocol in 1987. The Montreal Protocol initially called for a 50 percent reduction in CFC production by the end of the twentieth century, but subsequent meetings set up an accelerated schedule for major industrialized nations to phase out these products completely by 1996.

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  1. Bette Hileman, “A Giant among Chemists,” Chemical and Engineering News 85 (December 24, 2007): 30–33.

    Article  Google Scholar 

  2. M.J. Molina and F.S. Rowland, “Stratospheric Sink for Chlorofluoromethanes: Chlorine Atom-Catalysed Destruction of Ozone,” Nature 249 (1974): 810–812.

    Article  Google Scholar 

  3. F. Sherwood Rowland, “Stratospheric Ozone Depletion” Philosophical Transactions of the. Royal Society Bulletin 361 (2006): 769–790;

    Article  Google Scholar 

  4. J.E. Lovelock, R.J. Maggs, and R.J. Wade, “Halogenated Hydrocarbons in and over the Atlantic,” Nature 241 (1973): 194–196.

    Article  Google Scholar 

  5. Sydney Chapman, “A Theory of Upper Atmospheric Ozone,” Memoirs of the Royal Meteorological Society 3 (1930): 103–125.

    Google Scholar 

  6. F.S. Rowland and M.J. Molina, “Chlorofluoromethanes in the Environment,” Reviews of Geophysics and Space Physics. 13 (1975): 1–35.

    Article  Google Scholar 

  7. R.S. Stolarski and R.J. Cicerone, “Stratospheric Chlorine: A Possible Sink for Ozone,” Canadian Journal of Chemistry 52 (1974): 1610–1615.

    Article  Google Scholar 

  8. PJ. Crutzen, “The Influence of Nitrogen Oxides on the Atmospheric Ozone Content,” Royal Meteorological Society Quarterly Journal 96 (1970): 320–325;

    Article  Google Scholar 

  9. H.S. Johnston, “Reduction of Stratospheric Ozone by Nitrogen Oxide Catalysts from Supersonic Transport Exhaust,” Science 173 (1971): 517–522;

    Article  Google Scholar 

  10. P.J. Crutzen, “Ozone Production Rates in an Oxygen-Hydrogen-Nitrogen Oxide Atmosphere,” Journal Geophysical Research 76 (1971): 7311–7327.

    Article  Google Scholar 

  11. A.L. Schmeltekopf et al., “Measurements of Stratospheric CFCl3, CF2O2 and N2O,” Geophysical Research Letters 2 (1975): 393–396;

    Article  Google Scholar 

  12. L.E. Heidt et al., “Stratospheric Profiles of CCl3F and CClF,” Geophysical Research Letters 2 (1975): 445–447.

    Article  Google Scholar 

  13. G.M.B. Dobson, “Forty Years’ Research on Atmospheric Ozone at Oxford: A History,” Applied Optics 7 (1968): 401.

    Article  Google Scholar 

  14. J.C. Farman, B.G. Gardiner, and J.D. Shanklin, “Large Losses of Ozone in Antarctica Reveal Seasonal ClOx/NOx Interaction,” Nature 315 (1985): 207–210.

    Article  Google Scholar 

  15. R.S. Stolarski et al., “Nimbus 7 SBUV/TOMS Measurements of the Springtime Antarctic Ozone Decrease,” Nature 322 (1986): 808–811.

    Article  Google Scholar 

  16. R.L. deZafra et al., “High Concentrations of Chlorine Monoxide at Low Altitudes in the Antarctic Spring Stratosphere, I, Diurnal Variation,” Nature 328 (1987): 408–411.

    Article  Google Scholar 

  17. J.G. Anderson, W.H. Brune, and M.H. Proffitt, “Ozone Destruction by Chlorine Radicals within the Antarctic Vortex: The Spatial and Temporal Evolution of ClO-O3 Anti-correlation Based on In Situ ER-2 Data,” Journal Geophysical Research 94 (1989): 11465-l1479.

    Google Scholar 

  18. L.T. Molina and M.J. Molina, “Production of Cl2O2 from the Self-Reaction of the ClO Radical,” Journal of Physical Chemistry 91 (1987): 433–436.

    Article  Google Scholar 

  19. N.R.P. Harris and F.S. Rowland, “Trends in Total Ozone at Arosa,” Eos 67 (1986): 875.

    Google Scholar 

  20. F.S. Rowland et al., “Statistical Error Analyses of Ozone Trends—Winter Depletion in the Northern Hemisphere,” in R.D. Bojkov and P. Fabian, eds., Ozone in the Atmosphere (Hampton, Virginia: Deepak Publishing, 1989)), 71–75.

    Google Scholar 

  21. C.R. Booth and S. Madronich, “Radiation Amplification Factors: Improved Formula Accounts for Large Increases in Ultraviolet Radiation Associated with Antarctic Ozone Depletion,” in C.S. Weiler and P.A. Penhale, eds., Antarctic Research Series 62 (Washington, D.C.: American Geophysical Union, 1994), 39–42.

    Google Scholar 

  22. C.R. Booth et al., Antarctic Journal of the United States 39 (1994): 256–259.

    Google Scholar 

  23. Richard Elliot Benedick, Ozone Diplomacy (Cambridge, Massachusetts: Harvard University Press, 1991).

    Google Scholar 

  24. James Rodger Fleming, The Callendar Effect: The Life and Work of Guy Stewart Callendar (1898–1964), The Scientist Who Established the Carbon Dioxide Theory of Climate Change (Boston: American Meteorological Society, 2007).

    Book  Google Scholar 

  25. James Rodger Fleming, Historical Perspectives on Climate Change (New York: Oxford University Press, 1998);

    Google Scholar 

  26. Spencer W. Weart, The Discovery of Global Warming (Cambridge, Massachusetts: Harvard University Press, 2003));

    Google Scholar 

  27. C.D. Keeling, “The Concentration and Isotopic Abundances of Carbon Dioxide in the Atmosphere,” Tellus 12 (1960): 200–203.

    Article  Google Scholar 

  28. Rowland, “Global Warming,” 2008; I.J. Simpson et al., “Influence of Biomass Burning during Recent Fluctuations in the Slow Growth of Global Tropospheric Methane,” Geophysical Research Letters 33 (2006): L22808.

    Article  Google Scholar 

  29. I.J. Simpson et al., “Implications of the Recent Fluctuations in the Growth Rate of Tropospheric Methane,” Geophysical Research Letters 29 (2002): 1479.

    Google Scholar 

  30. D.R. Blake and F.S. Rowland, “Continuing World-wide Increase in Tropospheric Methane 1978–1987,” Science 239 (1988): 1129–1131.

    Article  Google Scholar 

  31. T.M. Thompson et al., “Halocarbons and Other Atmospheric Trace Species” in R.C. Schnell, A.-M. Buggle, and R.M. Rosson, eds., Climate Monitoring and Diagnostics Laboratory, Summary Report No. 27 (Boulder, Colorado: NOAA CMDL, 2004), 115–133.

    Google Scholar 

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© 2010 Roger D. Launius, James Rodger Fleming, and David H. DeVorkin

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Thamattoor, D.M. (2010). Stratospheric Ozone Depletion and Greenhouse Gases since the International Geophysical Year: F. Sherwood Rowland and the Evolution of Earth Science. In: Launius, R.D., Fleming, J.R., DeVorkin, D.H. (eds) Globalizing Polar Science. Palgrave Studies in the History of Science and Technology. Palgrave Macmillan, New York. https://doi.org/10.1057/9780230114654_20

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  • DOI: https://doi.org/10.1057/9780230114654_20

  • Publisher Name: Palgrave Macmillan, New York

  • Print ISBN: 978-0-230-10533-1

  • Online ISBN: 978-0-230-11465-4

  • eBook Packages: Palgrave History CollectionHistory (R0)

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