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Ligand-Driven Light-Induced Spin Change (LD-LISC): A Promising Photomagnetic Effect

  • Chapter
Spin Crossover in Transition Metal Compounds II

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 234))

Abstract

“Ligand-driven light-induced spin change” (LD-LISC) is a photomagnetic effect based on the modulation of the ligand-field strength of a suitable spin-crossover complex through a photochemical reaction on the ligand. It allows one to switch the electronic spin state of the metal ion by means of light over a broad range of temperatures possibly including room temperature. Among the photochemical reactions capable of triggering the spin conversion reversibly, we have firstly selected cis-trans isomerization. The occurrence of the LD-LISC effect was shown in several iron(II) or iron(III) complexes. On varying the molecular components, the working temperature and excitation wavelengths were modulated so that the effect could be observed at room temperature upon irradiation of the sample with visible light. The experiments were performed on compounds either in solution or included in polymeric matrices.

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Acknowledgements

We would like to thank all our collaborators and colleagues, whose names appear with ours in a number of references, for their contributions to the LD-LISC findings presented above. The European Science Foundation, the European TMR programme (ERB-FMRX-CT98-0199) and the CNRS “Groupement de Recherches COMES” are also gratefully acknowledged.

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Authors and Affiliations

  1. Laboratoire de Chimie Inorganique, UMR CNRS 8613, ICMMO, Bât 420, Université Paris-Sud, 91405, Orsay Cedex, France

    Marie-Laure Boillot, Jacqueline Zarembowitch & Angélique Sour

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  1. Marie-Laure Boillot
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  2. Jacqueline Zarembowitch
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  3. Angélique Sour
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Correspondence to Marie-Laure Boillot .

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Boillot, ML., Zarembowitch, J., Sour, A. Ligand-Driven Light-Induced Spin Change (LD-LISC): A Promising Photomagnetic Effect. In: Spin Crossover in Transition Metal Compounds II. Topics in Current Chemistry, vol 234. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b95419

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  • DOI: https://doi.org/10.1007/b95419

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-40396-8

  • Online ISBN: 978-3-540-36774-1

  • eBook Packages: Springer Book Archive

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