Abstract
The morphology of polyethylene has been an important theme in polymer science for more than 50 years. This review provides an historical background and presents the important findings on five specialised topics: the crystal thickness, the nature of the fold surface, the lateral habit of the crystals, how the spherulite develops from the crystal lamellae, and multi-component crystallisation and segregation of low molar mass and branched species.
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Paynter OI, Simmonds DJ, Whiting MC (1982) Chem Commun 1982:1165
Bunn CW (1939) Trans Faraday Soc 35:428
Busing WR (1990) Macromolecules 23:4608
Chatani Y, Ueda Y, Tadokoro H (1977) Annual Meeting of the Society of Polymer Science, Japan, Tokyo, Preprint, p 1326
Swan PR (1962) J Polym Sci 56:409
Holdsworth PJ, Keller A (1967) J Polym Sci, Polym Lett 5:605
Preedy JE (1973) Br Polym J 5:13
Balta Calleja FJ, Gonzales Ortega JC, Martinez Salazar J (1978) Polymer 19:1094
Martinez Salazar FJ, Baltá Calleja FJ (1979) J Cryst Growth 48:282
Teare PW, Holmes DR (1957) J Polym Sci 24:496
Seto T, Hara T, Tanaka K (1968) Japanese J Phys 7:31
Bassett DC, Block S, Piermarini GJ (1974) J Appl Phys 45:4146
Bassett DC, Turner B (1974) Phil Mag 29:925
Sakaruda l, Ito T, Nakamae K (1966) J Polym Sci C15:236
Mizushima R, Shimanouchi T (1949) J Am Chem Soc 71:1320
Shauffele RF, Shimanouchi T (1967) J Chem Phys 47:3605
Davis GT, Eby RK, Colson JP (1970) J Appl Phys 41:4316
Bunn CW, de Daubeny R (1954) Trans Faraday Soc 50:1173
Boyd RH (1985) Polymer 26:323
Boyd RH (1985) Polymer 26:1123
Ashcraft CR, Boyd RH (1976) J Polym Sci, Polym Phys 14:2153
Mansfield M, Boyd RH (1978) J Polym Sci, Polym Phys 16:1227
Boyd RH, Biliyar K (1973) Am Chem Soc Div Polym Chem Polym Prepr 14:329
Boyd RH (1984) Macromolecules 7:903
Crissman JM, Passaglia E (1971) J Appl Phys 42:4636
Crissman JM (1975) J Polym Sci, Polym Phys 13:1407
Keller A (1957) Phil Mag 2:1171
Fischer EW (1957) Z Naturf 12a:753
Till PH (1957) J Polym Sci 24:301
Wittmann JC, Lotz B (1985) J Polym Sci, Polym Phys 23:205
Keller A (1991) Chain-folded crystallisation of polymers from discovery to present day: a personalised journey. In: Chambers CG, Enderby JE, Keller A, Lang AR, Steeds JW (eds) Sir Charles Frank, OBE, FRS: an eightieth birthday tribute. Adam Hilger, Bristol, p 265
Bassett DC, Frank FC, Keller A (1963) Phil Mag 8:1739
Bassett DC (1968) Phil Mag 17:145
Dorset DL, Alamo RG, Mandelkern L (1993) Macromolecules 26:3 143
Vaughan AS, Bassett DC (1989) In: Allen G, Bevington JC (eds) Comprehensive polymer science, vol 2. Pergamon, Oxford, p 415
Keller A (1964) Kolloid Z Z Polym 197:98
Toda A, Keller A (1993) Colloid Polym Sci 271:328
Keller A (1967) Kolloid Z Z Polym 219:118
Kobayashi K (1962) Kagaku Chem 8:203
Bunn CW, Alcock TC (1945) Trans Faraday Soc 41:317
Bassett DC, Keller A, Mitsuhashi S (1963) J Polym Sci A 1:763
Wunderlich B (1976) Macromolecular physics, vol 2: Crystal nucleation, growth, annealing. Academic Press, New York
Kawai T (1965) Makromol Chem 84:290
Illers K-H, Hendus H (1968) Makromol Chem 113:1
Hoffman JD, Frolen LJ, Ross GS, Lauritzen JI (1975) J Res Nat Bur Std-A Phys Chem 79A:671
Bassett DC, Hodge AM, Olley RH (1981) Proc R Soc London A377:39
Mandelkern L, Sharma RK, Jackson JF (1969) Macromolecules 2:644
Weaver TJ, Harrison IR (1981) Polymer 22:1590
Ungar G, Organ SJ (1990) J Polym Sci, Polym Phys 28:2353
Organ SJ, Ungar G, Keller A (1990) J Polym Sci, Polym Phys 28:2365
Hobbs JK, Hill MJ, Barham PJ (2000) Polymer 41:8761
Keller A (1968) Rep Prog Phys 31:623
Ungar G, Keller A (1987) Polymer 27:1835
Patel D, Bassett DC (2002) Polymer 43:3795
Fischer EW, Schmidt GF (1962) Angew Chem 74:551
Hoel RH (1976) PhD Thesis, Department of Physics, University of Bristol, UK
Dreyfuss P, Keller A (1970) Polym Lett 8:253
Keller A, Priest DJ (1970) Polym Lett 8:13
Bark M, Zachmann HG, Alamo R, Mandelkern L (1992) Makromol Chem 193:2363
Kawai T (1967) Kolloid Z 229–2:116
Hoffman JD, Weeks JJ (1965) J Chem Phys 42:4301
Blackadder DA, Keniry JS, Richardson MJ (1972) Polymer 13:584
Barham PJ, Chivers RA, Keller A, Martinez-Salazar J, Organ SJ (1985) J Mater Sci 20:1625
Organ SJ, Keller A (1985) J Mater Sci 20:1602
Lauritzen JI, Hoffman JD (1960) J Res Nat Bur Std 64A:73
Wunderlich B (1980) Macromolecular physics, vol 3: Crystal melting. Academic Press, New York
Arakawa T, Wunderlich B (1967) J Polym Sci C16:653
Sadler DM (1983) Polymer 24:1401
Sadler DM, Gilmer GH (1984) Polymer 25:1446
Hoffman JD, Lauritzen JI, Passaglia E, Ross GS, Frolen LJ, Weeks JJ (1968) Kolloid Z Z Polym 231:564
Broadhurst MG (1962) J Chem Phys 36:2578
Broadhurst MG (1966) J Res Natl Bur Std A Phys Chem 70A:481
Flory PJ, Vrij A (1963) J Am Chem Soc 85:3548
Grubb DT (1985) Macromolecules 18:2282
Hoffman JD, Weeks JJ (1962) J Res Natl Bur Std—A Phys Chem 66A:13
Blundell DJ, Keller A, Connor T (1967) J Polym Sci A-2 5:991
Williams T, Blundell DJ, Keller A, Ward IM (1968) J Polym Sci A-2 6:1613
Keller A, Martuscelli E, Priest DJ, Udagawa Y (1971) J Polym Sci A-2 9:1807
Keller A (1962) Polymer 3:393
Petraccone V, Allegra G, Corradini P (1972) J Polym Sci C 38:419
Spells SJ, Organ SJ, Keller A, Zerbi G (1987) Polymer 28:697
Wolf S, Schmid C, Hägele PC (1990) Polymer 31:1222.
Cheam TC, Krimm S (1981) J Polym Sci, Polym Phys 19:423
Flory PJ (1962) J Am Chem Soc 84:2857
Sadler DM, Keller A (1979) Science 203:263
Spells SJ, Keller A, Sadler DM (1984) Polymer 25:749
Ungar G, Stejny J, Keller A, Bidd I, Whiting MC (1985) Science 229:386
Nisman R, Smith P, Vancso GJ (1994) Langmuir 10:1667
Frank FC (1979) General introduction. Faraday Soc General Discussion 68:7
DiMarzio EA, Guttman CM (1980) Polymer 21:733
Gedde UW (1995) Polymer physics. Kluwer, Dordrecht
Guttman CM, DiMarzio EA, Hoffman JD (1981) Polymer 22:1466
Schelten J, Ballard DGH, Wignall GD, Longman G, Schmaltz W (1976) Polymer 17:751
Sadler DM, Keller A (1977) Macromolecules 19:1128
Yoon DY, Flory PJ (1979) Faraday Soc General Discussion 68:452
Guttman CM, DiMarzio EA, Hoffman JD (1981) Polymer 22:597
Schelten J, Wignall GD, Ballard DGH (1974) Polymer 15:682
Schelten J, Wignall GD, Ballard DGH, Longman GW (1977) Polymer 18:1111
Mutter R, Stille W, Strobl GR (1993) J Polym Sci, Polym Phys 3 1:99
Kitamaru R, Horii F, Hyon S-H (1977) J Polym Sci, Polym Phys 15:821
Vonk CG, Pijpers AP (1985) J Polym Sci, Polym Phys 23:25 17
Keith HD (1964) J Appl Phys 35:3115
Organ SJ, Keller A (1985) J Mater Sci 20:1571
Labaig JJ (1978) PhD Thesis, University of Strasbourg
Bassett DC, Olley RH, al Rehail IAM (1988) Polymer 29:1539
Keith HD, Padden FJ, Lotz B, Wittman JC (1989) Macromolecules 22:2230
Toda A (1992) Colloid Polym Sci 270:667
Bassett DC, Hodge AM (1981) Proc R Soc London A377:61
Keller A (1955) J Polym Sci 17:351
Point J-J (1955) Bull Acad R Belg 41:982
Keller A (1955) J Polym Sci 17:291
Keith HD, Padden FJ (1963) J Polym Sci 39:101
Keith HD, Padden FJ (1963) J Polym Sci 39:123
Keller A (1959) J Polym Sci 39:151
Rego Lopez JM, Gedde UW (1988) Polymer 29:1037
Maxfield J, Mandelkern L(1977) Macromolecules 10:1141
Anderson FR (1964) J Appl Phys 35:64
Mandelkern L, Price JM, Gopalan M, Fatou JG (1966) J Polym Sci, Polym Phys 4:385
Bassett DC, Hodge AM (1978) Proc R Soc London A359:121
Kanig G (1973) Kolloid Z Z Polym 25 1:782
Olley RH, Hodge AM, Bassett DC (1979) J Polym Sci, Polym Phys 17:627
Frank FC, Tosi MP (1961) Proc R Soc London A263:323
Lauritzen JI, Passaglia E (1967) J Res Nat Bur Std A Phys Chem 71A:261
Abo el Maaty MI, Bassett DC (2001) Polymer 42:4957
Bassett DC (1984) CRC Crit Rev 12:97
Bassett DC, Olley RM (1984) Polymer 25:935
Bassett DC, Vaughan AS (1985) Polymer 26:7 17
Bassett DC, Olley RH, Sutton SJ, Vaughan AS (1996) Macromolecules 29:1852
Bassett DC, Olley RH, Sutton SJ, Vaughan AS (1996) Polymer 37:4993
Teckoe J, Bassett DC (2000) Polymer 41:1953
Hosier IL, Bassett DC (2000) Polymer 41:8801
Hosier IL, Bassett DC (2002) Polymer 43:307
Hill MJ, Barham PJ (1995) Polymer 36:1523
Wignall GD, Alamo RG, Londono JD, Mandelkern L, Stehling FC (1996) Macromolecules 29:5332
Alamo RG, Graessley WW, Krishnamoorti R, Lohse DI, Londono JD, Mandelkern L, Stehling FC, Wignall GD (1997) Macromolecules 30:561
Barham PJ, Hill MJ, Keller A, Rosney CCA (1988) J Mater Sci Lett 7:1271
Morgan RL, Hill MJ, Barham PJ, Frye C-J (1997) Polymer 38:1903
Tanem BS, Stori A (2001) Polymer 42:4309
Tanem BS, Stori A (2001) Polymer 42:5689
Hill MJ, Barham PJ, Keller A (1992) Polymer 33:2530
Hill MJ (1994) Polymer 35:1991
Hill MJ, Barham PJ (1994) Polymer 35:1802
Hill MJ, Barham PJ, van Ruiten J (1993) Polymer 34:2975
Thomas D, Williamson J, Hill MJ, Barham PJ (1993) Polymer 34:4919
Hill MJ, Barham PJ (1995) Polymer 36:3369
Morgan RL, Hill MJ, Barham PJ, van der Pol A, Kip BJ, Ottjes R, van Ruiten J (2001) Polymer 42:2121
Bank MI, Krimm S (1970) J Polym Sci Lett 8:143
Wunderlich B, Mehta A (1974) J Polym Sci, Polym Phys 12:255
Mehta A, Wunderlich B (1975) Colloid Polym Sci 253:193
Zachmann HG (1967) Kolloid Z Z Polym 216–217:180
Zachmann HG (1969) Kolloid Z Z Polym 231:504
Gedde UW, Eklund S, Jansson J-F (1983) Polymer 24:1532
Dlugosz J, Fraser GV, Grubb DT, Keller A, Odell JA, Goggin PL (1976) Polymer 17:471
Gedde UW, Jansson J-F (1984) Polymer 25:1263
Smith P, St. John Manley R (1979) Macromolecules 12:483
Rego Lopez JM, Conde Braña MT, Terselius B, Gedde UW (1988) Polymer 29:1045
Conde Braña MT, Iragorri Sainz JI, Gedde UW (1989) Polym Bull 22:277
Gustafsson A, Conde Braña MT, Gedde UW (1991) Polymer 32:426
Gedde UW, Jansson J-F, Liljenström G, Eklund S, Wang P-L, Holding S, Werner P-E (1988) Polym Eng Sci 28:1289
Gedde UW, Jansson J-F (1983) Polymer 24:1521
Clampitt BH (1965) J Polym Sci 3:671
Datta NK, Birley AW (1982) Plast Rubber Proc Appl 2:237
Kyu T, Hu S-R, Stein RS (1987) J Polym Sci, Polym Phys 25:89
Hu S-R, Kyu T, Stein RS (1987) J Polym Sci, Polym Phys 25:71
Edwards GH (1986) Brit Polym 118:88
Norton DR, Keller A (1984) J Mater Sci 19:447
Rego Lopez JM, Gedde UW (1989) Polymer 30:22
Conde Braña MT, Iragorri Sainz JI, Terselius B, Gedde UW (1989) Polymer 30:410
Iragorri Sainz JI, Rego Lopez JM, Katime I, Conde Braña MT, Gedde UW (1992) Polymer 33:461
Conde Braña MT, Gedde UW (1992) Polymer 33:3123
Abo el Maaty MI, Hosier IL, Bassett DC (1998) Macromolecules 31:153
Abo el Maaty Ml, Bassett DC, Olley RH, Jääskeläinen P (1998) Macromolecules 31:7800
Hosier IL, Bassett DC (1999) Polymer J 31:772
Neway B, Hedenqvist MS, Mathot VBF, Gedde UW (2001) Polymer 42:5307
Acknowledgements
The financial support from the Swedish Research Council (grant 621–2001–1621) is gratefully acknowledged.
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Gedde, U.W., Mattozzi, A. Polyethylene Morphology. In: Albertsson, AC. (eds) Long Term Properties of Polyolefins. Advances in Polymer Science, vol 169. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b94176
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DOI: https://doi.org/10.1007/b94176
Publisher Name: Springer, Berlin, Heidelberg
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