Abstract
A surface charge at an electrolyte–insulator interface and its counterion cloud form an electric dipole, thus giving rise to a long-range interaction that has been identified as the usual dipolar interaction. In this paper, we show that the picture of interacting dipoles ceases to be valid for a thin film with a thickness smaller than the Debye screening length. Indeed, in this case, both parallel and antiparallel dipoles repel each other, with a force much stronger than expected from a dipolar interaction. This originates from the delocalization of the screening clouds in very thin films.
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© 2004 Springer-Verlag Berlin Heidelberg
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Foret, L., Würger, A. (2004). Long-range interactions of surface charges on electrolyte films. In: Trends in Colloid and Interface Science XVII. Progress in Colloid and Polymer Science, vol 126. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b93985
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DOI: https://doi.org/10.1007/b93985
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Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-20073-4
Online ISBN: 978-3-540-39761-8
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