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Surface Modification of Polyethylene

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Part of the book series: Advances in Polymer Science ((POLYMER,volume 169))

Abstract

Polyolefins such as polyethylene, polypropylene and their copolymers have excellent bulk physical/chemical properties, are inexpensive and easy to process. Yet they have not gained considerable importance as speciality materials due to their inert surface. Polyethylene in particular holds a unique status due to its excellent manufacturer- and user-friendly properties. Thus, special surface properties, which polyethylene does not possess, such as printability, hydrophilicity, roughness, lubricity, selective permeability and adhesion of micro-organisms, underscore the need for tailoring the surface of this valuable commodity polymer. The present article reviews some of the existing and emerging techniques of surface modification and characterisation of polyethylene.

Surface modification of polymers, polyethylene in particular, has been extensively studied for decades using conventional tools. Although some of these techniques are still in use, they suffer from distinct shortcomings. During the last two decades, different means of surface modification have been thoroughly explored. The increasing expectancy for smart materials in daily life has, of late, sharply influenced research in the area of surface modification. Technologies that involve surface engineering to convert inexpensive materials into valuable finished goods have become even more important in the present scenario. In this review article we have attempted to broadly address almost all conventional and modern techniques for the surface modification of different physical forms and chemical compositions of polyethylene. This article will hopefully stimulate further research in this area and result in the development of polyolefins with multi-functional and responsive surfaces, which would ultimately lead to the commodities of polyolefins with smart surfaces.

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Abbreviations

Å :

Angstrom

AA :

Acrylic acid

AFM :

Atomic force microscopy

AIBN :

α,α’-Azo bis(isobutyro nitrile)

AC :

α chymotrypsin

ATR :

Attenuated total reflectance

R :

Alkyl

BPO :

Benzoyl peroxide

BP :

Benzophenone

θ :

Contact angle

Co :

Cobalt

XLPE :

Cross linked polyethylene

DEM :

Diethyl maleate

EDX :

Energy-dispersive X-ray spectroscopy

EPDM :

Ethylene propylene diene elastomer

EPR :

Ethylene propylene rubber

EVA :

Ethyl vinyl alcohol

FTIR :

Fourier transform infrared

GHz :

Giga hertz

GMA :

Glycidyl methacrylate

HDPE :

High density polypropylene

HEMA :

2-Hydroxy ethyl methacrylate

HSPE :

High strength polyethylene

keV :

Kilo electron volt

LPE :

Linear polyethylene

LLDPE :

Linear low density polyethylene

LDPE :

Low density polyethylene

MeV :

Mega electron volt

MHz :

Mega hertz

Mg :

Magnesium

MA :

Maleic anhydride

MFA :

Multi functional acrylate

NR :

Natural rubber

NVP :

N-Vinyl pyrrolidone

PE :

Polyethylene

PP :

Polypropylene

PMMA :

Polymethyl methacrylate

RBS :

Rutherford back scattering

SEM :

Scanning electron microscope

SSIMS :

Static secondary ion mass spectroscopy

STM :

Scanning tunnelling microscope

SFM :

Scanning force microscopy

T :

Temperature

ToF :

Time-of-flight

TEM :

Tunnelling electron microscopy

L2ITMS :

Two-laser ion trap mass spectrometry

UV :

Ultra violet

UHMWPE :

Ultra high molecular weight polyethylene

ULDPE :

Ultra low density polyethylene

Vis :

Visible

W :

Watt

XPS :

X-ray photoelectron spectroscopy

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Acknowledgement

The authors thank Dr. S. Sivaram, Director, National Chemical Laboratory, Pune, for his fruitful discussions and critical suggestions. Dr. S.M. Desai would like to thank C.S.I.R., India for the Senior Research Fellowship.

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Desai, S.M., Singh, R.P. Surface Modification of Polyethylene. In: Albertsson, AC. (eds) Long Term Properties of Polyolefins. Advances in Polymer Science, vol 169. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b13524

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