Abstract
Metal-mediated selective construction of useful carbocyclic compounds from multi-component reaction systems has attracted much attention in recent years. Zirconocene (containing a Cp2Zr unit) and titanocene (containing a Cp2Ti unit) mediated reactions have made significant contributions to the development of synthetically useful methodologies for construction of carbocyclic compounds from different components. This review surveys applications of zirconacycles and titanacycles on construction of useful carbocyclic compounds from multi-components. A brief introduction into preparative methods for zirconacycles and titanacycles is also given.
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Xi, Z., Li, Z. Construction of Carbocycles via Zirconacycles and Titanacycles. In: Metallocenes in Regio- and Stereoselective Synthesis. Topics in Organometallic Chemistry, vol 8. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b13143
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DOI: https://doi.org/10.1007/b13143
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Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-01606-9
Online ISBN: 978-3-540-31452-3
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