Average One-Center Two-Electron Exchange Integrals and Exchange Interactions
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We show how the introduction of the average one-center two-electron exchange integral, which is closely related to Jørgensens spin-pairing energy parameter, facilitates comparison of the Heisenberg-Dirac-van Vleck exchange parameter for different transition metal dimers. The formalism is illustrated on μ-oxo-dimanganese(III) and μ-oxo-dichromium(III) complexes in which the oxo bridge is the important exchange pathway.
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