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Polyelectrolytes with Defined Molecular Architecture I pp 151–175Cite as

Lipid and Polyampholyte Monolayers to Study Polyelectrolyte Interactions and Structure at Interfaces

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Part of the book series: Advances in Polymer Science ((POLYMER,volume 165))

Abstract

Lipid and polyampholyte monolayers are shown to constitute interesting models for study of electrostatic and steric interactions of polyelectrolytes at interfaces. Measurements with Langmuir monolayers at the air/water interface yield access to the energetics and kinetics of adsorption processes. Newly developed types of optical microscopy, X-ray diffraction, and reflection techniques yield fine structural details, for example lipid structure, segment density profiles, and domain structure. Scanning probe microscopy enables resolution of adsorbate structure on solid surfaces which proves to be most interesting for polyampholytes, for which the charge density can be varied via pH. The results can only partly be explained by theory. Unexpected and not yet explained findings are attractive interactions of polyelectrolytes and interfaces and long-range interactions affecting kinetics and micro phase separations. They can, however, be used as a primary means of controlling interface properties and structure.

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Acknowledgement

We would like to thank many groups leaders and graduate students, who are co-authors of the publications cited, for their motivated and skillful collaboration. Our work was funded by the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie, and the Bundesministerium für Forschung und Technologie.

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Authors and Affiliations

  1. Max-Planck-Institut für Kolloid- und Grenzflächenforschung, Am Mühlenberg 1, 14424, Potsdam, Germany

    H. Möhwald

  2. Institut für Technische Chemie, Technische Universität Braunschweig, Hans-Sommer-Strasse 10, 38106, Braunschweig, Germany

    H. Menzel

  3. Institut für Physik, Bereich Angewandte Physik, Ernst-Moritz-Arndt-Universität, Friedrich-Ludwig-Jahn-Strasse 16, 17487, Greifswald, Germany

    C. A. Helm

  4. Institut für Polymerforschung Dresden, Hohe Strasse 6, 01069, Dresden, Germany

    M. Stamm

Authors
  1. H. Möhwald
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  2. H. Menzel
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  3. C. A. Helm
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  4. M. Stamm
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Correspondence to H. Möhwald .

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Manfred Schmidt

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© 2004 Springer-Verlag Berlin Heidelberg

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Möhwald, H., Menzel, H., Helm, C.A., Stamm, M. (2004). Lipid and Polyampholyte Monolayers to Study Polyelectrolyte Interactions and Structure at Interfaces. In: Schmidt, M. (eds) Polyelectrolytes with Defined Molecular Architecture I. Advances in Polymer Science, vol 165. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b11269

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  • DOI: https://doi.org/10.1007/b11269

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-00528-5

  • Online ISBN: 978-3-540-36433-7

  • eBook Packages: Springer Book Archive

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