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Motional Phase Disorder of Polymer Chains as Crystallized to Hexagonal Lattices

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Interphases and Mesophases in Polymer Crystallization II

Part of the book series: Advances in Polymer Science ((POLYMER,volume 181))

Abstract

Chain-dynamics of flexible synthetic macromolecules in the crystalline state has been clarifiedby multinuclear solid-state NMR observations. Massive motional phenomena are shown when chains arecrystallized in the hexagonal phase. Several examples have been surveyed, where motion is inducedby high temperature and pressure or favored by inclusion of moderate amounts of comonomer units inthe main chain and by the use of monomers containing mobile side chains. Also, motional phenomenaof fast spinning and large librations of the macromolecules are promoted when the isolated chainsare confined to nanochannels formed in hexagonal crystal structures of suitable matrices. The motionalbehavior can be modulated by the topology and the interactions in the unusual environments. Thisknowledge provides information about polymers in close contact with heterogeneous interfaces, suchas polymers in nanocomposites or at surfaces.

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Authors and Affiliations

  1. Department of Materials Science, University of Milano ~ Bicocca, Via R. Cozzi 53, 20125, Milano, Italy

    P. Sozzani, S. Bracco, A. Comotti & R. Simonutti

Authors
  1. P. Sozzani
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  2. S. Bracco
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  3. A. Comotti
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  4. R. Simonutti
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Corresponding author

Correspondence to P. Sozzani .

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Editors and Affiliations

  1. Dipartimento di Chimica Materiali e Ingegneria Chimica “Giulio Natta”, Politecnico di Milano, Via L. Mancinelli, 7, 20131, Milano

    Giuseppe Allegra

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Sozzani, P., Bracco, S., Comotti, A., Simonutti, R. (2005). Motional Phase Disorder of Polymer Chains as Crystallized to Hexagonal Lattices. In: Allegra, G. (eds) Interphases and Mesophases in Polymer Crystallization II. Advances in Polymer Science, vol 181. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b107180

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