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Proton-Exchanging Electrolyte Membranes Based on Aromatic Condensation Polymers

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Inorganic Polymeric Nanocomposites and Membranes

Part of the book series: Advances in Polymer Science ((POLYMER,volume 179))

Abstract

The results of the research and development of novel proton-exchanging membranes based on aromaticcondensation polymers have been analysed and summarized with respect to their application in fuelcells. Primary attention has been paid to the basic properties of the starting polymers, such asthermal stability, water uptake and proton conductivity. General approaches to the preparation ofaromatic condensation polymers with high proton conductivity have been considered, including directsuffocation, synthesis from monomers containing sulfonic acid groups, incorporation of alkylsulfonatedsubstituents and formation of acid-basic polymer complexes. The bibliography includes 200 references.

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Abbreviations

13C-NMR:

Carbon-13 nuclear magnetic resonance

1H-NMR:

Proton nuclear magnetic resonance

ACPs:

Aromatic condensation polymers

DMAA:

N,N-Dimethylacetamide

DMF:

Dimethylformamide

DMSO:

Dimethylsulfoxide

DNTA:

Naphthalene-1,4,5,8-tetracarboxylic acid dianhydride

DSC:

Differential scanning calorimetry

FT-IR:

Fourier transform infrared spectroscopy

IR:

Infrared spectroscopy

m-disulfo PBT:

Poly[(benzo[1,2-d:4,5-d′]bisthiazole-2,6-diyl)-4,6-disulfo-1,3-phenylene]

m-sulfo PBT:

Poly[(benzo[1,2-d:4,5-d′]bisthiazole-2,6-diyl)-5-sulfo-1,3-phenylene]

N-MP:

N-Methyl-2-pyrrolidone

NMR:

Nuclear magnetic resonance

PBI-MPS:

(Methyl)propylsulfonated poly(benzimidazole)

PBI-PS:

Propylsulfonated poly(benzimidazole)

PBP:

Poly(4-benzoyl)-1,4-phenylene

PBTs:

Poly(benzobisthiazoles)

PEEK:

Poly(ether ether ketones)

PEMFS:

Proton-exchanging membrane fuel cells

PES:

Poly(ether sulfone)

PMFC:

Polymer membrane fuel cell

PPA:

Polyphosphoric acid

PPBP:

Poly(4-phenoxybenzoyl-1,4-phenylene)

PPTA:

Poly(p-phenylene terephthalamide)

PSPPI:

Phenoxy substituted polyperyleneimide

PSSA:

Poly(styrenesulfonic acid)

p-sulfo PBT:

Poly[(benzo[1,2-d:4,5-d′]bisthiazole-2,6-diyl)-2-sulfo-1,4-phenylene]

S-PBI:

Arylsulfonated poly(benzimidazole)

S-PEEK:

Sulfonated poly(ether ether ketone)

S-PEES:

Sulfonated poly(ether ether sulfone)

SPEFC:

Solid polymer electrolytes fuel cells

S-PPBP:

Sulfonated poly(4-phenoxybenzoyl-1,4-phenylene)

S-PPO:

Sulfonated poly(phenylene oxide)

S-PPQ:

Sulfonated polyphenylquinoxaline

S-PPS:

Sulfonated poly(phenylene sulfide)

S-PPX:

Sulfonated poly(p-xylylene)

TGA:

Thermogravimetric analysis

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Authors and Affiliations

  1. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, 28 Vavilova str., 119334, Moscow, Russia

    Alexandre L. Rusanov

  2. Materials Research Institute, UNAM, Cirquito Exterioir s/n, CU, Apdo Postal 70-360 Coyoacan, 04510, Mexico City, Mexico

    Dmitri Likhatchev

  3. YUKOS Research & Development Centre, 55/1 b.2, Leninski pr., 119333, Moscow, Russia

    Petr V. Kostoglodov

  4. Max-Planck-Institut fur Polymerforschung, Ackermannweg 10, 55128, Mainz, Germany

    Klaus Müllen & Markus Klapper

Authors
  1. Alexandre L. Rusanov
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  2. Dmitri Likhatchev
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  3. Petr V. Kostoglodov
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  4. Klaus Müllen
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  5. Markus Klapper
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  6. Manfred Schmidt
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Correspondence to F. Guida-Pietrasanta , George P. Simon , Alexandre L. Rusanov , Arimitsu Usuki or Alexandre L. Rusanov .

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Rusanov, A., Likhatchev, D., Kostoglodov, P., Müllen, K., Klapper, M., Schmidt, M. (2005). Proton-Exchanging Electrolyte Membranes Based on Aromatic Condensation Polymers. In: Inorganic Polymeric Nanocomposites and Membranes. Advances in Polymer Science, vol 179. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b104480

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