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Polysilalkylene or Silarylene Siloxanes Said Hybrid Silicones

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Book cover Inorganic Polymeric Nanocomposites and Membranes

Part of the book series: Advances in Polymer Science ((POLYMER,volume 179))

Abstract

This paper reviews different methods of synthesis of polysilalkylene or silarylene siloxanesthat are sometimes called “hybrid” silicones. This special type of silicone has beendeveloped to avoid the drawback of the depolymerization of classical polysiloxanes in certain conditionsand to obtain elastomers with enhanced thermal and fuel resistance properties. These silicones havebeen prepared through two main routes: the polycondensation of α,ω-bis silanol monomers(prepared either via an organometallic route or via hydrosilylation of α,ω-dienes) andthe polyhydrosilylation of α,ω-dienes with dihydrodisiloxanes or oligosiloxanes.

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Abbreviations

BPA:

bisphenol A

DMS:

dimethylsiloxane

HSCTs:

high speed civil transports

PDMS:

polydimethylsiloxane

PI/PS:

poly(imidesiloxanes)

Pt-DVTMDS:

platinum-divinyl-1,3 tetramethyldisiloxane

PTFPMS:

polytrifluoropropylmethylsiloxane

ScCO2 :

supercritical carbon dioxide

TMG/CF3CO2H:

tetramethylguanidine/trifluoroacetic acid

TMPS-DMS:

tetramethyl-p-silphenylenesiloxane-dimethylsiloxane

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Authors and Affiliations

  1. Laboratoire de Chimie Macromoléculaire, UMR 5076 CNRS, Ecole Nationale Supérieure de Chimie de Montpellier, 8 Rue de l’Ecole Normale, 34296, Montpellier Cedex 5, France

    F. Guida-Pietrasanta & B. Boutevin

Authors
  1. F. Guida-Pietrasanta
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  2. B. Boutevin
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  3. Oskar Nuyken
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Corresponding authors

Correspondence to F. Guida-Pietrasanta , George P. Simon , Alexandre L. Rusanov , Arimitsu Usuki or F. Guida-Pietrasanta .

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Guida-Pietrasanta, F., Boutevin, B., Nuyken, O. (2005). Polysilalkylene or Silarylene Siloxanes Said Hybrid Silicones. In: Inorganic Polymeric Nanocomposites and Membranes. Advances in Polymer Science, vol 179. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b104479

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