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Organometallic PAEs

  • Elisabeth KlemmEmail author
  • Thomas Pautzsch
  • Lars Blankenburg
Chapter
Part of the Advances in Polymer Science book series (POLYMER, volume 177)

Abstract

This review describes recent results in the field of poly(aryleneethynylene)s (PAEs) that contain metal ions in the polymer backbone, or in the polymer side chain. This work is focused primarily on polymers possessing ligands of metal complexes as part of the aryleneethynylene chain. PAEs with porphyrinylene in the backbone have also been addressed. Synthetic routes toward the polymers, as well as their photochemical, photophysical, and electrochemical properties, are presented. Monodisperse oligo(phenyleneethynylene)s with terminal metal complexes or with a ferrocene and thiol at each end are mentioned.

Sonogashira polycondensation Hybrid polymers Polypyridine ligands Copolymers Macromolecular metal complexes 

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Authors and Affiliations

  • Elisabeth Klemm
    • 1
    Email author
  • Thomas Pautzsch
    • 1
  • Lars Blankenburg
    • 1
  1. 1.Institut für Organische Chemie und Makromolekulare ChemieFriedrich-Schiller-Universität JenaJenaGermany

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