Abstract
The influence of the surfactant structure on the thickening mechanism of low molecular weight thickeners is examined. Experimental results from rheological experiments are evaluated. The surfactants used are Akyposal BA56, Akyposal RLM56, Akyposoft 100 NV, Surfagene S 30, Akypo RLM25, Avanel S90 and Avanel S30. The thickening mechanism in concentrated surfactant systems of low molecular weight thickeners is based on the increase of the hydrodynamic volume of the micelles by the building of EO-shells around the micellar core. The presence of long EO-chains in the surfactant molecules makes it impossible to build the additional shells. The ionic headgroup present in the surfactant molecule can, to some extent, either reinforce of diminish this effect. Sulphate surfactants have a stronger specific interaction with the EO-groups of the rheology modifier than sulphonates, and these are again stronger than carboxylic acid salts.
Preview
Unable to display preview. Download preview PDF.
References
Bieleman JH, Riesthuis FJJ, van der Velden PM (1986) Polym Paint Col J 176:450–460
Karunasena A, Glass JE (1989) Polym Mater Sci Eng 61:544–549
Char K, Frank CW, Gast AP (1989) Langmuir 5:1335–1340
Siano DB, Bock J, Myer P, Valint PL Jr (1987) Polym Mater Sci Eng 57:609–612
Mast AP, Prud'homme RK, Glass JE: submitted for publication in Langmuir
Brackman J (1991) PhD-thesis, Groningen, The Netherlands
Aalbers JG (1964) PhD-thesis, Amsterdam, The Netherlands
Glass JE. Kaczmarski JP (1991) PMSE-proc. ACS 65:175–176
Varadaraj R, Bock J, Geissler P, Zushma S, Brons N, Coletti T (1991) J Coll Interf Sci 147:387–395
Varadaraj R, Bock J, Geissler P, Zushma S, Brons N, Coletti T (1991) J Coll Interf Sci 147:396–402
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 1993 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG
About this paper
Cite this paper
Mast, A.P. (1993). The specific interactions between HEUR associative polymers and surfactants. In: Laggner, P., Glatter, O. (eds) Trends in Colloid and Interface Science VII. Progress in Colloid & Polymer Science, vol 93. Steinkopff. https://doi.org/10.1007/BFb0118472
Download citation
DOI: https://doi.org/10.1007/BFb0118472
Published:
Publisher Name: Steinkopff
Print ISBN: 978-3-7985-0955-9
Online ISBN: 978-3-7985-1676-2
eBook Packages: Springer Book Archive