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Structure, Dynamics and Properties of Disperse Colloidal Systems pp 174–178Cite as

Adsorption of anionic surfactant Na-dodecylsulphate (SDS) at the polyvinylpyrrolidone (PVP)-modified Na-montmorillonite surface

  • Colloidal Systems In Environmental Science
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Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 111))

Abstract

An enhanced adsorption of Na-dodecylsulphate (SDS) at Na-montmorillonite is observed through a specific binding to an adsorbed layer of nonionic polyvinylpyrrolidone (PVP) polymer. These results are supported by electrokinetic measurements and the fluorescence pyrene probe method. At high PVP loadings, a negative electrophoretic mobility increase and the fluorescence detection of PVP/SDS aggregates confirm that a PVP coiled structure promotes the interactions with anionic SDS molecules outside the range of electrostatic repulsion forces arising from the negatively charged montmorillonite surface.

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Authors and Affiliations

  1. Institute of Applied Physical Chemistry, Research Centre Jülich, D-52425, Jülich, Germany

    A. Hild, J. -M. Séquaris, H. D. Narres & M. J. Schwuger

Authors
  1. A. Hild
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  2. J. -M. Séquaris
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  3. H. D. Narres
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  4. M. J. Schwuger
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Corresponding author

Correspondence to J. -M. Séquaris .

Editor information

Heinz Rehage Gerhard Peschel

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© 1998 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Hild, A., Séquaris, J.M., Narres, H.D., Schwuger, M.J. (1998). Adsorption of anionic surfactant Na-dodecylsulphate (SDS) at the polyvinylpyrrolidone (PVP)-modified Na-montmorillonite surface. In: Rehage, H., Peschel, G. (eds) Structure, Dynamics and Properties of Disperse Colloidal Systems. Progress in Colloid & Polymer Science, vol 111. Steinkopff. https://doi.org/10.1007/BFb0118128

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  • DOI: https://doi.org/10.1007/BFb0118128

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1118-7

  • Online ISBN: 978-3-7985-1652-6

  • eBook Packages: Springer Book Archive

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